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US4762767A Expired / Lapsed US ⏱️ 0.0 years remaining

Negatively operating photoresist composition, with radiation-absorbing additives

Assignee: OCG Microelectronic Materials Inc
•
Filing: 1986-04-30
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Granted: 1988-08-09
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Expires: 2006-04-30
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Abstract

Abstract New aminoazobenzene derivatives of the general formula I ##STR1## in which R and R' independently of one another denote hydrogen, alkyl with up to 4 C atoms or halogen, X denotes hydrogen or O--Y and Y denotes alkyl or acyl with in each case up to 4 C atoms or optionally substituted aryl with up to 10 C atoms, are outstandingly suitable as radiation-absorbing substances in negatively operating photoresist compositions.

Inventors

  • 👤 Gunther Haas
  • 👤 Karl H. Neisius

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 02:37
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/04; C; C09; C09B; C09B29/00; C09B29/06; C09B29/08; C09B29/0805; C09B29/0807; C09B29/0809; C09B29/0811; C09B29/0813; G03F7/008; G03F7/0085; G03F7/09; G03F7/091

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 94 words
In a negatively operating photoresist composition consisting essentially of a photoresist polymer which is a cyclized rubber and a photosensitive crosslinking agent which is an aromatic bisazido compound, the improvement wherein the composition further consists essentially of an amount effective as a radiation-absorbing substance of a compound of the formula ##STR3## wherein R and R' independently are hydrogen, alkyl of up to 4C atoms or halogen, X is hydrogen or O--Y and Y is alkyl or alkanoyl in each case of up to 4C atoms, phenyl, phenyl substituted by C 1-4 -alkyl or napthyl.
Claim 2
Dependent Claim 94 words
In a negatively operating photoresist composition consisting essentially of a photoresist polymer which is a cyclized rubber and a photosensitive crosslinking agent which is an aromatic bisazido compound, the improvement wherein the composition further consists essentially of an amount effective as a radiation-absorbing substance of a compound of the formula ##STR3## wherein R and R' independently are hydrogen, alkyl of up to 4C atoms or halogen, X is hydrogen or O--Y and Y is alkyl or alkanoyl in each case of up to 4C atoms, phenyl, phenyl substituted by C 1-4 -alkyl or napthyl.
Claim 3
Dependent Claim 11 words
A composition of claim 1, wherein the bisazido compound is 2,6-bis-[(4-azido-phenyl)methylene]-4-methylcyclohexanone.
Claim 4
Dependent Claim 26 words
A composition of claim 1, wherein the amount of said radiation-absorbing substance is about 0.1 to 7 wt % based on the amount of cyclized rubber.
Claim 5
Dependent Claim 12 words
A composition of claim 1, wherein R and R' are both H.
Claim 6
Dependent Claim 9 words
A composition of claim 1, wherein X is H.
Claim 7
Dependent Claim 13 words
A composition of claim 1, wherein Y is methyl, ethyl, acetyl or phenyl.
Claim 8
Dependent Claim 15 words
A composition of claim 1, wherein 4-N-ethyl-N-(2-phenoxyethyl)-aminoazobenzene, 4-N,N-bis(2-ethoxyethyl)-aminoazobenzene or 4-N,N-bis(2-acetoxyethyl)aminoazobenzene is the radiation absorbing substance.
Claim 9
Dependent Claim 12 words
A composition of claim 1, wherein 4-N-ethyl-N-(2-methoxyethyl)-aminoazobenzene is the radiation absorbing substance.
Claim 10
Dependent Claim 22 words
An article comprising a negative photoresist composition according to claim 1 applied to the surface of a substrate having high reflecting power.
Claim 11
Dependent Claim 15 words
An article according to claim 9, wherein said substrate is silicon, aluminum, copper or chromium.
Claim 12
Dependent Claim 12 words
A composition of claim 3, wherein said amount is 0.5-4 wt %.

References Cited (Backward Citations)

GB422843A Cited
US2336309A Cited
US2528460A Cited
US2833649A Cited
US4287289A Cited
US4268603A Cited
US4311773A Cited
US4349619A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-09 1992-02-08 1992-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-09 1996-02-08 1996-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-09 2000-02-08 2000-08-09 $7700.00 Window Closed / Lapsed

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