US5039461A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for making balloon
Assignee: Okamoto Industries Inc
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Filing: 1989-09-25
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Granted: 1991-08-13
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Expires: 2009-09-25
Abstract
Abstract This invention relates more particularly to a process for making a balloon to be used with an endoscope in which, according to the present invention, the balloon is processed of a basic material solution including a natural rubber latex or synthetic rubber latex to which is added a sensitizer to radiation cross-linking so as to act and accelerate its cross-linking effect by irradiating ionizing radiations such as gamma (γ) rays utilizing a Co-60 source upon the rubber latex mixed with the sensitizer to radiation cross-linking, which is characterized in that such the balloon can be provided without any vulcanizing process as in the conventional, process. Nevertheless the balloon is still given various excellent properties such as transparency, inflatability, tensile strength with a high elasticity in which these properties have uncomparative advantages against any conventional type balloon which had problems caused by in its inferior transparency caused by addition of vulcanizing agent and the like into the basic latex, or increased thickness of the balloon's thin film with lower content of vulcanizing agent in order to secure the transparency and prevent inferior tensile strength due to the lower content of vulcanizing agent.
Inventors
- 👤 Kyogo Tsushima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 18:01
CPC Classifications
C; C08; C08F; C08F291/00; C08F291/02; B; B29; B29C; B29C35/00; B29C35/02; B29C35/08; B29C41/00; B29C41/02; B29C41/14; B29C35/0805; B29C2035/0844; B29C2035/085; B29C35/0866; B29K; B29K2021/00; B29L; B29L2022/00; B29L2022/02; B29L2022/022; B29L2031/00; B29L2031/753
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
199 words
A process for making a balloon comprising the steps of: (a) providing a member selected from the group consisting of a natural rubber latex and a synthetic rubber latex as a basic material; (b) providing an amount of a monofunctional monomer containing one polymerizable unsaturated C═C bond sensitizer to radiation cross-linking for adding into said basic material to compose a mixture with said basic material; (c) adding said sensitizer into said basic material; (d) irradiating said mixture with an ionizing radiation selected from the group consisting of alpha-rays, beta-rays, gamma-rays, X-rays, and electron beams for exciting said cross-linking action catalyzingly supported by said sensitizer within a composition of said mixture, wherein a main raw material is composed; and (e) forming said balloon having a shape with an inflatable portion incorporated with the end of its fixing portion, which is processed by dipping a former into said main raw material so as to form said shape made of a thin film adhered around said former thereon, drying said thin film together with said former for solidying said film after drawn up from said main raw material solution thereby, stripping said solidified film from said former, whereby said balloon is obtained.
Claim 2
Dependent Claim
199 words
A process for making a balloon comprising the steps of: (a) providing a member selected from the group consisting of a natural rubber latex and a synthetic rubber latex as a basic material; (b) providing an amount of a monofunctional monomer containing one polymerizable unsaturated C═C bond sensitizer to radiation cross-linking for adding into said basic material to compose a mixture with said basic material; (c) adding said sensitizer into said basic material; (d) irradiating said mixture with an ionizing radiation selected from the group consisting of alpha-rays, beta-rays, gamma-rays, X-rays, and electron beams for exciting said cross-linking action catalyzingly supported by said sensitizer within a composition of said mixture, wherein a main raw material is composed; and (e) forming said balloon having a shape with an inflatable portion incorporated with the end of its fixing portion, which is processed by dipping a former into said main raw material so as to form said shape made of a thin film adhered around said former thereon, drying said thin film together with said former for solidying said film after drawn up from said main raw material solution thereby, stripping said solidified film from said former, whereby said balloon is obtained.
Claim 3
Dependent Claim
125 words
A process for making a balloon for an endoscope comprising the steps of: (a) providing a latex selected from the group consisting of natural and synthetic latexes; (b) adding to said latex a monofunctional monomer containing one polymerizable unsaturated C═C bond sensitizer to radiation cross-linking to provide a mixture; (c) irradiating said mixture with ionizing radiation selected from the group consisting of alpha-rays, beta-rays, gamma-rays, X-rays, and electron beams to provide a cross-linked mixture; (d) dipping into said cross-linked mixture a former having the shape of the balloon to be formed; (e) removing said former with a think film of cross-linked latex from said mixture; (f) solidifying said thin film by drying; and (g) stripping said solidified film from said former to obtain said balloon.
Claim 4
Dependent Claim
125 words
A process for making a balloon for an endoscope comprising the steps of: (a) providing a latex selected from the group consisting of natural and synthetic latexes; (b) adding to said latex a monofunctional monomer containing one polymerizable unsaturated C═C bond sensitizer to radiation cross-linking to provide a mixture; (c) irradiating said mixture with ionizing radiation selected from the group consisting of alpha-rays, beta-rays, gamma-rays, X-rays, and electron beams to provide a cross-linked mixture; (d) dipping into said cross-linked mixture a former having the shape of the balloon to be formed; (e) removing said former with a think film of cross-linked latex from said mixture; (f) solidifying said thin film by drying; and (g) stripping said solidified film from said former to obtain said balloon.
Claim 5
Dependent Claim
32 words
The process of claim 2 comprising the additional steps of: (a) leaching said balloon in a dilute alkaline solution; (b) treating said balloon to prevent adhesion; and (c) again drying said balloon.
Claim 6
Dependent Claim
22 words
The process of claim 3 wherein the alkaline material is selected from the group consisting of ammonia, sodium hydroxide, and potassium hydroxide.
Claim 7
Dependent Claim
21 words
The process of claim 2 wherein an anti-oxidant is added to the mixture following cross-linking, but before dipping of said former.
Claim 8
Dependent Claim
23 words
The process of claim 5 wherein the amount of antioxidant is from 0.5 part to 2.0 parts per 100 parts of the latex.
Claim 9
Dependent Claim
21 words
The process of claim 2 wherein the amount of sensitizer is from 1 to 20 parts per 100 parts of latex.
Claim 10
Dependent Claim
21 words
The process of claim 7 wherein the amount of sensitizer is from 2 to 10 parts per 100 parts of latex.
Claim 11
Dependent Claim
17 words
The process of claim 2 wherein the amount of radiation employed is from 0.5 to 10 megarads.
Claim 12
Dependent Claim
16 words
The process of claim 9 wherein the amount of radiation is from 1.0 to 8 megarads.
Claim 13
Dependent Claim
12 words
The process of claim 2 wherein the latex is formed from polyisoprene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-08-12 | 1995-02-11 | 1995-08-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-08-12 | 1999-02-11 | 1999-08-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-08-12 | 2003-02-11 | 2003-08-13 | $7700.00 | Window Closed / Lapsed |