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US5066567A Expired / Lapsed US ⏱️ 0.0 years remaining

Image reversal process utilizing a positive-working photosensitive composition containing a dye

Assignee: CLARIANT AZ (DEUTSCHLAND) AG
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Filing: 1990-03-28
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Granted: 1991-11-19
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Expires: 2010-03-28
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Abstract

Abstract A positive-working photosensitive composition is disclosed that comprises a photosensitive compound which is either of the o-quinone diazide type or comprises a photolytic acid donor in combination with a compound containing a C-O-C group, a binder which is soluble or swellable in an aqueous-alkaline solution and a dye of the general formula I ##STR1## The photosensitive composition of the present invention has a higher photosensitivity than comparable compositions containing other dyes.

Inventors

  • 👤 Hans-Joachim Merrem
  • 👤 Gerhard Buhr
  • 👤 Ruediger Lenz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 20:11
CPC Classifications
G; G03; G03C; G03C1/00; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/091

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 268 words
A process for the production of a relief pattern according to the image reversal process, the process comprising the steps of: coating a support with a photosensitive composition comprising in admixture a photosensitive compound selected from the group consisting of (a) a combination of a photolytic acid donor and an acid-cleavable compound containing a C--O--C group and (b) an o-quinone diazide, in an amount sufficient to change the solubility of areas of a layer of the composition that have been exposed to actinic light, a binder that is insoluble in water and soluble or swellable in an aqueous-alkaline solution in an amount sufficient to produce a uniform film when the composition is coated on the support, a crosslinking agent in an amount sufficient to effect crosslinking of the binder and a dye comprising a non-bleachable compound that absorbs light in the actinic region and corresponds to the general formula I ##STR3## wherein R 1 denotes hydrogen, alkyl, aryl, alkoxy or nitrilo, R 2 and R 3 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, nitrilo, amino, alkylamino or halogen, and R 4 , R 5 , R 6 and R 7 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, amino, alkylamino or halogen, the dye being present in an amount sufficient to reduce interference effects on optical resolution, drying the layer, imagewise exposing the layer to actinic light, then subjecting the layer to an overall reexposure by means of actinic radiation, and then developing the layer with an aqueous-alkaline solution to remove the imagewise unexposed areas and achieve image reversal.
Claim 2
Dependent Claim 268 words
A process for the production of a relief pattern according to the image reversal process, the process comprising the steps of: coating a support with a photosensitive composition comprising in admixture a photosensitive compound selected from the group consisting of (a) a combination of a photolytic acid donor and an acid-cleavable compound containing a C--O--C group and (b) an o-quinone diazide, in an amount sufficient to change the solubility of areas of a layer of the composition that have been exposed to actinic light, a binder that is insoluble in water and soluble or swellable in an aqueous-alkaline solution in an amount sufficient to produce a uniform film when the composition is coated on the support, a crosslinking agent in an amount sufficient to effect crosslinking of the binder and a dye comprising a non-bleachable compound that absorbs light in the actinic region and corresponds to the general formula I ##STR3## wherein R 1 denotes hydrogen, alkyl, aryl, alkoxy or nitrilo, R 2 and R 3 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, nitrilo, amino, alkylamino or halogen, and R 4 , R 5 , R 6 and R 7 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, amino, alkylamino or halogen, the dye being present in an amount sufficient to reduce interference effects on optical resolution, drying the layer, imagewise exposing the layer to actinic light, then subjecting the layer to an overall reexposure by means of actinic radiation, and then developing the layer with an aqueous-alkaline solution to remove the imagewise unexposed areas and achieve image reversal.
Claim 3
Dependent Claim 24 words
A process as claimed in claim 1, wherein the dye has an absorption peak in the range of the emission of mercury vapor lamps.
Claim 4
Dependent Claim 22 words
A process as claimed in claim 1, wherein the dye has an absorption peak in the region from 365 to 436 nm.
Claim 5
Dependent Claim 17 words
A process as claimed in claim 1, wherein the photolytic acid donor comprises an organic halogen compound.
Claim 6
Dependent Claim 15 words
A process as claimed in claim 1, wherein the binder comprises a novolak condensation resin.
Claim 7
Dependent Claim 27 words
A process as claimed in claim 5, wherein the alkali-soluble novolak condensation resin is blended with up to 20% by weight of at least one other resin.
Claim 8
Dependent Claim 25 words
A process as claimed in claim 1, wherein the photosensitive layer consists essentially of the photosensitive compound, the binder, the crosslinking agent and the dye.
Claim 9
Dependent Claim 36 words
A process as claimed in claim 7, consisting essentially of the steps of coating the support with the layer, drying the layer, imagewise exposing the layer, subjecting the layer to overall reexposure, and developing the layer.
Claim 10
Dependent Claim 81 words
A process as claimed in claim 1, wherein R 1 denotes hydrogen, (C 1 -C 3 )alkyl or phenyl, R 2 and R 3 denote hydrogen, hydroxy, (C 1 -C 3 )alkyl, (C 6 -C 10 )aryl, (C 1 -C 3 )alkoxy, amino, (C 1 -C 3 )alkylamino, halogen, and R 4 , R 5 , R 6 and R 7 denote hydrogen, (C 1 -C 3 )alkyl, (C 6 -C 10 )aryl, (C 1 -C 3 )alkoxy, amino or halogen.
Claim 11
Dependent Claim 59 words
A process as claimed in claim 1, wherein R 1 denotes hydrogen, R 2 and R 3 denote hydrogen, hydroxy (C 1 -C 3 )alkyl, phenyl, amino or chlorine, and R 4 and R 6 and R 5 and R 7 are identical and denote hydrogen, (C 1 -C 3 )alkyl, (C 1 -C 3 )alkoxy, amino or chlorine.
Claim 12
Dependent Claim 49 words
A process as claimed in claim 1, wherein R 1 denotes hydrogen, R 2 and R 3 denote hydrogen, hydroxy or (C 1 -C 3 )alkyl and R 4 and R 6 and R 5 and R 7 are identical and denote hydrogen or (C 1 -C 3 )alkyl.
Claim 13
Dependent Claim 18 words
A process as claimed in claim 1, wherein the radicals R 1 to R 7 are all hydrogen.
Claim 14
Dependent Claim 26 words
A process as claimed in claim 1, wherein the radicals R 1 and R 3 to R 7 are all hydrogen and R 2 is methyl.
Claim 15
Dependent Claim 22 words
A process as claimed in claim 1, wherein R 2 and/or R 3 are hydroxy, (C 1 -C 3 )alkyl or phenyl.
Claim 16
Dependent Claim 28 words
A process as claimed in claim 1, wherein R 2 and/or R 3 are in each case in the o-position with respect to the tertiary aromatic amino group.
Claim 17
Dependent Claim 31 words
A process as claimed in claim 1, wherein R 2 and R 3 denote chlorine or bromine and R 4 , R 5 , R 6 and R 7 denote chlorine.
Claim 18
Dependent Claim 21 words
A process as claimed in claim 1, wherein the dried layer comprises from 0.05 to 5% by weight of the dye.
Claim 19
Dependent Claim 21 words
A process as claimed in claim 1, wherein the dried layer comprises from 0.02 to 2% by weight of the dye.

References Cited (Backward Citations)

US4349619A Cited
US4762767A Cited
US4581321A Cited
US4575480A Cited
EP0164248A2 Cited
US4626492A Cited
US4931381A Cited
EP0231522A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-11-18 1995-05-20 1995-11-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-11-18 1999-05-20 1999-11-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-11-18 2003-05-20 2003-11-19 $7700.00 Window Closed / Lapsed

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