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US5017271A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for printed circuit board pattern making using selectively etchable metal layers

Assignee: Gould Electronics Inc
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Filing: 1990-08-24
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Granted: 1991-05-21
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Expires: 2010-08-24
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Abstract

Abstract The present invention provides a method for producing high density electronic circuit boards comprising the steps of depositing a layer of a first metal upon a layer of foil to produce a composite then attaching the composite to an insulative support to produce a laminate. The layer of foil is then removed from the layer of first metal. Photoresist is then applied to the layer of first metal, exposed and developed. During the development of the photoresist portions of the photoresist are removed from the layer of first metal. A layer of third metal is then plated upon the portions of the layer of first metal that are not covered by the photoresist. All remaining photoresist and the portions of the layer of first metal which are not covered by the third metal are then removed producing a finished fine-line pattern having conductive and insulative areas. The finished fine-line pattern may then be utilized to produce a circuit board.

Inventors

  • 👤 Christopher J. Whewell
  • 👤 Sidney J. Clouser
  • 👤 Chin-Ho Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:13
CPC Classifications
C; C23; C23F; C23F1/00; C23F1/02; H; H05; H05K; H05K3/00; H05K3/02; H05K3/022; H05K3/025; H05K3/10; H05K3/108; H05K2203/00; H05K2203/01; H05K2203/0147; H05K2203/0152; H05K2203/03; H05K2203/0376; H05K2203/07; H05K2203/0703; H05K2203/0726; H05K2203/0779; H05K2203/0786; H05K2203/0793

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 152 words
A method of producing a circuit board comprising the steps of: (A) depositing a layer of a first metal upon a layer of a second metal having a different chemical composition than the layer of first metal; (B) attaching the layers of first and second metal to a support such that the layer of first metal is located between the support and the layer of second metal; (C) removing the layer of second metal from the layer of first metal to form a thin metal laminate; (D) applying a photoresist to the layer of first metal and irradiating portions of the photoresist; (E) removing portions of the photoresist so as to uncover portions of the layer of first metal and form a pattern; and (F) depositing a layer of third metal having a different chemical composition than the layer of first metal upon the uncovered portions of the layer of first metal.
Claim 2
Independent Claim 152 words
A method of producing a circuit board comprising the steps of: (A) depositing a layer of a first metal upon a layer of a second metal having a different chemical composition than the layer of first metal; (B) attaching the layers of first and second metal to a support such that the layer of first metal is located between the support and the layer of second metal; (C) removing the layer of second metal from the layer of first metal to form a thin metal laminate; (D) applying a photoresist to the layer of first metal and irradiating portions of the photoresist; (E) removing portions of the photoresist so as to uncover portions of the layer of first metal and form a pattern; and (F) depositing a layer of third metal having a different chemical composition than the layer of first metal upon the uncovered portions of the layer of first metal.
Claim 3
Dependent Claim 62 words
A method of producing a circuit board as set forth in claim 1 including subsequent to said step (F) the steps of: (G) removing from the layer of first metal any remaining photoresist; and (H) removing from the support the portions of the layer of first metal which have no third metal deposited thereon so as to form a finished fine-line pattern.
Claim 4
Dependent Claim 23 words
A method of producing a circuit board as set forth in claim 1 wherein the layer of second metal comprises a metallic foil.
Claim 5
Dependent Claim 23 words
A method of producing a circuit board as set forth in claim 1 wherein the layer of second metal comprises copper (Cu) foil.
Claim 6
Dependent Claim 21 words
A method of producing a circuit board as set forth in claim 1 wherein said support comprises a layer of resin.
Claim 7
Dependent Claim 22 words
A method of producing a circuit board as set forth in claim 1 wherein said layer of first metal comprises chromium (Cr).
Claim 8
Dependent Claim 50 words
A method of producing a circuit board as set forth in claim 1 wherein the layer of first metal comprises chromium (Cr), the layer of second metal comprises copper (Cu) foil, and during said step (C) the layer of second metal is chemically removed from the layer of first metal.
Claim 9
Dependent Claim 38 words
A method of producing a circuit board as set forth in claim 7 wherein during said step (C) the chemical removal of the layer of second metal is accomplished utilizing a solution of cupric chloride (CuCl 2 ).
Claim 10
Dependent Claim 22 words
A method of producing a circuit board as set forth in claim 1 wherein the layer of third metal comprises nickel (Ni).
Claim 11
Dependent Claim 49 words
A method of producing a circuit board as set forth in claim 2 wherein the layer of first metal comprises chromium (Cr), the layer of second metal comprises copper (Cu), and during said step (H) the portions of the layer of first metal are chemically removed from the support.
Claim 12
Dependent Claim 51 words
A method of producing a circuit board as set forth in claim 10 wherein during said step (H) the uncovered portions of the layer of first metal are chemically removed utilizing a solution of sulfuric acid (H 2 SO 4 ) and touching the layer of first metal with zinc (Zn).
Claim 13
Dependent Claim 22 words
A method of producing a circuit board as set forth in claim 2 wherein the layer of first metal comprises nickel (Ni).
Claim 14
Dependent Claim 40 words
A method of producing a circuit board as set forth in claim 12 wherein during said step (C) the second layer of metal is removed utilizing a solution containing water (H 2 O) laden with ammonia (NH 3 ) gas.
Claim 15
Dependent Claim 38 words
A method of producing a circuit board as set forth in claim 12 wherein the layer of second metal comprises copper (Cu) and during said step (H) the portions of the layer of first metal are chemically removed.
Claim 16
Dependent Claim 47 words
A method of producing a circuit board as set forth in claim 14 wherein during said step (H) the portions of the layer of first metal are removed utilizing a solution comprising hydrogen peroxide (H 2 O 2 ) and ammonium bifluoride (NH 4 HF 2 ).
Claim 17
Dependent Claim 21 words
A method of producing a circuit board as set forth in claim 1 wherein the layer of first metal comprises tin.
Claim 18
Dependent Claim 38 words
A method of producing a circuit board as set forth in claim 16 wherein during said step (C) the layer of second metal is removed utilizing an etching solution containing water (H 2 O) laden with ammonia gas.
Claim 19
Dependent Claim 22 words
A method of producing a circuit board as set forth in claim 16 wherein the layer of second metal comprises copper (Cu).
Claim 20
Dependent Claim 33 words
A method of producing a circuit board as set forth in claim 18 wherein during said step (H) the portions of the layer of first metal are chemically removed utilizing a stripping solution.
Claim 21
Independent Claim 184 words
A method of producing a finished fine-line pattern for use in producing a printed circuit board comprising the steps of: (A) electrodepositing a layer of a first metal upon a layer of a second metal so as to form a metal composite; (B) laminating the metal composite to a support and forming a metals layers laminate wherein the layer of first metal is disposed between the support and the layer of second metal; (C) removing the layer of second metal from the laminate to form a thin metal laminate; (D) applying a photoresist to the layer of first metal and irradiating portions of the photoresist; (E) removing portions of the photoresist so as to expose portions of the layer of first metal; (F) depositing a layer of third metal upon the exposed portions of the layer of first metal; (G) removing from the layer of first metal any remaining photoresist; (H) removing from the support the portions of the layer of first metal which have no third metal deposited thereon so as to produce a finished fine-line pattern having conductive areas and insulative areas.
Claim 22
Independent Claim 184 words
A method of producing a finished fine-line pattern for use in producing a printed circuit board comprising the steps of: (A) electrodepositing a layer of a first metal upon a layer of a second metal so as to form a metal composite; (B) laminating the metal composite to a support and forming a metals layers laminate wherein the layer of first metal is disposed between the support and the layer of second metal; (C) removing the layer of second metal from the laminate to form a thin metal laminate; (D) applying a photoresist to the layer of first metal and irradiating portions of the photoresist; (E) removing portions of the photoresist so as to expose portions of the layer of first metal; (F) depositing a layer of third metal upon the exposed portions of the layer of first metal; (G) removing from the layer of first metal any remaining photoresist; (H) removing from the support the portions of the layer of first metal which have no third metal deposited thereon so as to produce a finished fine-line pattern having conductive areas and insulative areas.
Claim 23
Dependent Claim 22 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein the support comprises an insulative resin substrate.
Claim 24
Dependent Claim 56 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein during said step (A) the layer of second metal comprises a metal foil and the finished fine-line pattern includes a circuit pattern consisting of less than about 0.0016 and less than about 0.0020 of an inch conductive lines and insulative spaces.
Claim 25
Dependent Claim 31 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein during said step (E) the non-irradiated portions of the photoresist are removed utilizing a developing solution.
Claim 26
Dependent Claim 31 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein during said step (G) the remaining photoresist is removed utilizing a solution of potassium hydroxide (KOH).
Claim 27
Dependent Claim 36 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein the layer of second metal comprises copper (Cu) foil having a surface with a matte finish of about 10 microns Rtm.
Claim 28
Dependent Claim 29 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein the layer of first metal has a thickness of less than about five microns.
Claim 29
Dependent Claim 29 words
A method of producing a finished fine-line pattern as set forth in claim 20 wherein the layer of second metal has a thickness of less than about 35 microns.
Claim 30
Independent Claim 133 words
A method of producing a fine-line pattern for use in producing a circuit board comprising the steps of: (A) electrodepositing a layer of a first metal upon a layer of a second metal comprising a section of copper (Cu) foil so as to form a composite; (B) laminating the composite to a substrate so as to form a laminate wherein the first layer of metal is located between the substrate and the copper foil; (C) chemically removing the copper foil from the laminate; (D) applying a photoresist to the layer of first metal and exposing portions of the photoresist; (E) removing portions of the photoresist thereby uncovering portions of the layer of first metal; and (F) electrodepositing a layer of a third metal upon the uncovered portions of the layer of first metal.
Claim 31
Independent Claim 133 words
A method of producing a fine-line pattern for use in producing a circuit board comprising the steps of: (A) electrodepositing a layer of a first metal upon a layer of a second metal comprising a section of copper (Cu) foil so as to form a composite; (B) laminating the composite to a substrate so as to form a laminate wherein the first layer of metal is located between the substrate and the copper foil; (C) chemically removing the copper foil from the laminate; (D) applying a photoresist to the layer of first metal and exposing portions of the photoresist; (E) removing portions of the photoresist thereby uncovering portions of the layer of first metal; and (F) electrodepositing a layer of a third metal upon the uncovered portions of the layer of first metal.
Claim 32
Dependent Claim 50 words
A method of producing a fine-line pattern as set forth in claim 28 including the steps of: (G) removing from the layer of first metal any remaining photoresist; and (H) chemically removing from the substrate the portions of the layer of first metal which have no third metal deposited thereon.
Claim 33
Dependent Claim 20 words
A method of producing a fine-line pattern as set forth in claim 28 wherein the third metal comprises copper (Cu).

References Cited (Backward Citations)

GB690691A Cited
US3469982A Cited
US3857681A Cited
US3981691A Cited
US4049481A Cited
US4082620A Cited
US4863808A Cited
US4705592A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-20 1994-11-19 1995-05-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-20 1998-11-19 1999-05-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-20 2002-11-19 2003-05-21 $7700.00 Window Closed / Lapsed

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