Polyol(allyl carbonate) compositions and polymerizates prepared therefrom

Claim 2

A process for preparing liquid, gel-free, partially polymerized polyol(allyl carbonate) having from 20 to 50 percent allylic utilization, which process compromises (a) preparing a mixture of polyol(allyl carbonate) monomer and an organic solvent selected from C 1 -C 2 chlorinated solvents, the ratio of solvent to monomer being from 0.5 to 5 milliliters of solvent per gram of monomer, said polyol(allyl carbonate) monomer being represented by the graphic formula: ##STR16## wherein R 1 is allyl, R 2 is derived from an alkylene glycol of from 2 to 4 carbon atoms, a poly (C 2 -C 4 ) alkylene glycol, or isopropylidene bis(paraphenol), and n is 2, (b) polymerizing said monomer with from 0.5 to 1.5 weight percent of peroxydicarbonate ester initiator until from 20 to 50 percent of the allylic carbon-carbon linkages are consumed, and (c) removing said solvent from the product of the polymerization to produce a gel-free, liquid, polymerizable composition.

Claim 3

A process for preparing liquid, substantially gel-free, partially polymerized polyol(allyl carbonate) having from 20 to 50 percent allylic utilization, which process comprises (a) preparing a mixture of polyol(allyl carbonate) monomer and an organic solvent in which the monomer and the partially polymerized polyol(allyl carbonate) are soluble, said solvent being non-reactive chemically with said monomer and said partially polymerized polyol(allyl carbonate), and having a higher vapor pressure than said monomer, (b) polymerizing said monomer with free radical initiator until from 20 to 50 percent of the allylic carbon-carbon linkages are consumed, and (c) removing said solvent from the product of the polymerization to produce a gel-free, liquid, polymerizable composition.

Claim 4

A process for preparing liquid, substantially gel-free, partially polymerized polyol(allyl carbonate) having from 20 to 50 percent allylic utilization, which process comprises (a) preparing a mixture of polyol(allyl carbonate) monomer and an organic solvent in which the monomer and the partially polymerized polyol(allyl carbonate) are soluble, said solvent being non-reactive chemically with said monomer and said partially polymerized polyol(allyl carbonate), and having a higher vapor pressure than said monomer, (b) polymerizing said monomer with free radical initiator until from 20 to 50 percent of the allylic carbon-carbon linkages are consumed, and (c) removing said solvent from the product of the polymerization to produce a gel-free, liquid, polymerizable composition.

Claim 5

A process for preparing liquid, substantially gel-free, partially polymerized polyol(allyl carbonate) having from 20 to 50 percent allylic utilization in admixture with cure enhancing additive, which process comprises (a) preparing a mixture of polyol(allyl carbonate) monomer and an organic solvent in which the monomer and the partially polymerized polyol(allyl carbonate) are soluble, said solvent being non-reactive chemically with said monomer and said partially polymerized polyol(allyl carbonate), and having a higher vapor pressure than said monomer, (b) polymerizing said monomer with free radical initiator until from 20 to 50 percent of the allylic carbon-carbon linkages are consumed, (c) to the resulting composition, adding from 5 to 30 weight percent, basis the partially polymerized monomer, of acrylate cure enhancing additive selected from the group consisting of (1) monofunctional acrylate monomer, (2) polyfunctional acrylate monomer, and (3) mixtures thereof, and (d) removing said solvent from said further composition to produce a gel-free, liquid, polymerizable composition.

Claim 6

A process for preparing liquid, substantially gel-free, partially polymerized polyol(allyl carbonate) having from 20 to 50 percent allylic utilization in admixture with cure enhancing additive, which process comprises (a) preparing a mixture of polyol(allyl carbonate) monomer and an organic solvent in which the monomer and the partially polymerized polyol(allyl carbonate) are soluble, said solvent being non-reactive chemically with said monomer and said partially polymerized polyol(allyl carbonate), and having a higher vapor pressure than said monomer, (b) polymerizing said monomer with free radical initiator until from 20 to 50 percent of the allylic carbon-carbon linkages are consumed, (c) to the resulting composition, adding from 5 to 30 weight percent, basis the partially polymerized monomer, of acrylate cure enhancing additive selected from the group consisting of (1) monofunctional acrylate monomer, (2) polyfunctional acrylate monomer, and (3) mixtures thereof, and (d) removing said solvent from said further composition to produce a gel-free, liquid, polymerizable composition.

Claim 7

The process of claim 1 wherein the peroxydicarbonate ester is selected from di-n-propyl peroxydicarbonate, diisopropyl peroxydicarbonate, disecondary butyl peroxydicarbonate, di(2-ethylhexyl) peroxydicarbonate, dicetylperoxydicarbonate, dicyclohexyl peroxydicarbonate, di(4-tertiarybutyl cyclohexyl) peroxydicarbonate and mixtures thereof.

Claim 8

The process of claim 4 wherein the polyol(allyl carbonate) is diethylene glycol bis(allyl carbonate).

Claim 9

The process of claim 2 wherein the polyol(allyl carbonate) monomer is represented by the graphic formula: ##STR17## wherein R 1 is an allyl radical represented by the graphic formula ##STR18## wherein R 0 is hydrogen, chlorine, bromine, or a C 1 -C 4 alkyl, R 2 is a polyvalent radical derived from an aliphatic or aromatic polyol containing from 2 to 5 hydroxy groups, and n is a whole integer from 2 to 5.

Claim 10

The process of claim 2 wherein the organic solvent is a halogenated C 1 -C 2 hydrocarbon.

Claim 11

The process of claim 2 wherein the ratio of organic solvent to monomer in said mixture is from about 0.5 to 5 milliliters of solvent to one gram of monomer.

Claim 12

The process of claim 8 wherein the solvent is selected from the group consisting of methyl chloride, methylene chloride, ethyl chloride, ethylene dichloride, 1,1,2-trichloro-1,2,2-trifluoroethane and mixtures of such solvents.

Claim 13

The process of claim 8 wherein said free radical initiator is organic peroxide initiator.

Claim 14

The process of claim 10 wherein the organic peroxide initiator is a peroxydicarbonate ester.

Claim 15

The process of claim 2 wherein the polyol(allyl carbonate) monomer is diethylene glycol bis(allyl carbonate), the organic solvent is a chlorinated C 1 -C 2 hydrocarbon, the free-radical initiator is used in amounts of from 0.1 to 1.5 weight percent, based on the monomer, and the polymerization temperature is from 28° C. to 100° C.