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US5059245A Expired / Lapsed US ⏱️ 0.0 years remaining

Ink incorporating optically variable thin film flakes

Assignee: Viavi Solutions Inc
•
Filing: 1988-09-26
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Granted: 1991-10-22
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Expires: 2008-09-26
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Abstract

Abstract Optically variable ink for obtaining a color shaft between two distinct two colors at first and second angles of incident light comprised of an ink vehicle and optically variable flakes disposed in the ink vehicle. The optically variable flakes are comprised of a multilayer thin film interference structure having first and second parallel planar surfaces. The optically variable flakes have physical dimensions such that when the flakes are measured in directions parallel and perpendicular respectively to the planar surfaces an aspect ratio of at least 2 to 1 is provided. The multilayer thin film structure is of symmetrical design and includes a metal reflector having first and second surfaces parallel to the first and second parallel planar surfaces and at least one period disposed on each of said first and second surfaces of the metal reflector. Each period is comprised of a dielectric layer with an index of refraction of 1.65 or less and a semi-opaque layer.

Inventors

  • 👤 Roger W. Phillips
  • 👤 Thomas Mayer
  • 👤 Gary S. Ash

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 06:26
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/0015; C09C1/0051; B; B05; B05D; B05D1/00; B05D1/28; B05D1/286; B05D5/00; B05D5/06; B41; B41M; B41M3/00; B41M3/14; C03; C03C; C03C17/00; C09C1/0078; C09D; C09D11/00; C09D11/50; F; F24; F24S; F24S70/00; F24S70/20; F24S70/225; C01; C01P; C01P2004/00; C01P2004/51; C01P2004/54; C09C2200/00; C09C2200/10; C09C2200/1054; C09C2200/24; C09C2220/00; C09C2220/20; Y; Y02; Y02E; Y02E10/00; Y02E10/40

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 155 words
In an optically variable ink for obtaining a color shift between two distinct colors at first and second angles of incident light, an ink vehicle and optically variable flakes disposed in the ink vehicle, the optically variable flakes being comprised of a multilayer thin film interference structure having first and second parallel planar surfaces, the optically variable flakes having physical dimensions such that when the flakes are measured in directions parallel and perpendicular respectively to the planar surfaces an aspect ratio of at least 2 to 1 is provided, the multilayer thin film structure being of symmetrical design and including a metal reflector having first and second surfaces parallel to the first and second parallel planar surfaces at least one period disposed on each of said first and second surfaces of the metal reflector, each period being comprised of a dielectric layer with an index of refraction of 1.65 or less and a semi-opaque layer.
Claim 2
Dependent Claim 155 words
In an optically variable ink for obtaining a color shift between two distinct colors at first and second angles of incident light, an ink vehicle and optically variable flakes disposed in the ink vehicle, the optically variable flakes being comprised of a multilayer thin film interference structure having first and second parallel planar surfaces, the optically variable flakes having physical dimensions such that when the flakes are measured in directions parallel and perpendicular respectively to the planar surfaces an aspect ratio of at least 2 to 1 is provided, the multilayer thin film structure being of symmetrical design and including a metal reflector having first and second surfaces parallel to the first and second parallel planar surfaces at least one period disposed on each of said first and second surfaces of the metal reflector, each period being comprised of a dielectric layer with an index of refraction of 1.65 or less and a semi-opaque layer.
Claim 3
Dependent Claim 30 words
An ink as in claim 1 together with a substantially transparent pigment dispersed in the ink vehicle for blocking out on undesired color or modifying a color in the spectrum.
Claim 4
Dependent Claim 26 words
An ink as in claim 2 wherein said multilayer thin film structure provides a green-to-gold color shift and wherein the pigment is a yellow blocking pigment.
Claim 5
Dependent Claim 21 words
An ink as in claim 1 wherein said optically variable flakes constitute from 15 to 50% by weight of the ink.
Claim 6
Dependent Claim 21 words
An ink as in claim 2 wherein the pigment blocks out undesired colors between the first and second angles of incidence.
Claim 7
Dependent Claim 26 words
An ink as in claim 2 wherein the pigment blocks out undesired colors at angles of incidence higher than the first and second angles of incidence.
Claim 8
Dependent Claim 19 words
An ink as in claim 1 wherein the flakes have a maximum dimension ranging from 2 to 125 microns.
Claim 9
Dependent Claim 176 words
In an optical variable ink for obtaining a color shift between two distinct predetermined colors, an ink vehicle and optically variable flakes dispersed in the ink vehicle and having first and second parallel surfaces, said optically variable flakes being comprised of a multilayer thin film interference structure exhibiting two predetermined uniform colors as the incident light on the flakes is shifted between two angles, said flakes having physical dimensions in directions parallel and perpendicular respectively to the first and second planar surfaces to provide an aspect ratio of at least 2:1, said thin film interference structure including a metal reflector having first and second surfaces parallel to the first and second parallel surfaces and at least one period disposed on each of the first and second surfaces of the metal reflector, each period being comprised of a dielectric layer of an inorganic material of a predetermined thickness and a semi-opaque layer of a predetermined material and of a predetermined thickness so that the flakes are symmetrically optically variable providing increased saturation of color in the ink.
Claim 10
Dependent Claim 176 words
In an optical variable ink for obtaining a color shift between two distinct predetermined colors, an ink vehicle and optically variable flakes dispersed in the ink vehicle and having first and second parallel surfaces, said optically variable flakes being comprised of a multilayer thin film interference structure exhibiting two predetermined uniform colors as the incident light on the flakes is shifted between two angles, said flakes having physical dimensions in directions parallel and perpendicular respectively to the first and second planar surfaces to provide an aspect ratio of at least 2:1, said thin film interference structure including a metal reflector having first and second surfaces parallel to the first and second parallel surfaces and at least one period disposed on each of the first and second surfaces of the metal reflector, each period being comprised of a dielectric layer of an inorganic material of a predetermined thickness and a semi-opaque layer of a predetermined material and of a predetermined thickness so that the flakes are symmetrically optically variable providing increased saturation of color in the ink.
Claim 11
Dependent Claim 20 words
An ink as in claim 8 wherein said dielectric material has a low index of refraction of 1.65 or less.
Claim 12
Dependent Claim 19 words
An ink as in claim 8 wherein said flakes have a particle size ranging from 2 to 125 microns.
Claim 13
Dependent Claim 43 words
An ink as in claim 8 wherein the ink vehicle is for an Intaglio ink and wherein the optically variable flakes have a particle size in the range of approximately 5-15 microns and constitute approximately 10 to 30% by weight of the ink.

References Cited (Backward Citations)

GB957535A Cited
DE1242778B Cited
GB978200A Cited
US3858977A Cited
US4116710A Cited
US4010293A Cited
US4180407A Cited
US4221593A Cited
US4168986A Cited
JPS58203039A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-10-21 1995-04-22 1995-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-10-21 1999-04-22 1999-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-10-21 2003-04-22 2003-10-22 $7700.00 Window Closed / Lapsed

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