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Polyborosilazane and process for producing same

Assignee: EMD Performance Materials Corp
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Filing: 1990-01-18
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Granted: 1991-07-09
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Expires: 2010-01-18
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Abstract

Abstract Disclosed is a polyborosilazane having a B/Si atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to about 500,000 which can be pyrolyzed to give ceramics. The polyborosilazane is produced by reacting a polysilazane having a number-average molecular weight of about 100 to about 50,000 with a boron compound.

Inventors

  • 👤 Osamu Funayama
  • 👤 Mikiro Arai
  • 👤 Yuuji Tashiro
  • 👤 Takeshi Isoda
  • 👤 Kiyoshi Sato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 08:24
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/56; C08G77/60; C08G77/62; C08G79/00; C08G79/08

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 231 words
A polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000 and containing (a) skeletal groups of a recurring unit represented by the general formula: ##STR39## wherein R 1 , R 2 and R 3 , independently from each other, represent hydrogen, a hydrocarbyl group, a group other than the hydrocarbyl group and containing a carbon atom bonded to the silicon atom of the above general formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R 1 , R 2 and R 3 is hydrogen and (b) at least one cross-linkage which cross-links said skeletal groups and which is selected from the group consisting of: ##STR40## wherein R 4 represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group and R 7 represents a residue bound to the nitrogen atom of R 6 having a nitrogen atom, and wherein at least two of the six bonds of the group (iv) are used for the crosslinkage with the remaining bond or bonds, if any, being linked to hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group.
Claim 2
Dependent Claim 231 words
A polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 200 to 500,000 and containing (a) skeletal groups of a recurring unit represented by the general formula: ##STR39## wherein R 1 , R 2 and R 3 , independently from each other, represent hydrogen, a hydrocarbyl group, a group other than the hydrocarbyl group and containing a carbon atom bonded to the silicon atom of the above general formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R 1 , R 2 and R 3 is hydrogen and (b) at least one cross-linkage which cross-links said skeletal groups and which is selected from the group consisting of: ##STR40## wherein R 4 represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group and R 7 represents a residue bound to the nitrogen atom of R 6 having a nitrogen atom, and wherein at least two of the six bonds of the group (iv) are used for the crosslinkage with the remaining bond or bonds, if any, being linked to hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxyl group or an amino group.
Claim 3
Dependent Claim 196 words
A process for producing a polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 500 to 500,000, which comprises reacting a polysilazane having a number-average molecular weight of about 250 to about 50,000 and containing a skeletal structure of a recurring unit represented by the general formula (I): ##STR41## wherein R 1 , R 2 and R 3 , independently from each other, represent hydrogen, a hydrocarbyl group, a group other than the hydrocarbyl group and containing a carbon atom bonded to the silicon atom of the above general formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R 1 , R 2 and R 3 is hydrogen, with a boron compound represented by the following general formula (II), (III), (IV) or (V): ##STR42## wherein R 4 may be the same or different and represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxy group or an amino group, and L represents a compound capable of forming a complex with B(R 4 ) 3 .
Claim 4
Dependent Claim 196 words
A process for producing a polyborosilazane having a boron/silicon atomic ratio of 0.01 to 3 and a number-average molecular weight of about 500 to 500,000, which comprises reacting a polysilazane having a number-average molecular weight of about 250 to about 50,000 and containing a skeletal structure of a recurring unit represented by the general formula (I): ##STR41## wherein R 1 , R 2 and R 3 , independently from each other, represent hydrogen, a hydrocarbyl group, a group other than the hydrocarbyl group and containing a carbon atom bonded to the silicon atom of the above general formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with the proviso that at least one of R 1 , R 2 and R 3 is hydrogen, with a boron compound represented by the following general formula (II), (III), (IV) or (V): ##STR42## wherein R 4 may be the same or different and represents hydrogen, halogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an alkylamino group, a hydroxy group or an amino group, and L represents a compound capable of forming a complex with B(R 4 ) 3 .
Claim 5
Dependent Claim 10 words
A polyborosilazane obtained by the process according to claim 2.
Claim 6
Dependent Claim 19 words
The process of claim 2 wherein chains of said skeletal structure are crosslinked by reaction with said boron compound.
Claim 7
Dependent Claim 25 words
The process of claim 2 wherein said polyborosilazane has a number-average molecular weight of 800-200,000 and said polysilazane has a number-average molecular weight of 500-10,000.

References Cited (Backward Citations)

US4581968A Cited
US4581468A Cited
US4707556A Cited
US4906763A Cited

USPTO Annuity & Maintenance Windows

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