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US4314918A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating compositions containing organic alcoholic reactive diluents

Assignee: PPG Industries Ohio Inc
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Filing: 1980-06-26
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Granted: 1982-02-09
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Expires: 2000-06-26
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Abstract

Abstract Reactive diluents are derived from the reaction of a glycidyl ester and a hydroxyl and/or carboxyl functional compound. The diluents are useful in coating compositions together with crosslinking agents and, optionally, polyols.

Inventors

  • 👤 William J. Birkmeyer
  • 👤 Ronald J. Lewarchik
  • 👤 Joseph A. Klanica
  • 👤 Carl C. Anderson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 23:16
CPC Classifications
C; C09; C09D; C09D201/00

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 161 words
A coating composition capable of liquid application to a substrate, the vehicle portion of the composition, on a weight solids basis, consisting essentially of: (a) from about 35% to about 55% of a crosslinking agent; (b) from about 15% to about 50% of a curable polyol resin; and (c) from about 15% to about 50% of a reactive diluent derived from the reaction of (i) from about 0.25 to about 4 moles of a glycidyl ester with (ii) each mole of a functional material having a molecular weight of less than about 1000, a hydroxy equivalent weight of from about 30 to about 1000 and a carboxy equivalent weight of from about 50 to about 1000, provided the total hydroxyl and carboxyl functionality of the functional material is at least 2.0, said reactive diluent characterized in having an acid number of less than about 50, a non-volatile content of greater than about 85% and a Gardner-Holdt viscosity of less than Z-10.
Claim 2
Dependent Claim 161 words
A coating composition capable of liquid application to a substrate, the vehicle portion of the composition, on a weight solids basis, consisting essentially of: (a) from about 35% to about 55% of a crosslinking agent; (b) from about 15% to about 50% of a curable polyol resin; and (c) from about 15% to about 50% of a reactive diluent derived from the reaction of (i) from about 0.25 to about 4 moles of a glycidyl ester with (ii) each mole of a functional material having a molecular weight of less than about 1000, a hydroxy equivalent weight of from about 30 to about 1000 and a carboxy equivalent weight of from about 50 to about 1000, provided the total hydroxyl and carboxyl functionality of the functional material is at least 2.0, said reactive diluent characterized in having an acid number of less than about 50, a non-volatile content of greater than about 85% and a Gardner-Holdt viscosity of less than Z-10.
Claim 3
Dependent Claim 20 words
The composition of claim 1 wherein the functional material has a molecular weight of from about 60 to about 500.
Claim 4
Dependent Claim 20 words
The composition of claim 2 wherein the functional material has a molecular weight of from about 100 to about 300.
Claim 5
Dependent Claim 34 words
The composition of claim 2 wherein the functional material has from 0 to 10 hydroxyl groups, from about 0 to 10 carboxyl groups and a total hydroxyl and carboxyl functionality of at least 2.0.
Claim 6
Dependent Claim 33 words
The composition of claim 3 wherein the functional material has from 0 to 3 hydroxyl groups, from 0 to 3 carboxyl groups and a total hydroxyl and carboxyl functionality of at least 2.0.
Claim 7
Dependent Claim 46 words
The composition of claim 4 wherein the functional material used in making the reactive diluent is a polyhydric compound having 2 to 4 hydroxyl groups, a dicarboxylic acid or anhydride thereof or a compound having at least one hydroxyl group and at least one carboxyl group.
Claim 8
Dependent Claim 28 words
The composition of claims 1 or 6 wherein the glycidyl ester has the formula: ##STR6## where R is a hydrocarbon group having from 1 to 17 carbon atoms.
Claim 9
Dependent Claim 35 words
The composition of claim 7 wherein the functional material reacted with the glycidyl ester is selected from the group consisting of neopentyl glycol; dimethylolpropionic acid; 2,2-dimethyl-3-hydroxypropyl-2,2-dimethyl-3-hydroxypropionate; 12-hydroxystearic acid; adipic acid; hexahydrophthalic acid; and mixtures thereof.
Claim 10
Dependent Claim 26 words
The composition of claim 7 wherein the reactive diluent has a non-volatile content of greater than about 90% and a Gardner-Holdt viscosity of less than Z-8.
Claim 11
Dependent Claim 20 words
The composition of claim 8 wherein the hydrocarbon group in the glycidyl ester has from 4 to 12 carbon atoms.
Claim 12
Dependent Claim 40 words
The composition of claim 1 wherein the polyol is selected from the group consisting of a hydrocarbon polyol, ester polyol, ether polyol polyester polyol, polyether polyol, polyamide polyol, polyurethane polyol, polyurea polyol, cyclic nitrogen-containing polyol, acrylic polyol and mixtures thereof.
Claim 13
Dependent Claim 28 words
The composition of claim 11 wherein the polyol has a hydroxyl equivalent weight of from about 30 to about 2000 and a hydroxyl functionality of at least 2.0.
Claim 14
Dependent Claim 27 words
The composition of claim 11 wherein the crosslinking agent is selected from the group consisting of an aminoplast resin, phenoplast resin, isocyanate blocked isocyanate and mixtures thereof.
Claim 15
Dependent Claim 13 words
The composition of claim 11 wherein the crosslinking agent is an aminoplast resin.
Claim 16
Dependent Claim 25 words
The composition of claim 7 wherein about 1 to about 3 moles of the glycidyl ester is reacted with each mole of the functional compound.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-08 1985-08-10 1986-02-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-08 1989-08-10 1990-02-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-08 1993-08-10 1994-02-09 $7700.00 Window Closed / Lapsed

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