Silica particulate composition

Claim 2

A silica powder composition in which the powder particles have an average size of from 0.05 to 15 microns, a specific surface area of from 25 to 400 m 2 /g, and consist essentially of a shell of amorphous hydroxylated silica having a shape and a thickness in the range of from 10 to 50 nanometers.

Claim 3

The silica powder composition of claim 1 in which the shell of amorphous hydroxylated silica is impervious.

Claim 4

A process for preparing a silica powder composition in which the powder particles consist essentially of a shell of amorphous hydroxylated silica having a shape, the process consisting essentially of: (a) forming an aqueous suspension of a particulate generally inert acid leachable core material in which the core material has a specific surface area in the range of from 1 to 50 m 2 /g; (b) adding amorphous hydroxylated silica to the aqueous suspension in the presence of from 0.001 to 5 wt.% of a polyvalent metal ion at a temperature of from 45° C. to 100° C. and at a rate which avoids precipitation of free silica while maintaining the pH of the aqueous suspension at a value in the range of from 8 to 11 while forming an amorphous hydroxylated silica coating layer having metal ions randomly dispersed therein and a thickness of from 10 to 50 nm around the core particles; (c) removing the core material by adding an acid in which the core material is soluble to the aqueous suspension of the silica coated particles while maintaining the pH of the suspension at a value in the range of from 1.5 to 3.5 whereby the core material is dissolved and can be extracted leaving a hollow shell of amorphous hydroxylated silica; and (d) recovering the silica shells which remain from the aqueous suspension.

Claim 5

A process for preparing a silica powder composition in which the powder particles consist essentially of a shell of amorphous hydroxylated silica having a shape, the process consisting essentially of: (a) forming an aqueous suspension of a particulate generally inert acid leachable core material in which the core material has a specific surface area in the range of from 1 to 50 m 2 /g; (b) adding amorphous hydroxylated silica to the aqueous suspension in the presence of from 0.001 to 5 wt.% of a polyvalent metal ion at a temperature of from 45° C. to 100° C. and at a rate which avoids precipitation of free silica while maintaining the pH of the aqueous suspension at a value in the range of from 8 to 11 while forming an amorphous hydroxylated silica coating layer having metal ions randomly dispersed therein and a thickness of from 10 to 50 nm around the core particles; (c) removing the core material by adding an acid in which the core material is soluble to the aqueous suspension of the silica coated particles while maintaining the pH of the suspension at a value in the range of from 1.5 to 3.5 whereby the core material is dissolved and can be extracted leaving a hollow shell of amorphous hydroxylated silica; and (d) recovering the silica shells which remain from the aqueous suspension.

Claim 6

The process of claim 3 in which the core material is an alkaline earth metal carbonate.

Claim 7

The process of claim 4 in which the core material is removed by adding an acid in which the core material is soluble to the aqueous suspension of the silica coated particles while maintaining the pH of the suspension at a value in the range of from 1.5 to 3.5 whereby the core material is dissolved and can be extracted leaving the hollow shell of amorphous hydroxylated silica.

Claim 8

The process of claim 3 in which the recovered silica shells are calcined at a temperature of from 700° C. to 900° C. for at least 1 and up to 3 hours.

Claim 9

The process of claim 3 in which the recovered silica shells are rendered impervious by coating them with a non-porous layer of active silica.