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US5045426A Expired / Lapsed US ⏱️ 0.0 years remaining

Toner adhesion-enhancing coating for security documents

Assignee: Standard Register Co
•
Filing: 1989-06-21
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Granted: 1991-09-03
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Expires: 2009-06-21
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Abstract

Abstract A coated cellulosic web product and coating composition which provides enhanced toner adhesion for documents printed using noncontact printing devices such as laser printers is provided. The toner adhesion enhancing coated cellulosic product includes a cellulosic web having first and second major surfaces with at least one of the major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a generally transparent copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C and from about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer. The web may be either continuous or in sheet form. The toner adhesion-enhancing composition may also optionally include a coloring agent and a plasticizing agent.

Inventors

  • 👤 Theodore Maierson
  • 👤 William H. Mowry, Jr.
  • 👤 Dianne M. Potter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 07:59
CPC Classifications
D; D21; D21H; D21H21/00; D21H21/14; D21H21/40; D21H21/44; D21H21/46; G; G03; G03G; G03G13/00; G03G13/14; G03G13/16; G03G7/00; G03G7/0006; G03G7/0013; G03G7/002; G03G7/0026; G03G7/004; G03G7/006; G03G7/0073; G03G7/008

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 79 words
A toner adhesion-enhancing coated cellulosic product comprising a cellulosic web having first and second major surfaces, at least one of said major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a cross-linked copolymer formed from a mixture of a dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer.
Claim 2
Dependent Claim 79 words
A toner adhesion-enhancing coated cellulosic product comprising a cellulosic web having first and second major surfaces, at least one of said major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a cross-linked copolymer formed from a mixture of a dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer.
Claim 3
Dependent Claim 16 words
The coated product of claim 1 in which said toner adhesion-enhancing composition includes a coloring agent.
Claim 4
Dependent Claim 20 words
The coated product of claim 2 in which said coloring agent is a dye contained in a plurality of microcapsules.
Claim 5
Dependent Claim 18 words
The coated product of claim 3 in which said microcapsules are less than about 5.0 micrometers in diameter.
Claim 6
Dependent Claim 20 words
The coated product of claim 4 in which said microcapsules are between about 2.0 to about 2.5 micrometers in diameter.
Claim 7
Dependent Claim 22 words
The coated product of claim 1 in which said toner adhesion-enhancing composition is coated only on selected portions of said cellulosic web.
Claim 8
Dependent Claim 25 words
The coated product of claim 1 in which said toner adhesion-enhancing composition is applied at a coating weight of between about 0.3 and 1.0 lb/ream.
Claim 9
Dependent Claim 14 words
The coated product of claim 1 in which said coating further includes a plasticizer.
Claim 10
Dependent Claim 29 words
The coated product of claim 8 in which said plasticizer comprises a phthalate ester in an amount of less than about 10% by weight of said toner adhesion-enhancing composition.
Claim 11
Dependent Claim 88 words
A security document having enhanced toner adhesion characteristics for printing with a noncontact printing device comprising a cellulosic web having first and second major surfaces, at least one of said major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a cross-linked copolymer formed from a mixture of a dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer.
Claim 12
Dependent Claim 88 words
A security document having enhanced toner adhesion characteristics for printing with a noncontact printing device comprising a cellulosic web having first and second major surfaces, at least one of said major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a cross-linked copolymer formed from a mixture of a dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer.
Claim 13
Dependent Claim 16 words
The security document of claim 10 in which said toner adhesion-enhancing composition includes a coloring agent.
Claim 14
Dependent Claim 20 words
The security document of claim 11 in which said coloring agent is a dye contained in a plurality of microcapsules.
Claim 15
Dependent Claim 18 words
The security document of claim 12 in which said microcapsules are less than about 5.0 micrometers in diameter.
Claim 16
Dependent Claim 20 words
The security document of claim 13 in which said microcapsules are between about 2.0 to about 2.5 micrometers in diameter.
Claim 17
Dependent Claim 31 words
The security document of claim 10 in which said toner adhesion-enhancing composition is coated only on selected portions of said cellulosic web where MICR code, payee, and/or amount information is printed.
Claim 18
Dependent Claim 25 words
The security document of claim 10 in which said toner adhesion-enhancing composition is applied at a coating weight of between about 0.3 and 1.0 lb/ream.
Claim 19
Dependent Claim 14 words
The security document of claim 10 in which said coating further includes a plasticizer.
Claim 20
Dependent Claim 29 words
The security document of claim 17 in which said plasticizer comprises a phthalate ester in an amount of less than about 10% by weight of said toner adhesion-enhancing composition.
Claim 21
Independent Claim 125 words
A method of printing a document using a noncontact printing device comprising the steps of forming a latent image of said document on an imaging drum, applying a toner to said latent image, transferring said latent image to a surface of a cellulosic web product having coated thereon a polymeric toner adhesion-enhancing composition comprising a mixture of a dispersion of copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer, said adhesion-enhancing composition having been dried to form a cross-linked copolymer, and thereafter fusing said toner to said surface of said cellulosic product by the application of heat and pressure.
Claim 22
Independent Claim 125 words
A method of printing a document using a noncontact printing device comprising the steps of forming a latent image of said document on an imaging drum, applying a toner to said latent image, transferring said latent image to a surface of a cellulosic web product having coated thereon a polymeric toner adhesion-enhancing composition comprising a mixture of a dispersion of copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. and about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer, said adhesion-enhancing composition having been dried to form a cross-linked copolymer, and thereafter fusing said toner to said surface of said cellulosic product by the application of heat and pressure.
Claim 23
Dependent Claim 15 words
The method of claim 19 in which said toner adhesion-enhancing composition includes a coloring agent.
Claim 24
Dependent Claim 30 words
The method of claim 19 in which said toner adhesion-enhancing composition is coated only on selected portions of said cellulosic web where MICR code, payee, and/or amount information is printed.
Claim 25
Dependent Claim 24 words
The method of claim 19 in which said toner adhesion-enhancing composition is applied at a coating weight of between about 0.3 and 1.0 lb/ream.
Claim 26
Dependent Claim 13 words
The method of claim 19 in which said coating further includes a plasticizer.
Claim 27
Dependent Claim 28 words
The method of claim 23 in which said plasticizer comprises a phthalate ester in an amount of less than about 10% by weight of said toner adhesion-enhancing composition.
Claim 28
Independent Claim 97 words
A method for making a toner adhesion-enhancing coated cellulosic product comprising a cellulosic web having first and second major surfaces, by coating on at least one of said major surfaces a polymeric toner adhesion-enhancing composition, wherein said adhesion-enhancing composition is formed by mixing an aqueous dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. with a zinc oxide ammonia cross-linking agent complex-contained in an aqueous alkaline solution, and drying said adhesion-enhancing composition which has been coated on said surface to form a cross-linked copolymer.
Claim 29
Independent Claim 97 words
A method for making a toner adhesion-enhancing coated cellulosic product comprising a cellulosic web having first and second major surfaces, by coating on at least one of said major surfaces a polymeric toner adhesion-enhancing composition, wherein said adhesion-enhancing composition is formed by mixing an aqueous dispersion of a copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C. with a zinc oxide ammonia cross-linking agent complex-contained in an aqueous alkaline solution, and drying said adhesion-enhancing composition which has been coated on said surface to form a cross-linked copolymer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-09-02 1995-03-04 1995-09-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-09-02 1999-03-04 1999-09-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-09-02 2003-03-04 2003-09-03 $7700.00 Window Closed / Lapsed

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