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US5034218A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable conditioning shampoo containing compatible anionic surfactant/cationic conditioning agent-non-volatile silicone emulsion

Assignee: Helene Curtis Inc
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Filing: 1990-07-13
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Granted: 1991-07-23
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Expires: 2010-07-13
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Abstract

Abstract A hair conditioning shampoo composition comprising an emulsion of water; about 5 to about 65 percent by weight of an anionic cleaning surfactant, such as ammonium lauryl sulfate; from about 0.1 to about 20 percent by weight of a cationic di-long chain alkyl quaternary nitrogen-containing conditioning agent, wherein the long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain, such as distearyl dimethyl ammonium chloride; from about 0.5 to about 10 weight percent of a long chain fatty alcohol having about 8 to about 32 carbons in the long chain, such as stearyl alcohol; from about 0.5 to about 10 weight percent of a non-volatile silicone; and about 0.1 to about 5% of an anionic cross-linked polymeric suspending agent, such as polyacrylic acid.

Inventors

  • 👤 Lane A. Duvel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:20
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61K8/33; A61K8/34; A61K8/342; A61K8/46; A61K8/466; A61K8/72; A61K8/81; A61K8/8141; A61K8/8147; A61K8/8152; A61K8/84; A61K8/89; A61K8/891; A61Q; A61Q5/00; A61Q5/02; A61Q5/12; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5424

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 114 words
A hair conditioning shampoo composition comprising an emulsion of water; about 5 to about 65 percent by weight of an anionic cleaning surfactant; from about 0.1 to about 20 percent by weight of a cationic di-long chain alkyl quaternary nitrogen-containing conditioning agent, wherein the long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain; from about 0.5 to about 10 weight percent of a long chain fatty alcohol having about 8 to about 32 carbons in the long chain; from about 0.5 to about 10 weight percent of a non-volatile silicone; and about 0.1 to about 5% of an anionic cross-linked polymeric suspending agent.
Claim 2
Dependent Claim 114 words
A hair conditioning shampoo composition comprising an emulsion of water; about 5 to about 65 percent by weight of an anionic cleaning surfactant; from about 0.1 to about 20 percent by weight of a cationic di-long chain alkyl quaternary nitrogen-containing conditioning agent, wherein the long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain; from about 0.5 to about 10 weight percent of a long chain fatty alcohol having about 8 to about 32 carbons in the long chain; from about 0.5 to about 10 weight percent of a non-volatile silicone; and about 0.1 to about 5% of an anionic cross-linked polymeric suspending agent.
Claim 3
Dependent Claim 30 words
The hair conditioning shampoo composition according to claim 1 wherein said non-volatile silicone is present in an amount of about 1.5 to about 5 percent by weight of said composition.
Claim 4
Dependent Claim 39 words
The hair conditioning shampoo composition according to claim 1 wherein said quaternary nitrogen-containing conditioning agent is a quaternary ammonium salt containing two alkyl radicals having a carbon chain length from about 12 to about 18 carbon atoms per radical.
Claim 5
Dependent Claim 30 words
The hair conditioning shampoo composition according to claim 1 wherein said quaternary nitrogen-containing conditioning agent is present at about 1 percent to about 3 percent by weight of the composition.
Claim 6
Dependent Claim 31 words
The hair conditioning shampoo composition according to claim 1 wherein said long chain fatty alcohol is present in an amount of about 2 to about 5 weight percent of said composition.
Claim 7
Dependent Claim 37 words
The composition of claim 1 wherein the non-volatile silicone has a viscosity at 25° C. of at least 5 centistokes and a boiling point at 760 mm Hg pressure and 25° C. of at least 250° C.
Claim 8
Dependent Claim 15 words
The composition of claim 1 wherein the polymeric suspending agent is a cross-linked acrylic resin.
Claim 9
Dependent Claim 36 words
The composition of claim 7 wherein the cross-linked resin is polyacrylic acid or a metal salt of polyacrylic acid and is present in an amount of about 0.1% to about 3% by weight of the composition.
Claim 10
Dependent Claim 28 words
The hair conditioning composition according to claim 1 wherein said long chain fatty alcohol is selected from the group consisting of cetyl alcohol, stearyl alcohol and mixtures thereof.
Claim 11
Dependent Claim 106 words
The hair conditioning composition according to claim 1 wherein said quaternary nitrogen-containing conditioning agent is selected from the group consisting of (a) compounds having two long carbon chains and two identical or different short chain alkyl groups containing one to four carbon atoms bonded to the quaternary nitrogen atom, (b) compounds having two long carbon chains, one benzyl group and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom, and (c) compounds having two long carbon chains, one hydrogen atom and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom.
Claim 12
Dependent Claim 63 words
In a hair conditioning shampoo composition containing water, an anionic cleaning surfactant, a fatty alcohol, a non-volatile silicone and a quaternary nitrogen-containing conditioning agent, the improvement comprising the conditioning agent having only two long chain alkyl groups bonded to the quaternary nitrogen atom, and an anionic polymeric suspending agent, in an amount of about 0.1% to about 5% by weight of the composition.
Claim 13
Dependent Claim 63 words
In a hair conditioning shampoo composition containing water, an anionic cleaning surfactant, a fatty alcohol, a non-volatile silicone and a quaternary nitrogen-containing conditioning agent, the improvement comprising the conditioning agent having only two long chain alkyl groups bonded to the quaternary nitrogen atom, and an anionic polymeric suspending agent, in an amount of about 0.1% to about 5% by weight of the composition.
Claim 14
Dependent Claim 18 words
A method of shampooing and conditioning hair which comprises applying to said hair the composition of claim 1.
Claim 15
Dependent Claim 19 words
A method of shampooing and conditioning hair simultaneously which comprises applying to said hair the composition of claim 11.
Claim 16
Dependent Claim 132 words
A method of manufacturing the conditioning shampoo composition of claim 1 comprising: heating a mixture of water, an anionic, polymeric suspending agent, and an anionic surfactant to a temperature above the melting point of the fatty alcohol; adding the fatty alcohol to said heated water until said alcohol is completely melted to form an anionic alcohol solution; adding the non-volatile silicone to said alcohol solution to form a two-phase composition; vigorously agitating the two-phase composition to break up the silicone into droplets; adding the di-long chain alkyl quaternary nitrogen-containing conditioning agent before or after said vigorous agitation while maintaining the temperature of the two phase composition at or above the melting point of said conditioning agent to form a stable emulsion having a viscosity of about 5,000 centipoises to about 20,000 centipoises.
Claim 17
Dependent Claim 27 words
The method of claim 14 further including adding 1-20% of the water and a proportionate quantity of the anionic surfactant to the composition after said vigorous agitation.
Claim 18
Dependent Claim 26 words
The method of claim 14 wherein said non-volatile silicone is present in an amount of about 1.5 to about 5 percent by weight of said composition.
Claim 19
Dependent Claim 35 words
The method of claim 14 wherein said quaternary nitrogen-containing conditioning agent is a quaternary ammonium salt containing two alkyl radicals having a carbon chain length from about 12 to about 18 carbon atoms per radical.
Claim 20
Dependent Claim 25 words
The method of claim 14 wherein said quaternary nitrogen-containing conditioning agent is present at about 2 to about 3 percent by weight of the composition.
Claim 21
Dependent Claim 27 words
The method of claim 14 wherein said long chain fatty alcohol is present in an amount of about 2 to about 5 weight percent of said composition.
Claim 22
Dependent Claim 37 words
The method of claim 14 wherein the non-volatile silicone has a viscosity at 25° C. of at least 5 centistokes and a boiling point at 760 mm Hg pressure and 25° C. of at least 250° C.
Claim 23
Dependent Claim 15 words
The method of claim 14 wherein the polymeric suspending agent is a cross-linked acrylic resin.
Claim 24
Dependent Claim 36 words
The method of claim 21 wherein the cross-linked resin is polyacrylic acid or a metal salt of polyacrylic acid and is present in an amount of about 0.1% to about 3% by weight of the composition.
Claim 25
Dependent Claim 25 words
The method of claim 14 wherein said long chain fatty alcohol is selected from the group consisting of cetyl alcohol, stearyl alcohol and mixtures thereof.
Claim 26
Dependent Claim 110 words
A hair conditioning shampoo composition comprising an emulsion of water; about 5 to about 65 percent by weight of an anionic cleaning surfactant; from about 0.1 to about 20 percent by weight of a cationic di-long chain alkyl quaternary nitrogen-containing conditioning agent, wherein the long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain; from about 0.5 to about 10 weight percent of a long chain fatty alcohol having about 8 to about 32 carbons in the long chain; from about 0.5 to about 10 weight percent of a non-volatile silicone; and about 0.1 to about 5% of guar gum.
Claim 27
Dependent Claim 110 words
A hair conditioning shampoo composition comprising an emulsion of water; about 5 to about 65 percent by weight of an anionic cleaning surfactant; from about 0.1 to about 20 percent by weight of a cationic di-long chain alkyl quaternary nitrogen-containing conditioning agent, wherein the long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain; from about 0.5 to about 10 weight percent of a long chain fatty alcohol having about 8 to about 32 carbons in the long chain; from about 0.5 to about 10 weight percent of a non-volatile silicone; and about 0.1 to about 5% of guar gum.
Claim 28
Dependent Claim 39 words
The hair conditioning shampoo composition according to claim 24 wherein said quaternary nitrogen-containing conditioning agent is a quaternary ammonium salt containing two alkyl radicals having a carbon chain length from about 12 to about 18 carbon atoms per radical.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-22 1995-01-21 1995-07-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-22 1999-01-21 1999-07-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-22 2003-01-21 2003-07-23 $7700.00 Window Closed / Lapsed

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