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US5039759A Expired / Lapsed US ⏱️ 0.0 years remaining

Water borne high solids coating compositions

Assignee: Union Carbide Chemicals and Plastics Technology LLC
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Filing: 1985-08-01
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Granted: 1991-08-13
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Expires: 2005-08-01
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Abstract

Abstract Water borne high solids coating compositions are made by blending a water-dispersible, crosslinkable organic polymer free of amide groups, water, at least one reactive urea derivative, a crosslinking agent and optionally a crosslinking catalyst. Optionally a mixture of reactive urea and carbamate derivatives can be used. The resultant water borne high solids coating compositions can be either solutions or dispersions depending upon the particular polymer and reactive urea or carbamate chosen as the reactive cosolvent or reactive diluent.

Inventors

  • 👤 Kenneth L. Hoy
  • 👤 Forrest A. Richey, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:07
CPC Classifications
C; C09; C09D; C09D167/00; C09D5/00; C09D5/02; C09D5/024; C09D7/00; C09D7/20

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 257 words
Method of making water-borne high solids coating compositions which comprises blending: (A) at least one water borne organic polymer free of amide groups which is interpolymerzable with reactive urea derivatives and crosslinking agents; (B) water; (C) at least one reactive urea derivative having the generic formula: ##STR3## wherein each of R 1 , R 2 , R 3 and R 4 is a monovalent radical selected from the class consisting of hydrogen, alkyl groups having 1 to about 10 carbon atoms, hydroxyalkyl groups having 2 to about 4 carbon atoms and one or more hydroxyl groups, hydroxyalkyleneoxy groups having one or more hydroxyl groups and hydroxypolyalkyleneoxy groups having one or more hydroxyl groups and with the provisos that: (i) said urea contains at least one --NH and one --OH group or at least two --OH groups or at least two --NH groups; (ii) R 1 and R 2 or R 1 and R 3 can be linked to form a ring structure; and (iii) R 1 , R 2 , R 3 and R 4 are never all hydrogen at the same time; (D) a cross-linking amount of a cross-linking agent selected from the group consisting of a water-soluble polyepoxide, a water-dispersible polyepoxide, and a water-dispersible aminoplast; wherein for an aqueous dispersion coating the reactive urea derivative/water ratio is in the range of about 5 to 95 to about 30 to 70 and for an aqueous solution coating the reactive urea derivative/water ratio is in the range of about 20 to 80 to about 60 to 40.
Claim 2
Dependent Claim 257 words
Method of making water-borne high solids coating compositions which comprises blending: (A) at least one water borne organic polymer free of amide groups which is interpolymerzable with reactive urea derivatives and crosslinking agents; (B) water; (C) at least one reactive urea derivative having the generic formula: ##STR3## wherein each of R 1 , R 2 , R 3 and R 4 is a monovalent radical selected from the class consisting of hydrogen, alkyl groups having 1 to about 10 carbon atoms, hydroxyalkyl groups having 2 to about 4 carbon atoms and one or more hydroxyl groups, hydroxyalkyleneoxy groups having one or more hydroxyl groups and hydroxypolyalkyleneoxy groups having one or more hydroxyl groups and with the provisos that: (i) said urea contains at least one --NH and one --OH group or at least two --OH groups or at least two --NH groups; (ii) R 1 and R 2 or R 1 and R 3 can be linked to form a ring structure; and (iii) R 1 , R 2 , R 3 and R 4 are never all hydrogen at the same time; (D) a cross-linking amount of a cross-linking agent selected from the group consisting of a water-soluble polyepoxide, a water-dispersible polyepoxide, and a water-dispersible aminoplast; wherein for an aqueous dispersion coating the reactive urea derivative/water ratio is in the range of about 5 to 95 to about 30 to 70 and for an aqueous solution coating the reactive urea derivative/water ratio is in the range of about 20 to 80 to about 60 to 40.
Claim 3
Dependent Claim 27 words
Method claimed in claim 1 wherein R 1 is 2-hydroxyethyl, R 2 and R 3 are linked to form an ethylene bridge and R 4 is hydrogen.
Claim 4
Dependent Claim 22 words
Method claimed in claim 1 wherein R 1 and R 3 are hydrogen, R 2 is butyl and R 4 is hydroxyethyl.
Claim 5
Dependent Claim 23 words
Method claimed in claim 1 wherein R 1 and R 3 are each hydrogen, R 2 is methyl and R 4 is butyl.
Claim 6
Dependent Claim 23 words
Method claimed in claim 1 wherein R 1 and R 3 are each hydrogen, R 2 is propyl and R 4 is butyl.
Claim 7
Dependent Claim 23 words
Method claimed in claim 1 wherein R 1 and R 3 are each 2-hydroxyethyl, R 2 is ethyl and R 4 is hydrogen.
Claim 8
Dependent Claim 14 words
Method claimed in claim 1 wherein the organic polymer is a polyester alkyd resin.
Claim 9
Dependent Claim 18 words
Method claimed in claim 1 wherein the organic polymer is a carboxylated, hydroxyl containing epoxy fatty acid ester.
Claim 10
Dependent Claim 13 words
Method claimed in claim 1 wherein the organic polymer is a carboxylated polyester.
Claim 11
Dependent Claim 14 words
Method claimed in claim 1 wherein the organic polymer is a carboxylated alkyd resin.
Claim 12
Dependent Claim 14 words
Method claimed in claim 1 wherein the organic polymer is a carboxylated acrylic interpolymer.
Claim 13
Dependent Claim 15 words
Method claimed in claim 1 wherein the organic polymer is a homogeneously dispersed acrylic interpolymer.
Claim 14
Dependent Claim 14 words
Method claimed in claim 1 wherein the organic polymer is a carboxylated vinyl interpolymer.
Claim 15
Dependent Claim 10 words
Coating composition made by the method claimed in claim 1.
Claim 16
Dependent Claim 17 words
The method of claim 1 wherein the coating composition includes a catalytic amount of a cross-linking catalyst.
Claim 17
Dependent Claim 17 words
Method claimed in claim 1 wherein said water-borne, cross-linkable organic polymer is a water dispersible organic polymer.
Claim 18
Dependent Claim 17 words
Method claimed in claim 1 wherein said water-borne, cross-linkable organic polymer is a water soluble organic polymer.
Claim 19
Dependent Claim 75 words
Method claimed in claim 1 wherein the cross-linkable organic polymer free of amide groups is present in an amount of about 15 to 50 percent by weight, water is present in an amount of about 5 to 60 percent by weight, said reactive urea derivative is present in an amount of about 5 to 20 percent by weight and said crosslinking agent is present in an amount of about 5 to 30 percent by weight.
Claim 20
Dependent Claim 9 words
Coating composition made by the method of claim 2.
Claim 21
Dependent Claim 9 words
Coating composition made by the method of claim 7.

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