US5030532A — Electrophotographic imaging member utilizing poly…

Claim 1

Independent Claim 188 words

An electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising a polyarylamine polymer represented by the formula: ##STR32## wherein: n is between about 5 and about 5,000, or 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p is between about 2 and about 100, or is 0 if n>0, X' and X" are independently selected from a group having bifunctional linkages, Q is a divalent group derived from a hydroxy terminated arylamine reactant containing the group: ##STR33## Q' is a divalent group derived from a hydroxy terminated polyarylamine containing the group defined for Q and having a weight average molecular weight between about 1000 and about 80,000, wherein: Ar is selected from the group consisting of: ##STR34## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR35## and the weight average molecular weight of the polyarylamine polymer is between about 10,000 and about 1,000,000.

Claim 2

Dependent Claim 188 words

An electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising a polyarylamine polymer represented by the formula: ##STR32## wherein: n is between about 5 and about 5,000, or 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p is between about 2 and about 100, or is 0 if n>0, X' and X" are independently selected from a group having bifunctional linkages, Q is a divalent group derived from a hydroxy terminated arylamine reactant containing the group: ##STR33## Q' is a divalent group derived from a hydroxy terminated polyarylamine containing the group defined for Q and having a weight average molecular weight between about 1000 and about 80,000, wherein: Ar is selected from the group consisting of: ##STR34## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR35## and the weight average molecular weight of the polyarylamine polymer is between about 10,000 and about 1,000,000.

Claim 3

Dependent Claim 22 words

An electrostatographic imaging member according to claim 1 wherein said imaging member comprises a charge generating layer and a charge transport layer.

Claim 4

Dependent Claim 17 words

An electrostatographic imaging member according to claim 2 wherein said charge transport layer comprises said polyarylamine polymer.

Claim 5

Dependent Claim 17 words

An electrostatographic imaging member according to claim 2 wherein said charge generating layer comprises said polyarylamine polymer.

Claim 6

Dependent Claim 25 words

An electrostatographic imaging member according to claim 2 wherein said imaging member comprises a blocking layer between said charge generating layer an said support layer.

Claim 7

Dependent Claim 20 words

An electrostatographic imaging member according to claim 2 wherein said imaging member comprises a protective overcoating comprising said polyarylamine polymer.

Claim 8

Dependent Claim 257 words

An electrostatographic imaging member according to claim 1 wherein said polyarylamine polymer is represented by the formula: ##STR36## wherein: m is 0 or 1, n is between about 5 and about 5,000, or is 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p if between about 2 and about 100, or is 0 if n>0, Z is selected from the group consisting of: ##STR37## r is 0 or 1, Ar is selected from the group consisting of: ##STR38## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR39## X is selected from the group consisting of: --CH 2 --, --C(CH 3 ) 2 --, --O--, --S--, ##STR40## s is 0, 1 or 2, X' AND X" are independently selected from a group having bifunctional linkages, and Y and Y' are independently selected from a group represented by the formula: --CH.sub.2).sub.t t is 0, 1, 2, 3, or 4 Q' is represented by the formula: ##STR41## wherein: Ar, Ar', Z, Y, Y', and m, are as defined previously, and B represents a bifunctional linkage. Typical examples of which include: ##STR42## and g is between about 2 and about 350 such that the weight average molecular weight of Q' is between about 1000 and about 80,000, and the weight average molecular weight of said polyarylamine polymer is between about 20,000 and about 500,000.

Claim 9

Dependent Claim 44 words

An electrostatographic imaging member according to claim 1 wherein said polyarylamine polymer is the reaction product of a dihydroxy arylamine compound and a co-reactant diisocyanate compound represented by the formula: O═C═N--X'--N═C═O wherein X' is a bifunctional linkage containing from 1 to 25 carbon atoms.

Claim 10

Dependent Claim 41 words

An electrostatographic imaging member according to claim 8 wherein an additional diisocyanate compound is included in said reaction, said additional diisocyanate compound being represented by the formula: O═C═N--X"--N═C═O wherein X" is a bifunctional linkage containing from 1 to 25 carbon atoms.

Claim 11

Dependent Claim 99 words

An electrostatographic imaging member according to claim 1 wherein said polyarylamine polymer is the reaction product of a diisocyanate with a low molecular weight hydroxy group terminated arylamine polymer represented by the generic formula: HO--Q'--OH wherein: Q' is a divalent group derived from a dihydroxy terminated polyarylamine material containing the following group: ##STR43## wherein: Ar is selected from the group consisting of: ##STR44## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR45##

Claim 12

Dependent Claim 30 words

An electrostatographic imaging member according to claim 9 wherein said low molecular weight hydroxy group terminated arylamine polymer has a weight average molecular weight between about 1,000 and about 80,000.

Claim 13

Dependent Claim 229 words

An electrophotographic imaging process comprising forming an electrostatic latent image on the imaging surface of an electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising a polyarylamine polymer represented by the formula: ##STR46## wherein: n is between about 5 and about 5,000, or 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p is between about 2 and about 100, or is 0 if n>0, X' and X" are independently selected from a group having bifunctional linkages, Q is a divalent group derived from a hydroxy terminated arylamine reactant containing the group: ##STR47## Q' is a divalent group derived from a hydroxy terminated polyarylamine containing the group defined for Q and having a weight average molecular weight between about 1000 and about 80,000, wherein: Ar is selected from the group consisting of: ##STR48## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR49## and the weight average molecular weight of the polyarylamine polymer is between about 10,000 and about 1,000,000 and contacting said imaging surface with a developer to from a toner marking particle deposit on said imaging surface in conformance to said electrostatic latent image.

Claim 14

Dependent Claim 229 words

An electrophotographic imaging process comprising forming an electrostatic latent image on the imaging surface of an electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising a polyarylamine polymer represented by the formula: ##STR46## wherein: n is between about 5 and about 5,000, or 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p is between about 2 and about 100, or is 0 if n>0, X' and X" are independently selected from a group having bifunctional linkages, Q is a divalent group derived from a hydroxy terminated arylamine reactant containing the group: ##STR47## Q' is a divalent group derived from a hydroxy terminated polyarylamine containing the group defined for Q and having a weight average molecular weight between about 1000 and about 80,000, wherein: Ar is selected from the group consisting of: ##STR48## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR49## and the weight average molecular weight of the polyarylamine polymer is between about 10,000 and about 1,000,000 and contacting said imaging surface with a developer to from a toner marking particle deposit on said imaging surface in conformance to said electrostatic latent image.

Claim 15

Dependent Claim 15 words

An electrophotographic imaging process according to claim 12 wherein said developer is a liquid developer.

Claim 16

Dependent Claim 17 words

An electrophotographic imaging process according to claim 13 wherein said liquid developer comprises an organic carrier fluid.

Claim 17

Dependent Claim 18 words

An electrophotographic imaging process according to claim 12 including transfering said marking particle deposit to a receiving member.

Claim 18

Dependent Claim 19 words

An electrophotographic imaging process according to claim 15 including repeating said forming, contacting and transfering steps at least once.

Claim 19

Dependent Claim 87 words

An electrophotographic imaging process according to claim 12 wherein said imaging member comprises a charge generating layer and a charge transport layer comprising said polyarylamine polymer, said charge transport layer being substantially transparent to radiation in the region in which said imaging member is exposed during electrophotographic imaging and capable of supporting the injection of photo-generated holes from said charge generating layer and transporting said holes through said charge transport layer to selectively discharge an electrostatic charge on said imaging surface to form said electrostatic latent image.

Claim 20

Dependent Claim 257 words

An electrophotographic imaging process according to claim 12 wherein said polyarylamine polymer is represented by the formula: ##STR50## wherein: m is 0 or 1, n is between about 5 and about 5,000, or is 0 if p>0, o is between about 0 and about 5,000, or is 0 if p>0 or n=0, p if between about 2 and about 100, or is 0 if n>0, Z is selected from the group consisting of: ##STR51## r is 0 or 1, Ar is selected from the group consisting of: ##STR52## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR53## X is selected from the group consisting of: --CH 2 --, --C(CH 3 ) 2 --, --O--, --S--, ##STR54## s is 0, 1 or 2, X' AND X" are independently selected from a group having bifunctional linkages, and Y and Y' are independently selected from a group represented by the formula: --CH.sub.2).sub.t t is 0, 1, 2, 3, or 4 Q' is represented by the formula: ##STR55## wherein: Ar, Ar', Z, Y, Y', and m, are as defined previously, and B represents a bifunctional linkage. Typical examples of which include: ##STR56## and g is between about 2 and about 350 such that the weight average molecular weight of Q' is between about 1000 and about 80,000, and the weight average molecular weight of said polyarylamine polymer is between about 20,000 and about 500,000.

Claim 21

Dependent Claim 99 words

An electrophotographic imaging process according to claim 12 wherein said polyarylamine polymer is the reaction product of a diisocyanate with a low molecular weight hydroxy group terminated arylamine polymer represented by the generic formula: HO--Q'--OH wherein: Q' is a divalent group derived from a dihydroxy terminated polyarylamine material containing the following group: ##STR57## wherein: Ar is selected from the group consisting of: ##STR58## R is selected from the group consisting of --CH 3 , --C 2 H 5 , --C 3 H 7 , and --C 4 H 9 , Ar' is selected from the group consisting of: ##STR59##

Claim 22

Dependent Claim 30 words

An electrophotographic imaging process according to claim 19 wherein said low molecular weight hydroxy group terminated arylamine polymer has a weight average molecular weight between about 1,000 and about 80,000.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1994-07-08	1995-01-07	1995-07-09	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1998-07-08	1999-01-07	1999-07-09	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	2002-07-08	2003-01-07	2003-07-09	$7700.00	Window Closed / Lapsed

Electrophotographic imaging member utilizing polyarylamine polymers

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