Thermosetting resin composition, printed circuit board using the resin composition and process for producing printed circuit board

Claim 2

A printed circuit board, which comprises a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR26## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR27## m is an integer of 1 to 4 and n is an integer of 5 to 100; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 3

A printed circuit board, which comprises a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR28## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR29## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 4

A printed circuit board, which comprises a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR28## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR29## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 5

A multi-layered, printed circuit board, which comprises a lamination of a plurality of printed circuit boards each comprising a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I) A--R.sub.1 A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR30## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR31## m is an integer of 1 to 4 and n is an integer of 5 to 100, or printed circuit boards each comprising a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR32## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR33## is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 6

A multi-layered, printed circuit board, which comprises a lamination of a plurality of printed circuit boards each comprising a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I) A--R.sub.1 A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR30## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR31## m is an integer of 1 to 4 and n is an integer of 5 to 100, or printed circuit boards each comprising a conductor of a metallic foil and an insulating layer made of a fibrous substrate material impregnated and cured with a thermosetting resin composition, the thermosetting resin composition comprising a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR32## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR33## is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 7

A curable material which comprises a woven fabric or non-woven fabric of inorganic fibers or organic fibers, impregnated with a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR34## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR35## m is an integer of 1 to 4 and n is an integer of 5 to 100 or a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR36## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR37## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 8

A curable material which comprises a woven fabric or non-woven fabric of inorganic fibers or organic fibers, impregnated with a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR34## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR35## m is an integer of 1 to 4 and n is an integer of 5 to 100 or a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR36## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR37## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 9

A thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR38## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR39## m is an integer of 1 to 4 and n is an integer of 5 to 100; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 10

A thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR38## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR39## m is an integer of 1 to 4 and n is an integer of 5 to 100; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 11

A thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR40## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR41## is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated amido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 12

A thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR40## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR41## is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated amido group; a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight.

Claim 13

A process for producing a printed circuit board, which comprises: a step of heating a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR42## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR43## m is an integer of 1 to 4 and n is an integer of 5 to 100, thereby forming a prepolymer, a mixing ratio of the cyanate compound of isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight; a step of dissolving the prepolymer in a solvent, thereby forming an impregnation varnish, impregnating a fibrous substrate material with the impregnation varnish, followed by drying, thereby preparing a prepreg; and a step of laminating a plurality of the thus obtained prepregs, thereby obtaining a laminate, and pressing the laminate together with conductor metal foils with heating.

Claim 14

A process for producing a printed circuit board, which comprises: a step of heating a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR42## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR43## m is an integer of 1 to 4 and n is an integer of 5 to 100, thereby forming a prepolymer, a mixing ratio of the cyanate compound of isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight; a step of dissolving the prepolymer in a solvent, thereby forming an impregnation varnish, impregnating a fibrous substrate material with the impregnation varnish, followed by drying, thereby preparing a prepreg; and a step of laminating a plurality of the thus obtained prepregs, thereby obtaining a laminate, and pressing the laminate together with conductor metal foils with heating.

Claim 15

A process for producing a printed circuit board, which comprises: a step of heating a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR44## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR45## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group, thereby forming a prepolymer, a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight; a step of dissolving the prepolymer in a solvent, thereby forming an impregnation varnish, impregnating a fibrous substrate material with the impregnation varnish, followed by drying, thereby preparing a prepreg; and a step of laminating a plurality of the thus obtained prepregs, thereby obtaining a laminate, and pressing the laminate together with conductor metal foils with heating.

Claim 16

A process for producing a printed circuit board, which comprises: a step of heating a thermosetting resin composition which comprises a cyanate compound or an isocyanate compound represented by the following general formula (I): A--R.sub.1 --A (I) wherein R 1 is an aromatic group, an alicyclic group or a mixed group thereof and A is a cyanate group or an isocyanate group, and a poly-(p-hydroxystyrene) derivative represented by the following general formula (II): ##STR44## wherein X is a fluorine atom, a bromine atom or a chlorine atom, R 2 is an alkenyl group and an unsaturated carboxyl group, each having 2 to 4 carbon atoms, B is any one of a polymerization initiator residue, a polymerization-terminating agent residue, H and ##STR45## m is an integer of 1 to 4 and n is an integer of 5 to 100 and a compound having at least one N-substituted unsaturated imido group, thereby forming a prepolymer, a mixing ratio of the cyanate compound or isocyanate compound represented by the general formula (I) to the poly-(p-hydroxystyrene) derivative represented by the general formula (II) is in the range of 20:80 to 80:20 by weight; a step of dissolving the prepolymer in a solvent, thereby forming an impregnation varnish, impregnating a fibrous substrate material with the impregnation varnish, followed by drying, thereby preparing a prepreg; and a step of laminating a plurality of the thus obtained prepregs, thereby obtaining a laminate, and pressing the laminate together with conductor metal foils with heating.