Novel benzotrifluoride aryl ether gas separation membranes

Claim 2

A process of separating gases comprising: A. contacting one side of a semi-permeable gas separation membrane comprising a thin discriminating layer of a benzotrifluoride aryl ether polymer with a feed gas mixture under pressure, wherein the membrane divides a separation chamber into a high pressure side into which the feed gas mixture is fed and a low pressure side; B. maintaining a pressure differential across the membrane under conditions such that at least one gaseous component in the feed gas mixture selectively permeaters through the membrane from the high pressure side to the low pressure side of the membrane; C. removing from the low pressure side of the membrane permeated gas which is enriched in the selectively permeating gaseous component(s); and D. removing from the high pressure side of the membrane non-permeated gas which is depleted in the selectively permeating gaseous component(s).

Claim 3

The process of claim 1 wherein the feed gas mixture contains at least one of the gases selected from the group consisting of hydrogen, helium, oxygen, nitrogen, carbon monoxide, carbon dioxide, water vapor, hydrogen sulfide, ammonia, and light hydrocarbons.

Claim 4

The process of claim 2 wherein the pressure of the feed gas mixture is between about 5 psig and about 1000 psig.

Claim 5

The process of claim 3 wherein the temperature of the feed gas mixture is between about 0° C. and about 150° C.

Claim 6

A semi-permeable gas separation membrane comprising a thin discriminating layer of a benzotrifluoride aryl ether polymer.

Claim 7

A semi-permeable gas separation membrane comprising a thin discriminating layer of a benzotrifluoride aryl ether polymer.

Claim 8

The membrane of claim 5 wherein the benzotrifluoride aryl ether polymer comprises a polymer backbone structure corresponding to the formula: ##STR6## wherein Ar is a divalent aromatic residue selected from the group consisting of: A. an unsubstituted or inertly substituted phenylene, unsubstituted or inertly substituted naphthylene; B. ##STR7## wherein L is a direct bond, a divalent C 1-15 hydrocarbyl radical, a divalent C 1-8 halohydrocarbyl radical, --O--, --CO--, --S--, --SO--, --SO 2 --, or --SS--, X is individually in each occurrence a hydrogen radical, a monovalent C 1-4 hydrocarbyl radical, a monovalent C 1-4 halohydrocarbyl radical, or a halogen, and m is an integer between 1 and 4 inclusive; and C. a divalent bisphenyl fluorenyl or spiro indanyl radical; and Y is individually in each occurrence a hydrogen radical, a monovalent C 1-4 hydrocarbyl radical, a C 1-4 halohydrocarbyl radical, or a halogen, and p is an integer between 1 and 3 inclusive, and n is a positive real number such that the membrane possesses adequate physical integrity under conditions of use.

Claim 9

The membrane of claim 6 wherein Ar comprises an inertly substituted phenylene or naphthylene, wherein the inert substituents are selected from the group consisting of a monovalent C 1-8 hydrocarbyl radical, a monovalent C 1-8 hydrocarbyloxy radical, and a halogen.

Claim 10

The membrane of claim 7 wherein the inert substituents are selected from the group consisting of a monovalent C 1-4 hydrocarbyl radical, a monovalent C 1-4 hydrocarbyloxy radical, and a halogen.

Claim 11

The membrane of claim 8 wherein the inert substituents comprise a halogen selected from the group consisting of fluorine, chlorine, and bromine.

Claim 12

The membrane of claim 6 wherein Ar comprises ##STR8## wherein L is selected from the group consisting of a direct bond, a divalent C 1-8 hydrocarbyl radical, a divalent C 1-4 halohydrocarbyl radical, --O--, --CO--, --S--, --SO--, --SO 2 --, and --SS--.

Claim 13

The membrane of claim 10 wherein L is selected from the group consisting of a direct bond, a divalent C 1-4 hydrocarbyl radical, a divalent C 1-4 halohydrocarbyl radical, --O--, --CO--, --S--, --SO--, --SO 2 --, and --SS--.

Claim 14

The membrane of claim 11 wherein L is selected from the group consisting of a direct bond, a divalent C 1-3 hydrocarbyl radical, and a divalent C 1-3 fluorohydrocarbyl radical.

Claim 15

The membrane of claim 12 wherein L is selected from the group consisting of a direct bond, an unsubstituted or fluoro-substituted methylene radical, and an unsubstituted or fluoro-substituted isopropylidene radical.

Claim 16

The membrane of claim 6 wherein Ar comprises ##STR9## wherein X is selected from the group consisting of a hydrogen radical, a monovalent C 1-3 hydrocarbyl radical, a monovalent C 1-3 halohydrocarbyl radical, and a halogen.

Claim 17

The membrane of claim 14 wherein X is selected from the group consisting of a fluorohydrocarbyl radical and fluorine.

Claim 18

The membrane of claim 6 wherein the membrane is composite or asymmetric.

Claim 19

The membrane of claim 6 wherein the membrane is a hollow fiber.

Claim 20

The membrane of claim 6 wherein the separation factor for helium methane at about 30° C. is at least about 5.

Claim 21

The membrane of claim 6 wherein the permeability for helium is at least about 25 Barrers.

Claim 22

The membrane of claim 6 wherein the separation factor for oxygen/nitrogen at about 25° C. is at least about 1.25.

Claim 23

The membrane of claim 6 wherein the permeability for oxygen is at least about 5 Barrers.