Sensor element for determination of concentration of substances

Claim 2

An electro-optical sensor element for determining the concentration of substances contained in gaseous and liquid samples, comprising a carrier layer, a thin-film substrate comprising at least one photosensitive element, a plurality of electrical contacts and at least one area which is transparent to excitation radiation associated with said carrier layer by microelectronic and photolithographic techniques, an indicator layer, and a transparent coupling layer located between said thin-film substrate and said indicator layer, said transparent coupling layer containing a diffraction structure, said indicator layer being produced by microelectronic and photolithographic techniques and comprising at least one indicator substance having optical properties, at least one of the optical properties of said indicator substance changing upon interaction with said substances contained in said gaseous and liquid samples depending on the concentrations of said substances in said gaseous and liquid samples, and wherein said indicator substance of said indicator layer, which is excited by a source of excitation radiation, is in optical contact with said at least one photosensitive element via said transparent coupling layer, said diffraction structure directing said excitation radiation into areas of said indicator layer facing said at least one photosensitive element.

Claim 3

An electro-optical sensor element according to claim 1, wherein said diffraction structure is a periodic lattice structure.

Claim 4

An electro-optical sensor element for determining the concentration of substances contained in gaseous and liquid samples, comprising a carrier layer, a thin film substrate comprising at least one photosensitive element, a plurality of electrical contacts and at least one area which is transparent to excitation radiation associated with said carrier layer by microelectronic and photolithographic techniques, an indicator layer, a transparent coupling layer located between said thin-film substrate and said indicator layer, said indicator layer being produced by microelectronic and photolithographic techniques and comprising at least one indicator substance having optical properties, wherein at least one of the optical properties of said indicator substance will change upon interaction with said substances contained in said gaseous and liquid samples depending on the concentrations of said substances in said gaseous and liquid samples, and wherein said indicator substance of said indicator layer, which is excited by a source of excitation radiation, is in optical contact with said at least one photosensitive element via said transparent coupling layer, and transparent areas positioned in said thin-film substrate at an angle, such that said excitation radiation will strike said indicator layer at an angle a of 40° to 60°, exciting areas of said indicator layer facing said photosensitive elements.

Claim 5

An electro-optical sensor element for determining the concentration of substances contained in gaseous and liquid samples, comprising a carrier layer, a thin film substrate comprising at least one photosensitive element, a plurality of electrical contacts and at least one area which is transparent to excitation radiation associated with said carrier layer by microelectronic and photolithographic techniques, an indicator layer, a transparent coupling layer located between said thin-film substrate and said indicator layer, said indicator layer being produced by microelectronic and photolithographic techniques and comprising at least one indicator substance having optical properties, wherein at least one of the optical properties of said indicator substance will change upon interaction with said substances contained in said gaseous and liquid samples depending on the concentrations of said substances in said gaseous and liquid samples, and wherein said indicator substance of said indicator layer, which is excited by a source of excitation radiation, is in optical contact with said at least one photosensitive element via said transparent coupling layer, and transparent areas positioned in said thin-film substrate at an angle, such that said excitation radiation will strike said indicator layer at an angle a of 40° to 60°, exciting areas of said indicator layer facing said photosensitive elements.

Claim 6

An electro-optical sensor element for determining the concentration of substances contained in gaseous and liquid samples, comprising a carrier layer, a thin film substrate comprising at least one photosensitive element, a plurality of electrical contacts and at least one area which is transparent to excitation radiation associated with said carrier layer by microelectronic and photolithographic techniques, an indicator layer, a transparent coupling layer located between said thin-film substrate and said indicator layer, said indicator layer being produced by microelectronic and photolithographic techniques and comprising at least one indicator substance having optical properties, wherein at least one of the optical properties of said indicator substance will change upon interaction with said substances contained in said gaseous and liquid samples depending on the concentrations of said substances in said gaseous and liquid samples, and wherein said indicator substance of said indicator layer, which is excited by a source of excitation radiation, is in optical contact with said at least one photosensitive element via said transparent coupling layer, and wherein said coupling layer, which has a refractive index n 2 , together with boundary layers situated on both sides of said coupling layer, which have a refractive index n 1 , constitute a planar lightguide for said radiation to be measured, with n 2 >n 1 , wherein said boundary layer adjacent to said sample has at least one recess which is covered by said indicator layer, and wherein each of said recesses, seen in a direction of said excitation radiation, is situated above one of said areas transparent to said excitation radiation, and wherein total reflection of said radiation to be measured is cancelled in areas of said photosensitive elements.

Claim 7

An electro-optical sensor element for determining the concentration of substances contained in gaseous and liquid samples, comprising a carrier layer, a thin film substrate comprising at least one photosensitive element, a plurality of electrical contacts and at least one area which is transparent to excitation radiation associated with said carrier layer by microelectronic and photolithographic techniques, an indicator layer, a transparent coupling layer located between said thin-film substrate and said indicator layer, said indicator layer being produced by microelectronic and photolithographic techniques and comprising at least one indicator substance having optical properties, wherein at least one of the optical properties of said indicator substance will change upon interaction with said substances contained in said gaseous and liquid samples depending on the concentrations of said substances in said gaseous and liquid samples, and wherein said indicator substance of said indicator layer, which is excited by a source of excitation radiation, is in optical contact with said at least one photosensitive element via said transparent coupling layer, and wherein said coupling layer, which has a refractive index n 2 , together with boundary layers situated on both sides of said coupling layer, which have a refractive index n 1 , constitute a planar lightguide for said radiation to be measured, with n 2 >n 1 , wherein said boundary layer adjacent to said sample has at least one recess which is covered by said indicator layer, and wherein each of said recesses, seen in a direction of said excitation radiation, is situated above one of said areas transparent to said excitation radiation, and wherein total reflection of said radiation to be measured is cancelled in areas of said photosensitive elements.

Claim 8

An electro-optical sensor element according to claim 4, with only one of said areas transparent to said excitation radiation and wherein said photosensitive element has an annular structure concentric to said area.

Claim 9

An electro-optical sensor element according to claim 1, 3 or 4, wherein one end of a lightguide extends to said areas transparent to said excitation radiation.

Claim 10

An electro-optical sensor element according to claim 1, 3 or 4, wherein said areas transparent to said excitation radiation are provided with a filter layer.

Claim 11

An electro-optical sensor element according to claim 7, wherein said filter layer is an optical interference filter.

Claim 12

An electro-optical sensor element according to claim 1, 3 or 4, wherein said photosensitive elements are additionally coated with an optical filter layer.

Claim 13

An electro-optical sensor element according to claim 1, 3 or 4, wherein an interference filter is situated between said coupling layer and said indicator layer, which has different transmission coefficients for said excitation radiation and said fluorescent radiation emitted by said indicator substance.

Claim 14

An electro-optical sensor element according to claim 1, 3 or 4, wherein said indicator layer is provided with microareas corresponding to individual photosensitive elements and containing different indicators.

Claim 15

An electro-optical sensor element according to claim 1, 3 or 4, wherein said indicator layer is made of porous glass containing said indicator in an immobilized form.

Claim 16

An electro-optical sensor element according to claim 1, 3 or 4, wherein said indicator layer is a silicone film which is applied by spinning or rolling, and in which said indicator is contained.

Claim 17

An electro-optical sensor element according to claim 1, 3 or 4, wherein indicator molecules of said indicator substance are chemically bonded to said transparent coupling layer.

Claim 18

An electro-optical sensor element according to claim 1, 3 or 4, wherein said indicator substances are deposited by techniques such as micro-screenprinting or evaporation coating.

Claim 19

An electro-optical sensor element according to claim 1, 3 or 4, wherein electronic circuits are integrated on said carrier layer, said circuits being designed for amplifying electric signals produced by said photosensitive elements.

Claim 20

An electro-optical sensor element according to claim 16, wherein said carrier layer is provided with highly integrated electronic circuits for signal evaluation tasks.

Claim 21

An electro-optical sensor element according to claim 1, 3 or 4, wherein said microelectronic and photolithographic techniques comprise evaporation coating, sputtering, spinning, etching and ion beam erosion.