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Chemical process yielding stimulating emission of visible radiation via fast near resonant energy transfer

Assignee: Georgia Tech Research Corp
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Filing: 1989-07-03
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Granted: 1991-05-28
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Expires: 2009-07-03
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Abstract

Abstract A laser oscillator at 535 nm produced by a chemical process yielding stimulated emission of visible radiation via fast near resonant intermolecular energy transfer comprising the steps of reacting a reaction with a first metal vapor to form metastable states of metal oxides or metal halides, transferring the energy from the metastable states to receptor metal atoms by means of near resonant energy transfer to form electronically excited receptor metal atoms in an inverted configuration, and, through multiple reflection, allowing for the repeated passage of light through the inverted gain medium so as to produce oscillation.

Inventors

  • 👤 James L. Gole
  • 👤 James R. Woodward
  • 👤 Stephen H. Cobb

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 16:05
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/09; H01S3/095

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 396 words
A chemical process yielding stimulated emission of visible radiation via fast rear resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal or semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal or semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV; said reactant being selected from the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the said reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms in a population inversion relative to a lower level of excitation of said receptor atoms; and (f) providing a mirror configuration having first and second mirrors and windows associated with said mirrors, wherein said mirrors are chosen such that < g.sub.1 g.sub.2 <1, where g 1 =l-L/r 1 g 2 =1-L/r 2 L=separation between the mirrors (cavity length) r 1 =radius of curvature of said first mirror r 2 =radius of curvature of said second mirror L<r 1 and L<r 2 , said first and second mirrors being placed on opposite ends of an enclosed amplification zone such that the inverted population and multiple reflections allows for oscillation via the repeated passage of light through the inverted gain medium operative at the wavelength of the amplified transition associated with the population inversion created among the energy levels of the receptor atoms in a stable cavity configuration, said windows being operative in the wavelength ranges for the transition of the amplifying medium defined by the length of the cavity and radii of curvature of said mirrors, and said mirror configuration causing light associated with the amplified transition to undergo multiple passes through the inverted gain medium yielding oscillation of stimulated emission of visible radiation.
Claim 2
Dependent Claim 396 words
A chemical process yielding stimulated emission of visible radiation via fast rear resonant intermolecular energy transfer comprising the steps of: (a) providing a first source of vapor selected from the group consisting of metal or semimetal vapor to be reacted with an appropriate reactant to produce a metastable excited state reaction product which serves as an energy storage medium; (b) providing a second source of atomic vapor selected from the group consisting of metal or semimetal vapor to serve as receptor atoms to receive the energy from said metastable excited state of the reaction product; (c) providing a source of reactant to react with the first source of vapor in a highly exothermic reaction which liberates energy exceeding 2.5 eV; said reactant being selected from the group consisting of ozone, nitrogen oxide, nitrogen dioxide, and halides; (d) chemically reacting the reactant and the first source of vapor to form metastable states of a final reaction product; (e) transferring energy stored in the metastable states of the said reaction product to the second source of atomic vapor serving as receptor atoms by means of near resonant energy transfer to form electronically excited receptor atoms in a population inversion relative to a lower level of excitation of said receptor atoms; and (f) providing a mirror configuration having first and second mirrors and windows associated with said mirrors, wherein said mirrors are chosen such that < g.sub.1 g.sub.2 <1, where g 1 =l-L/r 1 g 2 =1-L/r 2 L=separation between the mirrors (cavity length) r 1 =radius of curvature of said first mirror r 2 =radius of curvature of said second mirror L<r 1 and L<r 2 , said first and second mirrors being placed on opposite ends of an enclosed amplification zone such that the inverted population and multiple reflections allows for oscillation via the repeated passage of light through the inverted gain medium operative at the wavelength of the amplified transition associated with the population inversion created among the energy levels of the receptor atoms in a stable cavity configuration, said windows being operative in the wavelength ranges for the transition of the amplifying medium defined by the length of the cavity and radii of curvature of said mirrors, and said mirror configuration causing light associated with the amplified transition to undergo multiple passes through the inverted gain medium yielding oscillation of stimulated emission of visible radiation.
Claim 3
Dependent Claim 17 words
A process as defined in claim 1 wherein the receptor atoms are non-reactive with the selected reactant.
Claim 4
Dependent Claim 39 words
A process as defined in claim 1 wherein the receptor atoms are selected from the group consisting of atoms capable of receiving gas kinetic or greater near resonant energy transfer from the metastable states of the oxide or halide.
Claim 5
Dependent Claim 36 words
A process as defined in claim 1 wherein the receptor atoms are selected from the group consisting of thallium, gallium, lead, alkali, and alkaline earth metals, scandium, vanadium, iron, nickel, yttrium, titanium, chromium, barium and strontium.
Claim 6
Dependent Claim 20 words
The process as claimed in claim 4 wherein said receptor atom is thallium and L<30 cm<r 1 ,r 2 .
Claim 7
Dependent Claim 20 words
The process as claimed in claim 4 wherein said receptor atom is sodium and L<30 cm<r 1 ,r 2 .
Claim 8
Dependent Claim 23 words
A process as defined in claim 1 wherein said first source of vapor is selected from the group consisting of germanium and silicon.
Claim 9
Dependent Claim 30 words
A process as defined in claim 1 wherein said first source of vapor is silicon and the reactant is selected from the group consisting of nitrogen oxide and nitrogen dioxide.
Claim 10
Dependent Claim 21 words
A process as defined in claim 1 wherein said first source of vapor is silicon and the reactant is nitrogen dioxide.
Claim 11
Dependent Claim 20 words
A process as defined in claim 1 wherein said first source of vapor is germanium and the reactant is ozone.
Claim 12
Dependent Claim 30 words
A process as defined in claim 1 wherein said first source of vapor is selected from the group consisting of scandium, yttrium, and lanthanum and the reactant is a halogen.
Claim 13
Dependent Claim 43 words
A process as defined in claim 1 wherein step (a) includes first providing a source of a first element selected from the group consisting of metals and semimetals and heating said first element to form the first source of vapor to be reacted.
Claim 14
Dependent Claim 27 words
A process as defined in claim 12, wherein said first element is heated to a temperature producing a vapor pressure of approximately 10 -1 to 2 Torr.
Claim 15
Dependent Claim 45 words
A process as defined in claim 1 wherein step (b) includes first providing a source of a second element selected from the group consisting of metals and semimetals and heating said second element to form said second source of vapor to serve as receptor atoms.
Claim 16
Dependent Claim 26 words
A process as defined in claim 11, wherein said second element is heated to a temperature producing approximately a 10 -1 to 10 Torr vapor pressure.
Claim 17
Dependent Claim 14 words
A process as defined in claim 1, wherein said mirror configuration comprises two mirrors.
Claim 18
Dependent Claim 16 words
A process as defined in claim 16, wherein said mirrors are concave inwardly towards each other.
Claim 19
Dependent Claim 19 words
A process as defined in claim 12, wherein said mirrors have a radius of curvature of about 2 m.
Claim 20
Dependent Claim 25 words
A process as defined in claim 16, wherein one of said mirrors is totally reflective and the other of said mirrors is an output coupler.
Claim 21
Dependent Claim 16 words
A process as defined in claim 19, wherein said output coupler has about a 3% transmissivity.
Claim 22
Dependent Claim 12 words
A process as defined in claim 1, further comprising a Brewster's windows.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-27 1994-11-26 1995-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-27 1998-11-26 1999-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-27 2002-11-26 2003-05-28 $7700.00 Window Closed / Lapsed

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