Monomeric composition of a diol bis(allyl carbonate), a dispersed polymer, and a multifunctional acrylate monomer, and polymers prepared therefrom

Claim 2

A composition of matter comprising: (a) an aliphatic diol bis(allyl carbonate); (b) an acrylate polymer; and (c) a multifunctional acrylate monomer.

Claim 3

The composition of claim 1 wherein said composition contains from about 1 part of polymer per hundred parts of diol bis(allyl carbonate) to about 100 parts of polymer per hundred parts of diol bis(allyl carbonate).

Claim 4

The composition of claim 1 wherein said composition contains from about 1 part of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate).

Claim 5

The composition of claim 3 wherein said composition contains: (a) from about 1 part of acrylate polymer per hundred parts of diol bis(allyl carbonate) to about 35 parts of acrylate polymer per hundred parts of diol bis(allyl carbonate); and (b) from about 1 part of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate); said composition having a pseudoplastic rheology with a shear stress of from 10 4 to 10 7 dynes per square centimeter at shear rates of from 10 1 to 10 4 per second.

Claim 6

The composition of claim 1 wherein the diol bis(allyl carbonate) monomer is represented by the formula ##STR17## where R 1 and R 3 are allyl groups independently represented by the formula ##STR18## where R 1 is chosen from the group consisting of hydrogen, fluorine, chlorine, bromine, and C 1 to C 4 alkyl groups, and R 2 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene polyether groups, alkylene carbonate groups, and mixtures thereof.

Claim 7

The composition of claim 1 wherein the copolymer is represented by the formula: ##STR19## where R 4 (CO)OH and R 5 (CO)OH are independently, chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, propyl acrylic acid, and butyl acrylic acid R 6 (OH) is allyl alcohol, and R 7 is chosen from the group consisting of H, and C 1 to C 4 alkyl groups.

Claim 8

The composition of claim 1 wherein the multifunctional acrylate monomer is represented by the formula: ##STR20## where n is from 2 to 5, R 9 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene carbonate groups, and mixtures thereof; and R 8 -(CO)OH is chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, and mixtures thereof.

Claim 9

The composition of claim 1 wherein (a) the diol bis(allyl carbonate) monomer is represented by the formula ##STR21## (b) the acrylate polymer is represented by the formula: ##STR22## (c) the multifunctional acrylate monomer is represented by the formula ##STR23## where n is from 2 to 5; (d) R 1 OH, R 3 OH, and R 6 OH are allyl alcohol and R 7 is chosen from the group consisting of H and C 1 to C 4 alkyl groups; (e) R 2 and R 9 are independently chosen from the group consisting of --CH 2 CH 2 --, --CH 2 CH 2 OCH 2 CH 2 --, --CH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 --, --C 3 H 6 --, --C 3 H 6 OC 3 H 6 --, --C 3 (H 6 OC 3 H 6 OC 3 H 6 --, and mixtures thereof; (f) R 4 , R 5 , and R 8 are independently chosen from the group consisting of CH 2 ═CH--, CH 2 ═C(CH 3 )--, and mixtures thereof; and (g) the composition contains (i) from about 1 part of copolymer per hundred parts of diol bis(allyl carbonate) to about 35 parts of the acrylate polymer per hundred parts of diol bis(allyl carbonate); and (ii) from about 1 part of the multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of the acrylate monomer per hundred parts of diol bis(allyl carbonate); said composition having a pseudoplastic rheology with a shear stress of from 10 4 to 10 7 dynes per square centimeter at shear rates of from 10 1 to 10 4 per second.

Claim 10

The polymeric product of a monomeric composition of (a) an aliphatic diol bis(allyl carbonate); (b) an acrylate polymer; and (c) a multifunctional acrylate monomer.

Claim 11

The polymeric product of a monomeric composition of (a) an aliphatic diol bis(allyl carbonate); (b) an acrylate polymer; and (c) a multifunctional acrylate monomer.

Claim 12

The polymeric product of claim 9 wherein said monomeric composition contains from about 1 part of acrylate polymer per hundred parts of diol bis(allyl carbonate) to about 100 parts of acrylate polymer per hundred parts of diol bis(allyl carbonate).

Claim 13

The polymeric product of claim 10 wherein said monomeric composition contains from about 1 part of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate).

Claim 14

The polymeric product of claim 11 wherein the diol bis(allyl carbonate) monomer is represented by the formula ##STR24## where R 1 and R 3 are allyl groups independently represented by the formula ##STR25## where R 1 is chosen from the group consisting of hydrogen, fluorine, chlorine, bromine, and C 1 to C 4 alkyl groups, and R 2 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene polyether groups, alkylene carbonate groups, and mixtures thereof.

Claim 15

The polymer product of claim 9 wherein the polymer is represented by the formula: ##STR26## where R 4 (CO)OH and R 5 (CO)OH are independently chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, propyl acrylic acid, and butyl acrylic acid, R 6 (OH) is allyl alcohol, and R 7 is chosen from the group consisting of H, and C 1 to C 4 alkyl groups.

Claim 16

The polymeric product of claim 9 wherein the multifunctional acrylate monomer is represented by the formula ##STR27## where n is from 2 to 5; R 9 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene carbonate groups, and mixtures thereof; and R 8 --(CO)OH is an chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, and mixtures thereof.

Claim 17

In a method of polymerizing a monomeric composition of a diol bis(allyl carbonate) having an acrylate polymer dispersed therethrough, the improvement comprising providing a multifunctional acrylate monomer in the monomeric composition.

Claim 18

In a method of polymerizing a monomeric composition of a diol bis(allyl carbonate) having an acrylate polymer dispersed therethrough, the improvement comprising providing a multifunctional acrylate monomer in the monomeric composition.

Claim 19

The method of claim 15 wherein said monomeric composition contains from about 1 part of acrylate polymer per hundred parts of diol bis(allyl carbonate) to about 35 parts of acrylate polymer per hundred parts of diol bis(allyl carbonate).

Claim 20

The method of claim 15 wherein said monomeric composition contains from about 1 part of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate).

Claim 21

The method of claim 15 wherein said monomeric composition contains: (a) from about 1 part of acrylate polymer per hundred parts of diol bis(allyl carbonate) to about 35 parts of acrylate polymer per hundred parts of diol bis(allyl carbonate); and (b) from about 1 part of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate) to about 20 parts of multifunctional acrylate monomer per hundred parts of diol bis(allyl carbonate); said composition having a pseudoplastic rheology with a shear stress of from 10 4 to 10 7 dynes per square centimeter at shear rates of from 10 1 to 10 4 per second.

Claim 22

The method of claim 15 wherein the diol bis(allyl carbonate) monomer is represented by the formula ##STR28## where R 1 and R 3 are allyl groups independently represented by the formula ##STR29## where R 1 is chosen from the group consisting of hydrogen, fluorine, chlorine, bromine, and C 1 to C 4 alkyl groups, and R 2 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene polyether groups, alkylene carbonate groups, and mixtures thereof.

Claim 23

The method of claim 15 wherein the acrylate polymer is represented by the formula: ##STR30## where R 4 (CO)OH and R 5 (CO)OH are independently chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, propyl acrylic acid, and butyl acrylic acid, R 6 (OH) is allyl alcohol, and R 7 is chosen from the group consisting of H, and C 1 to C 4 alkyl groups.

Claim 24

The method of claim 15 wherein the multifunctional acrylate monomer is represented by the formula ##STR31## where n is from 2 to 5; R 9 is chosen from the group consisting of alkylene groups, alkylene ether groups, alkylene carbonate groups, and mixtures thereof; and R 8 --(CO)OH is chosen from the group consisting of acrylic acid, methacrylic acid, ethyl acrylic acid, and mixtures thereof.