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US5050182A
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Chemical process yielding stimulated emission of visible radiation via fast near resonant energy transfer
Assignee: Georgia Tech Research Corp
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Filing: 1989-07-03
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Granted: 1991-09-17
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Expires: 2009-07-03
Abstract
Abstract A process for increasing the efficiency of a chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of reacting a first metal vapor with a reactant to form a metastable state of a metal oxide or metal halide and transferring the energy from the metastable state to receptor metal atoms by means of near resonant energy transfer to form electronically excited receptor metal atoms in an inverted configuration by using highly volatile precursor compounds to provide the receptor metal atoms, by introducing a quenchant gas during the energy transfer step, or by introducing CO2 laser photons during the energy transfer step.
Inventors
- 👤 James L. Gole
- 👤 James R. Woodward
- 👤 Stephen H. Cobb
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 20:43
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/09; H01S3/095
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
295 words
A chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal and semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal and semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV, said reactant being selected rom the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms generating a population inversion relative to a terminal laser level of excitation of said receptor atoms; and (f) introducing a quenching gas into the region in which the second source of atomic vapor receives energy in a near resonant energy transfer; and depleting said terminal laser level by means selected from the group consisting of near resonant energy transfer between the quenching gas and the terminal laser level, and complexation of the quenching gas with the terminal laser level or both, such that the population inversion between the excited and the terminal laser level of the receptor atoms can be maintained more effectively.
Claim 2
Dependent Claim
295 words
A chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal and semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal and semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV, said reactant being selected rom the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms generating a population inversion relative to a terminal laser level of excitation of said receptor atoms; and (f) introducing a quenching gas into the region in which the second source of atomic vapor receives energy in a near resonant energy transfer; and depleting said terminal laser level by means selected from the group consisting of near resonant energy transfer between the quenching gas and the terminal laser level, and complexation of the quenching gas with the terminal laser level or both, such that the population inversion between the excited and the terminal laser level of the receptor atoms can be maintained more effectively.
Claim 3
Dependent Claim
22 words
A process as defined in claim 1 wherein the gas is selected from the group consisting of atomic iodine and water vapor.
Claim 4
Dependent Claim
17 words
A process as defined in claim 1 wherein the receptor atoms are non-reactive with the selected reactant.
Claim 5
Dependent Claim
36 words
A process as defined in claim 1 wherein the receptor atoms are selected from the group consisting of atoms receiving gas kinetic or near resonant energy transfer from the metastable states of the oxide and halide.
Claim 6
Dependent Claim
19 words
A process as defined in claim 1 wherein the receptor atoms are selected from the group consisting of thallium.
Claim 7
Dependent Claim
24 words
A process as defined in claim 1 wherein the said first source of vapor is selected from the group consisting of germanium and silicon.
Claim 8
Dependent Claim
30 words
A process as defined in claim 1 wherein said first source of vapor is silicon and the reactant is selected from the group consisting of nitrogen oxide and nitrogen dioxide.
Claim 9
Dependent Claim
21 words
A process as defined in claim 1 wherein said first source of vapor is silicon and the reactant is nitrogen dioxide.
Claim 10
Dependent Claim
23 words
A process as defined in claim 1 wherein source of said first source of metal vapor is germanium and the reactant is ozone.
Claim 11
Dependent Claim
43 words
A process as defined in claim 1 wherein step (a) includes first providing a source of a first element selected from the group consisting of metals and semimetals and heating said first element to form the first source of vapor to be reacted.
Claim 12
Dependent Claim
27 words
A process as defined in claim 10, wherein said first element is heated to a temperature producing a vapor pressure of approximately 10 -1 to 2 Torr.
Claim 13
Dependent Claim
45 words
A process as defined in claim 1 wherein step (b) includes first providing a source of a second element selected from the group consisting of metals and semimetals and heating said second element to form said second source of vapor to serve as receptor atoms.
Claim 14
Dependent Claim
26 words
A process as defined in claim 12, wherein said second element is heated to a temperature producing approximately a 10 -1 to 10 Torr vapor pressure.
Claim 15
Dependent Claim
282 words
A chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal and semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal and semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV, said reactant being selected from the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms; generating a population inversion relative to a terminal level of excitation of said receptor atoms; and (f) introducing coherent photons into the region in which the second source of atomic vapor receives energy, to supply additional energy to the reactant leading to vibrational excitation of the reactant so that said reactant reacts with the first source of vapor and also reacts in an exothermic process with the terminal level of excitation of the receptor atoms to deplete said terminal level such that the population inversion can be maintained more effectively.
Claim 16
Dependent Claim
282 words
A chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal and semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal and semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV, said reactant being selected from the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms; generating a population inversion relative to a terminal level of excitation of said receptor atoms; and (f) introducing coherent photons into the region in which the second source of atomic vapor receives energy, to supply additional energy to the reactant leading to vibrational excitation of the reactant so that said reactant reacts with the first source of vapor and also reacts in an exothermic process with the terminal level of excitation of the receptor atoms to deplete said terminal level such that the population inversion can be maintained more effectively.
Claim 17
Dependent Claim
17 words
A process as defined in claim 14 wherein the photons are provided from a CO 2 laser.
Claim 18
Dependent Claim
18 words
A process as defined in claim 14 wherein the receptor metal atoms are non-reactive with the selected reactant.
Claim 19
Dependent Claim
39 words
A process as defined in claim 14 wherein the receptor metal atoms are selected from the group of metal atoms receiving gas kinetic or near resonant energy transfer from the metastable states of select metal oxide and metal halide.
Claim 20
Dependent Claim
22 words
A process a defined in claim 14 wherein the receptor metal atoms are selected from the group consisting of thallium and gallium.
Claim 21
Dependent Claim
43 words
A process as defined in claim 14 wherein the metal for said first source of metal vapor is selected from the group consisting of germanium and silicon and said reactant is selected from the group consisting of ozone, nitrogen oxide and nitrogen dioxide.
Claim 22
Dependent Claim
34 words
A process as defined in claim 14 wherein the metal for said first source of metal vapor is silicon and the reactant is selected from the group consisting of nitrogen oxide and nitrogen dioxide.
Claim 23
Dependent Claim
25 words
A process as defined in claim 14 wherein the metal for said first source of metal vapor is silicon and the reactant is nitrogen dioxide.
Claim 24
Dependent Claim
24 words
A process as defined in claim 14 wherein the metal for said first source of metal vapor is germanium and the reactant is ozone.
Claim 25
Dependent Claim
32 words
A process as defined in claim 14 wherein the metal for said first metal vapor is selected from the group consisting of scandium, yttrium, and lanthanum and the reactant is a halogen.
Claim 26
Dependent Claim
36 words
A process as defined in claim 14 wherein step (a) includes first providing a source of a first metal and heating said source of first metal forming the first source of metal vapor to be reacted.
Claim 27
Dependent Claim
30 words
A process as defined in claim 24, wherein said source of a first metal is heated to a temperature producing a vapor pressure of approximately 10 -1 to 2 Torr.
Claim 28
Dependent Claim
36 words
A process as defined in claim 14 wherein step (b) includes first providing a source of a second metal and heating said source of second metal to form atomic metal vapor to serve as receptor atoms.
Claim 29
Dependent Claim
28 words
A process as defined in claim 26, wherein the source of second metal is heated to a temperature producing approximately a 10 -1 to 10 Torr vapor pressure.
Claim 30
Dependent Claim
19 words
A process as defined in claims 1 or 14, wherein said receptor metal atoms are provided from precursor compounds.
Claim 31
Dependent Claim
14 words
A process as defined in claim 28, wherein said precursor compounds are highly volatile.
Claim 32
Dependent Claim
26 words
A process as defined in claim 29, wherein said precursor compounds are selected from the group consisting of multiply ligated hydrides, metal hydrides, and methyl compounds.
Claim 33
Dependent Claim
20 words
A process as defined in claim 30, wherein said metal atoms are selected from the transition series (Group IIIB-VIII) metals.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-09-16 | 1995-03-18 | 1995-09-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-09-16 | 1999-03-18 | 1999-09-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-09-16 | 2003-03-18 | 2003-09-17 | $7700.00 | Window Closed / Lapsed |