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US5039746A
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Thermoplastic molding compounds based on functionalized polyphenylene ethers and polyamides
Assignee: Huels AG
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Filing: 1989-02-27
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Granted: 1991-08-13
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Expires: 2009-02-27
Abstract
Abstract Thermoplastic molding compounds are prepared from a functionalized polyphenylene ether and a polyamide. The polyphenylene ether is functionalized by the incorporation of a small quantity of a functionalized phenol monomer.
Inventors
- 👤 Wolfgang Neugebauer
- 👤 Martin Bartmann
- 👤 Udo Kowalczik
- 👤 Joachim Mugge
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:20
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08G; C08G65/00; C08G65/34; C08G65/38; C08G65/44; C08G65/48; C08G65/485; C08L77/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
211 words
A thermoplastic molding compound, comprising: (i) 5-90 parts by weight of a polyphenylene ether having the structure: ##STR12## wherein R 1 , R 3 , R 5 and R 7 , independently, are selected from the group consisting of phenyl, benzyl, and C 1-10 straight-chain or branched alkyl groups; or R 1 and R 5 are hydrogen and R 3 and R 7 are a C 4-10 tertiary alkyl group, R 2 , R 4 , R 6 and R 8 are, independently, selected from the group consisting of hydrogen and C 1-10 alkyl groups; n is 10-200; and X is ##STR13## wherein R is a single C--C bond or a C 1--12 divalent aliphatic group and R', R" and R'" are, independently, hydrogen, C 1-10 alkyl groups, or C 1-10 alkyl groups which are substituted with one or more hydroxyl groups; and (ii) 95-10 parts by weight of a polyamide, wherein said polyphenylene ether is prepared by oxidatively coupling a phenol having the structure ##STR14## in the presence of a small quantity of a functionalized phenol having the structure ##STR15## wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and X are as defined above.
Claim 2
Dependent Claim
211 words
A thermoplastic molding compound, comprising: (i) 5-90 parts by weight of a polyphenylene ether having the structure: ##STR12## wherein R 1 , R 3 , R 5 and R 7 , independently, are selected from the group consisting of phenyl, benzyl, and C 1-10 straight-chain or branched alkyl groups; or R 1 and R 5 are hydrogen and R 3 and R 7 are a C 4-10 tertiary alkyl group, R 2 , R 4 , R 6 and R 8 are, independently, selected from the group consisting of hydrogen and C 1-10 alkyl groups; n is 10-200; and X is ##STR13## wherein R is a single C--C bond or a C 1--12 divalent aliphatic group and R', R" and R'" are, independently, hydrogen, C 1-10 alkyl groups, or C 1-10 alkyl groups which are substituted with one or more hydroxyl groups; and (ii) 95-10 parts by weight of a polyamide, wherein said polyphenylene ether is prepared by oxidatively coupling a phenol having the structure ##STR14## in the presence of a small quantity of a functionalized phenol having the structure ##STR15## wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and X are as defined above.
Claim 3
Dependent Claim
36 words
The thermoplastic molding of compound of claim 1, wherein R 1 and R 3 are, independently, a C 1-6 alkyl group, R 2 is hydrogen or a C 1-6 alkyl group, and R 4 is hydrogen.
Claim 4
Dependent Claim
24 words
The thermoplastic molding compound of claim 2, wherein R 1 and R 33 and methyl groups and R 2 and R 4 are hydrogen.
Claim 5
Dependent Claim
24 words
The thermoplastic molding compound of claim 1, wherein R 5 and R 7 are methyl groups and R 6 and R 88 are hydrogen.
Claim 6
Dependent Claim
13 words
The thermoplastic molding compound of claim 1, wherein R is a C--C bond.
Claim 7
Dependent Claim
13 words
The thermoplastic molding compound of claim 1, wherein X is the group ##STR16##
Claim 8
Dependent Claim
24 words
The thermoplastic molding compound of claim 1, wherein said polyphenylene ether has a viscosity number J in the range from 20-80 cm 3 /g.
Claim 9
Dependent Claim
36 words
The thermoplastic molding compound of claim 1, wherein said polyamide is selected from the group consisting of PA 6, PA 46, PA 66, PA 612, PA 1010, PA 1012, PA 11, PA 12 and PA 1212.
Claim 10
Dependent Claim
18 words
The thermoplastic molding compound of claim 1 wherein the numerical average molecular weight of said polyamide exceeds 5,000.
Claim 11
Dependent Claim
18 words
The thermoplastic molding compound of claim 9, wherein the numerical average molecular weight of said polyamide exceeds 10,000.
Claim 12
Dependent Claim
15 words
The thermoplastic molding compound of claim 1, further comprising 2-25 wt.% of a toughening agent.
Claim 13
Dependent Claim
21 words
The thermoplastic molding compound of claim 11, wherein aid toughening agent is a polyoctenylene or an ethylene-propylene-copolymer or an ethylene-propylene-diene terpolymer.
Claim 14
Dependent Claim
19 words
The thermoplastic molding compound of claim 1, wherein said small quantity comprises from about 0.2 to 4 mole %.
Claim 15
Dependent Claim
19 words
The thermoplastic molding compound of claim 1, wherein said small quantity is from about 0.5 to 3.0 mol %.
Claim 16
Dependent Claim
15 words
The thermoplastic molding compound of claim 1, wherein X is an ester or oxazoline group.
Claim 17
Dependent Claim
21 words
The thermoplastic molding compound of claim 1, comprising 10-70 parts by weight of polyphenylene ether and 90-30 parts by weight polyamide.
Claim 18
Dependent Claim
20 words
The thermoplastic molding compound of claim 16, comprising 20-60 parts by weight polyphenylene ether and 80-40 parts by weight polyamide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-08-12 | 1995-02-11 | 1995-08-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-08-12 | 1999-02-11 | 1999-08-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-08-12 | 2003-02-11 | 2003-08-13 | $7700.00 | Window Closed / Lapsed |