US5024171A
Expired / Lapsed
US
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Reduction of acidic emissions from combustion of sulfur-laden fuels
Assignee: WEXFORD MANAGEMENT LLC
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Filing: 1990-03-19
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Granted: 1991-06-18
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Expires: 2010-03-19
Abstract
Abstract The sulfur trioxide in the combustion gas stream of a power plant is reacted with injected ammonia to produce a solid ammonium sulfate that is captured, and not released to the atmosphere. A feedforward signal indicative of the total mass flow of sulfur trioxide is determined as the product of the measured boiler load and the sulfur trioxide content of the combustion gas, as measured prior to the addition of ammonia. The ammonia mass flow injection rate is preferably at a normal stoichiometric ratio of from about 1.0 to about 1.1 relative to the sulfur trioxide mass flow rate (that is, from about 2.0 to about 2.2 times the molar mass flow rate of the sulfur trioxide), avoiding the production of ammonia bisulfate. The ammonia content of the combustion gas stream is measured downstream of the location at which ammonia is added. Based upon this feedback measurement, the amount of ammonia added is adjusted to be just sufficient to react with all of the sulfur trioxide, but not in such excess as to be environmentally detrimental.
Inventors
- 👤 Henry V. Krigmont
- 👤 Everett L. Coe, Jr.
- 👤 Barry J. Southam
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 18:39
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; F; F23; F23J; F23J15/00; F23J15/006; F23G; F23G2207/00; F23G2207/10; F23G2207/106; F23G2207/60; F23J2215/00; F23J2215/20; F23J2217/00; F23J2217/10; F23J2217/102
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
99 words
A method for neutralizing at least a portion of the sulfur trioxide in a gas stream resulting from the combustion of fossil fuels within a boiler, comprising the steps of: measuring a combustion gas stream at a first location to determine the sulfur trioxide content of the combustion gas stream; adding ammonia to the combustion gas stream at a second location downstream of the first location in an amount responsive to the sulfur trioxide content determined in the step of measuring; and measuring the ammonia content of the gas stream at a third location downstream of the second location.
Claim 2
Independent Claim
99 words
A method for neutralizing at least a portion of the sulfur trioxide in a gas stream resulting from the combustion of fossil fuels within a boiler, comprising the steps of: measuring a combustion gas stream at a first location to determine the sulfur trioxide content of the combustion gas stream; adding ammonia to the combustion gas stream at a second location downstream of the first location in an amount responsive to the sulfur trioxide content determined in the step of measuring; and measuring the ammonia content of the gas stream at a third location downstream of the second location.
Claim 3
Dependent Claim
19 words
The process of claim 1, wherein the step of measuring includes the substep of measuring a boiler load signal.
Claim 4
Dependent Claim
24 words
The process of claim 2, wherein the step of measuring includes the substep of measuring the sulfur trioxide concentration of the combustion gas stream.
Claim 5
Dependent Claim
31 words
The process of claim 3, wherein the step of measuring includes the substep of multiplying the measured boiler load signal times the measured sulfur trioxide concentration to generate a control signal.
Claim 6
Dependent Claim
22 words
The process of claim 4, wherein the amount of ammonia added in the step of adding is proportional to the control signal.
Claim 7
Dependent Claim
29 words
The process of claim 1, wherein ammonia is added in the step of adding ammonia in a normal stoichiometric ratio relative to sulfur trioxide of greater than about 1.0.
Claim 8
Dependent Claim
22 words
The process of claim 6, wherein the ammonia is added in a normal stoichiometric ratio of from about 1.0 to about 1.1.
Claim 9
Dependent Claim
13 words
The process of claim 1, wherein the ammonia is added as gaseous ammonia.
Claim 10
Dependent Claim
16 words
The process of claim 1, wherein the combustion gas stream is produced by a power plant.
Claim 11
Dependent Claim
38 words
The process of claim 1, including the additional step of trimming the ammonia addition in the step of adding ammonia to maintain the ammonia content measured in the step of measuring the ammonia content at a preselected value.
Claim 12
Dependent Claim
11 words
The process of claim 10, wherein the preselected value is zero.
Claim 13
Dependent Claim
159 words
A process for controlling the composition of a combustion gas stream, comprising the steps of: measuring a boiler load signal proportional to a total flow rate of the combustion gas stream; measuring a sulfur trioxide content of the combustion gas stream; determining a control signal proportional to the product of the boiler load signal times the sulfur trioxide content of the combustion gas stream; adding ammonia to the combustion gas stream at a location downstream of the location at which the sulfur trioxide content of the combustion gas stream is measured, in an amount proportional to the control signal; measuring the ammonia content of the combustion gas stream at a location downstream of the location at which ammonia is added to the combustion gas stream; and trimming the flow rate of ammonia added in the step of adding ammonia such that the amount of ammonia measured in the step of measuring the ammonia content is at a preselected value.
Claim 14
Dependent Claim
159 words
A process for controlling the composition of a combustion gas stream, comprising the steps of: measuring a boiler load signal proportional to a total flow rate of the combustion gas stream; measuring a sulfur trioxide content of the combustion gas stream; determining a control signal proportional to the product of the boiler load signal times the sulfur trioxide content of the combustion gas stream; adding ammonia to the combustion gas stream at a location downstream of the location at which the sulfur trioxide content of the combustion gas stream is measured, in an amount proportional to the control signal; measuring the ammonia content of the combustion gas stream at a location downstream of the location at which ammonia is added to the combustion gas stream; and trimming the flow rate of ammonia added in the step of adding ammonia such that the amount of ammonia measured in the step of measuring the ammonia content is at a preselected value.
Claim 15
Dependent Claim
19 words
The process of claim 12, wherein the boiler load signal is the flow rate of fuel to the combustor.
Claim 16
Dependent Claim
11 words
The process of claim 12, wherein the preselected value is zero.
Claim 17
Dependent Claim
29 words
The process of claim 12, wherein ammonia is added in the step of adding ammonia in a normal stoichiometric ratio relative to sulfur trioxide of greater than about 1.0.
Claim 18
Dependent Claim
22 words
The process of claim 15, wherein the ammonia is added in a normal stoichiometric ratio of from about 1.0 to about 1.1.
Claim 19
Dependent Claim
13 words
The process of claim 12, wherein the ammonia is added as gaseous ammonia.
Claim 20
Dependent Claim
16 words
The process of claim 12, wherein the combustion gas stream is produced by a power plant.
Claim 21
Dependent Claim
113 words
A process for controlling the composition of a combustion gas stream of a power plant to which ammonia is added, comprising the steps of: adjusting the flow rate of the ammonia such that the molar flow rate of the ammonia is from about 2.0 to about 2.2 times the molar flow rate of sulfur trioxide in the combustion gas stream prior to the addition of the ammonia; measuring the ammonia content of the gas stream at a location downstream of the location at which ammonia is added; and trimming the flow rate of the ammonia added in the step of adding based upon the measurement of ammonia content in the step of measuring.
Claim 22
Dependent Claim
113 words
A process for controlling the composition of a combustion gas stream of a power plant to which ammonia is added, comprising the steps of: adjusting the flow rate of the ammonia such that the molar flow rate of the ammonia is from about 2.0 to about 2.2 times the molar flow rate of sulfur trioxide in the combustion gas stream prior to the addition of the ammonia; measuring the ammonia content of the gas stream at a location downstream of the location at which ammonia is added; and trimming the flow rate of the ammonia added in the step of adding based upon the measurement of ammonia content in the step of measuring.
Claim 23
Dependent Claim
31 words
The process of claim 19, including the additional step of measuring the sulfur trioxide content of the gas stream at a location upstream of the location at which ammonia is added.
Claim 24
Dependent Claim
22 words
The process of claim 20, including the additional step of measuring a boiler load signal indicative of the total combustion gas flow.
Claim 25
Dependent Claim
33 words
The process of claim 21, including the additional step of multiplying the sulfur trioxide content times the boiler load signal, to determine a value proportional to the total sulfur trioxide molar flow rate.
Claim 26
Dependent Claim
31 words
The process of claim 19, wherein the flow rate of ammonia is trimmed such that the ammonia content measured in the step of measuring the ammonia content is greater than zero.
References Cited (Backward Citations)
US4051225A
Cited
US4793268A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-06-17 | 1994-12-17 | 1995-06-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-06-17 | 1998-12-17 | 1999-06-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-06-17 | 2002-12-17 | 2003-06-18 | $7700.00 | Window Closed / Lapsed |