← Back to Patent Explorer
US5045579A Expired / Lapsed US ⏱️ 0.0 years remaining

Selective absorbents

Assignee: Liquid Waste Corp
•
Filing: 1990-05-18
•
Granted: 1991-09-03
•
Expires: 2010-05-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The preparation and use of unique, environmentally benign, economical and selectively modified polynorbornene sponges are described as selective absorbents for hydrocarbons, their halogenated analogs and selected oxygenated derivatives thereof. The modified polynorbornene material contains organo-titanium phosphates or oligophosphates and is environmentally stable for extended periods, easy to use, efficient and absorbate-retentive. Exhausted product will not drip or exude absorbate under conventional landfill disposal conditions and will produce only minimal ash when incinerated.

Inventors

  • 👤 Gerald Sugerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:34
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0091; C08K5/49; C08K5/51; C08K5/52

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 25 words
An absorbent aggregate comprising particulate polynorbornene, hydrocarbon plasticizer, minor proportions of an organo-titanium phosphate or oligophosphate and optionally minor amounts of a hard resin particulate.
Claim 2
Dependent Claim 25 words
An absorbent aggregate comprising particulate polynorbornene, hydrocarbon plasticizer, minor proportions of an organo-titanium phosphate or oligophosphate and optionally minor amounts of a hard resin particulate.
Claim 3
Dependent Claim 28 words
The absorbent aggregate of claim 1 wherein the organo-titanium phosphate or oligophosphate is present in an amount of from 0.1 to about 5.0 wt. % based on polynorbornene.
Claim 4
Dependent Claim 23 words
The absorbent aggregate of claim 1 wherein the hard resin content is from about 0.1 to about 25 wt. % based on polynorbornene.
Claim 5
Dependent Claim 48 words
An absorbent particulate prepared by thoroughly admixing polynorbornene with from about 10 to about 45 wt. % of a hydrocarbon plasticizer, from about 0.1 to about 5.0 wt. % of an organo-titanium phosphate or oligophosphate and optionally from about 0.1 to about 25 wt. % hard organic resin.
Claim 6
Dependent Claim 48 words
An absorbent particulate prepared by thoroughly admixing polynorbornene with from about 10 to about 45 wt. % of a hydrocarbon plasticizer, from about 0.1 to about 5.0 wt. % of an organo-titanium phosphate or oligophosphate and optionally from about 0.1 to about 25 wt. % hard organic resin.
Claim 7
Dependent Claim 189 words
The absorbent aggregate of claim 1 wherein the organo-titanium compound has the formula: ##STR3## where A 1 =(RO) wherein each R is an alkyl, alkenyl or aralkyl group having less than 20 carbon atoms inclusive of up to 4 ether and/or halogen substituents; A 2 =--O(CR 1 R2) b (CO) c O-- wherein each R 1 and R 2 is independently selected from hydrogen, alkyl, alkenyl, aralkyl or alkaryl groups or ether and/or halogen substituted derivatives thereof having less than 20 carbon atoms each; ##STR4## wherein R 3 , R 4 and R 5 are each independently selected from among alkyl, alkenyl, aralkyl or alkaryl groups having less than 20 carbon atoms each inclusive of up to 3 ether and/or halogen substituents; X and Y may each be chosen from among the same groups as R 3 , R 4 and R5 but where one of the X or a Y group may also be hydrogen; L is a diester phosphite having not more than 40 carbon atoms per molecule; and B 2 is --OP(O)(OR 3 )OP(O)(OR 4 )O-- wherein R 3 and R 4 are as defined above.
Claim 8
Dependent Claim 17 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV (bis-2,2-propenolatomethyl)butanolato, tris (dioctyl) phosphato-O.
Claim 9
Dependent Claim 17 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV (bis-2,2-propenolatomethyl)butanolato, tris (dioctyl) diphosphato-O.
Claim 10
Dependent Claim 27 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV bis(methyl, propyl) diphosphato-O, 2,3-bis phenoxymethyl-1-oxo-propanediolato, adduct with 1 mole of phenyl, 2-chloroethyl, hydrogen phosphite.
Claim 11
Dependent Claim 19 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV (dimethoxyethyl) cyclo diphosphato-0,0, (1-propoxyphenyl, 2-propyl) ethanediolato.
Claim 12
Dependent Claim 16 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV (dibenzyl) cyclodiphosphato-0,0, oxoethylenediolato.
Claim 13
Dependent Claim 28 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV hexanolato, (methyl, phenyl, propyl) pentaphosphato-0,1,2-octane diolato, adduct with 1 mole of (butyl, benzyl) hydrogen phosphite.
Claim 14
Dependent Claim 19 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV bis neopentanolato, bis (octyl, octadecyl) phosphato-0.
Claim 15
Dependent Claim 25 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV bis (diphenoxyethyl) diphosphato-0, 1,3-propanediolato, adduct with 1 mole of di(2-octadecenyl) hydrogen phosphite.
Claim 16
Dependent Claim 28 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV butanolato, (methyl, vinyl) cyclo diphosphato-0,0, (dioctyl) diphosphato-0, adduct with one mole of dimethyl, hydrogen phosphite.
Claim 17
Dependent Claim 19 words
The absorbent aggregate of claim 5 wherein the organo-titanium compound is titanium IV 2,4-dichlorophenylato, 2,3-pentanediolato, (tertiary butyl, vinyl) phosphato-0.

References Cited (Backward Citations)

US4277415A Cited
US4417009A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-09-02 1995-03-04 1995-09-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-09-02 1999-03-04 1999-09-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-09-02 2003-03-04 2003-09-03 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag