Abstract A crystalline saturated polyester resin such as polyethylene terephthalate, is molded into a desired shape in a molding machine under conditions such that the crystallization temperature of the resulting molded article is within 20° C. of the crystallization temperature of the starting saturated crystalline polyester resin. This is accomplished by preheating the resin in the molding apparatus to a temperature above its melting point to lower the viscosity of the resin to such an extent that the resin is not substantially degraded in the compression section of the molding machine. By avoiding reductions in the crystallization temperature of the molded resin, the resin can be shaped by, for example, blow molding into a bottle or other configuration while satisfying simultaneously the requirements for transparency and dimensional stability. The molded polyester articles obtained from the present invention are substantially free from chalking and variation in internal volume and are excellent in heat resistance.
A process for molding a dried saturated crystalline polyester resin into an article having a desired shape which comprises heating a starting saturated crystalline polyester resin having a crystallization temperature Tc 1 of at least about 165° C. to a temperature above the melting temperature of the resin, thereby lowering the viscosity of the resin, compressing and kneading the molten polyester resin of lowered viscosity such that mechanical shearing applied to the reduced viscosity molten resin, during said compression and kneading, does not substantially decrease the crystallizing temperature of the resulting molded article, and discharging the sheared molten polyester resin into a mold to form said molded article, whereby the molded article has a crystallization temperature Tc 2 (°C.), wherein Tc 1 -20° C.≦Tc 2 ≦Tc 1 .
Claim 2
Dependent Claim
128 words
A process for molding a dried saturated crystalline polyester resin into an article having a desired shape which comprises heating a starting saturated crystalline polyester resin having a crystallization temperature Tc 1 of at least about 165° C. to a temperature above the melting temperature of the resin, thereby lowering the viscosity of the resin, compressing and kneading the molten polyester resin of lowered viscosity such that mechanical shearing applied to the reduced viscosity molten resin, during said compression and kneading, does not substantially decrease the crystallizing temperature of the resulting molded article, and discharging the sheared molten polyester resin into a mold to form said molded article, whereby the molded article has a crystallization temperature Tc 2 (°C.), wherein Tc 1 -20° C.≦Tc 2 ≦Tc 1 .
Claim 3
Dependent Claim
16 words
The process as claimed in claim 1 wherein the saturated crystalline polyester resin is polyethylene terephthalate.
Claim 4
Dependent Claim
33 words
The process of claim 1 wherein the raw saturated crystallatine polyester resin is brought to and maintained at a temperature 40 to 90° C. higher than the melting point of said polyester resin.
Claim 5
Dependent Claim
28 words
The process of claim 1 wherein the crystallizing temperature, Tc 1 , of the starting unsaturated crystalline polyester resin is in the range of 167 to 180° C.
Claim 6
Dependent Claim
40 words
The process of claim 1 which further comprises first heating the starting saturated crystalline polyester resin to a temperature below its melting point to dry the polyester resin, and then further heating the dried resin to above its melting point.