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US4337305A Expired / Lapsed US ⏱️ 0.0 years remaining

Sensitized organic electron donor compounds

Assignee: 3M Co
•
Filing: 1981-02-23
•
Granted: 1982-06-29
•
Expires: 2001-02-23
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Abstract

Abstract Organic electron donor compounds for use in electrophotographic constructions must ordinarily be sensitized to desired regions of the electromagnetic spectrum. Indolenine dyes having phenylsulfonyl or benzoyl substituents thereon have been found to be efficient sensitizers, particularly in the infrared portion of the electromagnetic spectrum, for such organic donor compounds.

Inventors

  • 👤 Paolo Beretta
  • 👤 Louis M. Leichter
  • 👤 John J. Stofko, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:58
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/09

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 30 words
A photosensitive material comprising an organic electronically active donor compound sensitized with a sensitizing amount of an indolenine cyanine dye bearing a phenylsulfonyl or benzoyl substituent on the 5-position thereof.
Claim 2
Dependent Claim 30 words
A photosensitive material comprising an organic electronically active donor compound sensitized with a sensitizing amount of an indolenine cyanine dye bearing a phenylsulfonyl or benzoyl substituent on the 5-position thereof.
Claim 3
Dependent Claim 17 words
A layer of the photosensitive material of claim 1 wherein said donor compound is a polyvinyl carbazole.
Claim 4
Dependent Claim 27 words
A layer of the photosensitive material of claim 1 wherein said donor compound is present as at least 20% by weight in an electronically inactive polymeric binder.
Claim 5
Dependent Claim 42 words
A layer of the photosensitive material of claim 1 wherein said donor compound is a benzocarbazole derivative of the formula where X is ##STR12## wherein R and Y are independently selected from the group consisting of aliphatic, aromatic, and mixed aliphatic-aromatic groups.
Claim 6
Dependent Claim 162 words
The layers of claims 2, 3 or 4 in which said indolenine dye is represented by any of the formulae: ##STR13## wherein A is selected from ##STR14## n is a positive integer of 1 to 4, m and q each represents a positive integer of 1 to 2, p represents a positive integer of 1 to 3, r is 0 or 1, R 2 represents an acyclic hydrocarbon, R 1 is a 5-position phenylsulfonyl or benzoyl substituent, R 5 and R 6 are an aliphatic group, R 3 and R 4 represent the same or different alkyl groups of 1-6 carbon atoms, R 7 is selected from the group consisting of H, halogen, cyano, alkyl, alkoxy, phenoxy, aryl, amino, thiophenyl, and thioalkyl, Z represents the non-metallic atoms required to complete a heterocyclic nucleus of 5 to 6 ring atoms, Q represents the non-metallic atoms required to complete a heterocyclic nucleus of 5 to 6 ring atoms, and X represents an acid anion.
Claim 7
Dependent Claim 74 words
The layer of claims 2, 3, or 4 in which said indolenine dye is represented by the formula: ##STR15## wherein, n is 1, r is 1, R 2 is an aliphatic group of 1 to 13 carbon atoms, R 1 is phenylsulfonyl or benzoyl, R 3 and R 4 are selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl and hexyl, R 7 is halogen, and X - is an acid anion.
Claim 8
Dependent Claim 93 words
The layer of claims 2, 3, or 4 in which said indolenine dye is represented by the formula: ##STR16## wherein A is selected from ##STR17## r is 1, n is 1, R 2 is an aliphatic group of 1 to 13 carbon atoms, R 1 is a phenylsulfonyl or benzoyl group, R 3 and R 4 are selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, and hexyl, R 5 and R 6 are alkyl of 1 to 6 carbon atoms, R 7 is halogen, and X is an acid anion.
Claim 9
Dependent Claim 15 words
An electrophotographic element comprising, in sequence, a conductive substrate and the layer of claim 5.

References Cited (Backward Citations)

US4264694A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-28 1985-12-28 1986-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-28 1989-12-28 1990-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-28 1993-12-28 1994-06-29 $7700.00 Window Closed / Lapsed

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