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US5034449A Expired / Lapsed US ⏱️ 0.0 years remaining

Moldable polyblends of polyolefins and styrenic resins

Assignee: Lyondell Chemical Technology LP
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Filing: 1989-09-11
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Granted: 1991-07-23
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Expires: 2009-09-11
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Abstract

Abstract A polyblend composition containing an olefin polymer, a rubber-modified styrenic resin, and a block copolymer compatibilizer is disclosed. In a preferred embodiment, a crystalline propylene polymer, a styrene/maleic anhydride random thermoplastic copolymer modified with a grafted styrene/butadiene rubber, and a hydrogenated styrene/butadiene block copolymer are intimately mixed to form a useful thermoplastic polyblend.

Inventors

  • 👤 Ramesh Mallikarjun

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 04:37
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08L23/14; C08L51/00; C08L51/06; C08L53/00; C08L53/02; C08L53/025; C08L2205/00; C08L2205/03; C08L2205/035; C08L2205/08; C08L23/04; C08L23/06; C08L23/16; C08L35/00; C08L35/06; C08L51/04

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 212 words
A moldable polyblend composition comprising: (a) from about 40 to 80 weight percent of an olefin polymer, wherein the olefin polymer has a melt flow rate of less than 15 g/10 minutes and at least about 50 weight percent of the olefin polymer is a crystalline propylene polymer; (b) from about 5 to 40 weight percent of a rubber-modified styrenic resin comprised of from about 65 to 95 weight percent of a random thermoplastic copolymer of (i) from about 35 to 99 weight percent of a vinyl aromatic monomer; (ii) from about 1 to 30 weight percent of an α, β-unsaturated dicarboxylic acid derivative; and (iii) from 0 to about 35 weight percent of an ethylenically unsaturated monomer selected from the group consisting of unsaturated nitriles, α,β-unsaturated mono-carboxylic acids, C 1 -C 4 alkyl esters of α,β-unsaturated mono-carboxylic acids, and their mixtures; and from about 5 to 35 weight percent of a rubber selected from the group consisting of conjugated diene rubbers and ethylene propylene diene monomer rubbers, wherein said rubber is grafted with the random thermoplastic copolymer; and (c) from about 3 to 40 weight percent of a compatibilizer selected from the group consisting of mono-cinyl aromatic monomer/conjugated diene block copolymers, hydrogenated mono-vinyl aromatic monomer/conjugated diene block copolymers, and mixtures thereof.
Claim 2
Dependent Claim 212 words
A moldable polyblend composition comprising: (a) from about 40 to 80 weight percent of an olefin polymer, wherein the olefin polymer has a melt flow rate of less than 15 g/10 minutes and at least about 50 weight percent of the olefin polymer is a crystalline propylene polymer; (b) from about 5 to 40 weight percent of a rubber-modified styrenic resin comprised of from about 65 to 95 weight percent of a random thermoplastic copolymer of (i) from about 35 to 99 weight percent of a vinyl aromatic monomer; (ii) from about 1 to 30 weight percent of an α, β-unsaturated dicarboxylic acid derivative; and (iii) from 0 to about 35 weight percent of an ethylenically unsaturated monomer selected from the group consisting of unsaturated nitriles, α,β-unsaturated mono-carboxylic acids, C 1 -C 4 alkyl esters of α,β-unsaturated mono-carboxylic acids, and their mixtures; and from about 5 to 35 weight percent of a rubber selected from the group consisting of conjugated diene rubbers and ethylene propylene diene monomer rubbers, wherein said rubber is grafted with the random thermoplastic copolymer; and (c) from about 3 to 40 weight percent of a compatibilizer selected from the group consisting of mono-cinyl aromatic monomer/conjugated diene block copolymers, hydrogenated mono-vinyl aromatic monomer/conjugated diene block copolymers, and mixtures thereof.
Claim 3
Dependent Claim 41 words
The polyblend composition of claim 1 wherein the random thermoplastic copolymer is a copolymer of from about 70 to 99 weight percent of the vinyl aromatic monomer and from about 1 to 30 weight percent of the α,β-unsaturated dicarboxylic acid derivative.
Claim 4
Dependent Claim 49 words
The polyblend composition of claim 1 wherein the olefin polymer is a blend of from about 60 to 92.5 weight percent crystalline propylene polymer, from about 5 to 27 weight percent of an ethylene propylene diene monomer rubber, and from about 2.5 to 13 weight percent high density polyethylene.
Claim 5
Dependent Claim 13 words
The polyblend composition of claim 1 wherein the olefin polymer is crystalline polypropylene.
Claim 6
Dependent Claim 18 words
The polyblend composition of claim 1 wherein the vinyl aromatic monomer of the random thermoplastic copolymer is styrene.
Claim 7
Dependent Claim 20 words
The polyblend composition of claim 1 wherein the α,β-unsaturated dicarboxylic acid derivative of the random thermoplastic copolymer is maleic anhydride.
Claim 8
Dependent Claim 21 words
The polyblend composition of claim 1 wherein the random thermoplastic copolymer is a random thermoplastic copolymer of styrene and maleic anhydride.
Claim 9
Dependent Claim 14 words
The polyblend composition of claim 1 wherein the rubber is a styrene/butadiene block copolymer.
Claim 10
Dependent Claim 14 words
The polyblend composition of claim 1 wherein the compatibilizer is a styrene/butadiene block copolymer.
Claim 11
Dependent Claim 15 words
The polyblend composition of claim 1 wherein the compatibilizer is a hydrogenated styrene/butadiene block copolymer.
Claim 12
Dependent Claim 161 words
A moldable polyblend composition comprising: (a) from about 45 to 80 weight percent of an olefin polymer, wherein the olefin polymer has a melt flow rate of less than 12 g/10 minutes and at least about 60 weight percent of the olefin polymer is a crystalline propylene polymer; (b) from about 10 to 30 weight percent of a rubber-modified styrenic resin comprised of from about 75 to 90 weight percent of a random thermoplastic copolymer of (i) from about 75 to 95 weight percent of styrene; and (ii) from about 5 to 25 weight percent of maleic anhydride; and from about 10 to 25 weight percent of a mono-vinyl aromatic monomer/conjugated diene block copolymer rubber, wherein said rubber is grafted with said random thermoplastic copolymer and contains at least about 50 weight percent conjugated diene; and (c) from about 3 to 30 weight percent of a compatibilizer selected from the group consisting of styrene/butadiene block copolymers and hydrogenated styrene/butadiene block copolymers.
Claim 13
Dependent Claim 161 words
A moldable polyblend composition comprising: (a) from about 45 to 80 weight percent of an olefin polymer, wherein the olefin polymer has a melt flow rate of less than 12 g/10 minutes and at least about 60 weight percent of the olefin polymer is a crystalline propylene polymer; (b) from about 10 to 30 weight percent of a rubber-modified styrenic resin comprised of from about 75 to 90 weight percent of a random thermoplastic copolymer of (i) from about 75 to 95 weight percent of styrene; and (ii) from about 5 to 25 weight percent of maleic anhydride; and from about 10 to 25 weight percent of a mono-vinyl aromatic monomer/conjugated diene block copolymer rubber, wherein said rubber is grafted with said random thermoplastic copolymer and contains at least about 50 weight percent conjugated diene; and (c) from about 3 to 30 weight percent of a compatibilizer selected from the group consisting of styrene/butadiene block copolymers and hydrogenated styrene/butadiene block copolymers.
Claim 14
Dependent Claim 45 words
The polyblend composition of claim 11 wherein the olefin polymer is a blend of from about 60 to 92.5 weight percent crystalline polypropylene, from about 5 to 27 weight percent ethylene propylene diene rubber, and from about 2.5 to 13 weight percent high density polyethylene.
Claim 15
Dependent Claim 13 words
The polyblend composition of claim 11 wherein the olefin polymer is crystalline polypropylene.
Claim 16
Dependent Claim 16 words
The polyblend composition of claim 11 wherein the block copolymer rubber is a styrene/butadiene block copolymer.
Claim 17
Dependent Claim 39 words
The polyblend composition of claim 11 wherein the compatibilizer is a hydrogenated styrene/butadiene block copolymer having a linear triblock structure and containing from about 10 to 60 weight percent styrene and from about 40 to 90 weight percent butadiene.
Claim 18
Dependent Claim 27 words
A filled thermoplastic composition comprising the polyblend composition of claim 1, and a filler in a polyblend composition filler weight ratio of from about 0.5:1 to 20:1.
Claim 19
Dependent Claim 27 words
A filled thermoplastic composition comprising the polyblend composition of claim 11 and a filler in a polyblend composition filler weight ratio of from about 0.5:1 to 20:1.

References Cited (Backward Citations)

US4147739A Cited
US4097551A Cited
US4386187A Cited
US4386188A Cited
US4582871A Cited
JPS63205341A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-22 1995-01-21 1995-07-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-22 1999-01-21 1999-07-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-22 2003-01-21 2003-07-23 $7700.00 Window Closed / Lapsed

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