US4005041A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Air-drying or heat-curable polyurethane coating compositions
Assignee: Prolux Paint Manufacturing Ltd Pty
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Filing: 1975-06-24
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Granted: 1977-01-25
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Expires: 1995-06-24
Abstract
Abstract Air-drying or heat-curable coating compositions are based on allyl ether group-containing isocyanate adducts which are obtained by reacting isophorone diisocyanate with a polyhydroxy compound to give an intermediate containing free isocyanate groups, and then condensing the intermediate with an hydroxyl group-containing allyl ether of an aliphatic diol or polyol.
Inventors
- 👤 Kenneth Elliot Piggott
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 10:10
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; C08G18/6715; C08G18/675
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
84 words
A process for the production of allyl ether group-containing isocyanate adducts useful in coating compositions, comprising reacting isophorone diisocyanate in the presence of a catalyst with a polyhydroxy compound in the proportion of substantially one mole of the diisocyanate to each hydroxyl group, and then condensing the product so obtained with an hydroxyl group-containing allyl ether of an aliphatic diol or polyol in an amount such that substantially one hydroxyl group in the allyl ether is used for each unreacted isocyanate in said product.
Claim 2
Dependent Claim
84 words
A process for the production of allyl ether group-containing isocyanate adducts useful in coating compositions, comprising reacting isophorone diisocyanate in the presence of a catalyst with a polyhydroxy compound in the proportion of substantially one mole of the diisocyanate to each hydroxyl group, and then condensing the product so obtained with an hydroxyl group-containing allyl ether of an aliphatic diol or polyol in an amount such that substantially one hydroxyl group in the allyl ether is used for each unreacted isocyanate in said product.
Claim 3
Dependent Claim
24 words
A process as claimed in claim 1, wherein the polyhydroxy compound is formed by the reaction of a polybasic acid with an epoxy compound.
Claim 4
Dependent Claim
34 words
A process as claimed in claim 2, wherein the polybasic acid is the product of reaction of one mole of a polyol and at least two moles of an aliphatic or aromatic carboxylic anhydride.
Claim 5
Dependent Claim
27 words
A process as claimed in claim 2, wherein the epoxy compound is a glycidester having the general formula: ##STR6##where R is the residue of an organic acid.
Claim 6
Dependent Claim
51 words
A process as claimed in claim 4, wherein the group R in the glycidester is a branched chain grouping of the formula ##STR7## where R 1 and R 3 are hydrogen atoms or methyl groups and R 2 is a straight-chain aliphatic hydrocarbon residue containing between 1 and 11 carbon atoms.
Claim 7
Dependent Claim
31 words
A process as claimed in claim 2 wherein the polyhydroxy compound formed from the polybasic acid and the epoxy compound is blended with another polyhydroxy compound before reaction with the diisocyanate.
Claim 8
Dependent Claim
29 words
A process as claimed in claim 1 wherein the hydroxyl group-containing allyl ether is allyloxyisopropanol, trimethylol propane diallyl ether, trimethylolpropane monoallyl ether, glycerol diallyl ether or pentaerythritol triallyl ether.
Claim 9
Dependent Claim
29 words
A modification of the process as claimed in claim 1, wherein the allyl groups present in the final product are partially polymerised in the presence of a peroxide catalyst.
Claim 10
Dependent Claim
35 words
A process as claimed in claim 1, wherein the polyhydroxy compound is a copolymer of (i) an α.β-ethylenically unsaturated ester containing at least one hydroxyl group and (ii) one or more other ethylenically unsaturated compounds.
Claim 11
Dependent Claim
42 words
A process as claimed in claim 9, wherein the α,β-ethylenically unsaturated ester is the product of reaction of an α,β-ethylenically unsaturated mono- or di-basic carboxylic acid or anhydride, and/or an (oxy) alkyl hemiester of such a dibasic acid, with an epoxy compound.
Claim 12
Dependent Claim
26 words
A process as claimed in claim 10, wherein the epoxy compound is glycidester having the general formula: ##STR8##where R is the residue of an organic acid.
Claim 13
Dependent Claim
50 words
A process as claimed in claim 10, wherein the group R in the glycidester is a branched chain grouping of the formula ##STR9##where R 1 and R 2 are hydrogen atoms or methyl groups and R 2 is a straight-chain aliphatic hydrocarbon residue containing between 1 and 11 carbon atoms.
Claim 14
Dependent Claim
19 words
A process as claimed in claim 9, wherein the other ethylenically unsaturated compound is vinyl toluene or 2-ethylhexyl acrylate.
Claim 15
Dependent Claim
15 words
An allyl ether group-containing isocyanate adduct obtained by a process as claimed in claim 1.
Claim 16
Dependent Claim
23 words
A clear varnish or pigmented coating prepared from an adduct as claimed in claim 14 with the addition of a cobalt soap drier.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-25 | 1980-07-26 | 1981-01-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-25 | 1984-07-26 | 1985-01-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-25 | 1988-07-26 | 1989-01-25 | $7700.00 | Window Closed / Lapsed |