Encapsulated toner compositions

Claim 2

An encapsulated toner composition comprised of a core comprised of pigments or dyes and a polysiloxane incorporated core binder resin, which core is encapsulated in a shell and wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer derived from functionalized polysiloxanes capable of undergoing addition polymerization, and a monomer; and wherein the shell is selected from the group consisting of polyurea, polyamide, polyester, polyurethane and mixtures thereof.

Claim 3

A toner in accordance with claim 1 wherein the polysiloxane-incorporated binder resin is derived from the copolymerization of an addition-type monomer selected form the group consisting of propyl acrylate, propyl methacrylate, butyl acrylate, butyl methacrylate, pentyl acrylate, pentyl methacrylate, hexyl acrylate, hexyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, lauryl acrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, benzyl acrylate, benzyl methacrylate, ethoxypropyl acrylate, ethoxypropyl methacrylate, heptyl acrylate, heptyl methacrylate, isobutyl acrylate, isobutyl methacrylate, methylbutyl acrylate, methylbutyl methacrylate, tolyl acrylate, tolyl methacrylate, styrene, dodecyl styrene, hexyl methyl styrene, nonyl styrene, or tetradecyl styrene, and a functionalized polysiloxane.

Claim 4

A toner in accordance with claim 1 wherein the polysiloxane is represented by Formulas I, II, III, IV, V, or VI, wherein R' is alkylene, arylene, or the substituted derivatives thereof; R, R" and R'" are independently selected from the group consisting of alkyl and substituted alkyl; n represents the number of segments; and y and z are mole fraction numbers wherein y is greater than 0, and the sum of x+y is equal to 1.

Claim 5

A toner in accordance with claim 1 wherein the core binder is a copolymer derived from the copolymerization of an acryloxy-, a methacryloxy-, or a styryl-functionalized polysiloxane and an acrylate, a methacrylate, or a styryl monomer.

Claim 6

A toner in accordance with claim 1 wherein the core binder resin is comprised of a copolymer of acryloxy- or methacryloxy-functionalized polysiloxane and alkyl acrylate or alkyl methacrylate.

Claim 7

A toner in accordance with claim 1 wherein the core binder resin is comprised of a crosslinked copolymer of acryloxy- or methacryloxy-functionalized polysiloxane and alkyl acrylate or alkyl methacrylate.

Claim 8

A toner in accordance with claim 6 wherein the alkyl group contains from about 1 to about 30 carbon atoms, and preferably from about 3 to about 18 carbon atoms.

Claim 9

A toner in accordance with claim 1 wherein the core binder resin is comprised of a copolymer of styryl-functionalized polysiloxane and an addition monomer.

Claim 10

A toner in accordance with claim 1 wherein the functionalized polysiloxane is selected from the group consisting of a mono(acryloxyalkyl)-functionalized polydialkylsiloxane, a mono(methacryloxyalkyl)-functionalized polydialkylsiloxane, a bis(acryloxyalkyl)-functionalized polydialkylsiloxane, a bis(methacryloxy)-functionalized polydialkylsiloxane, a poly(acryloxy)-functionalized and a poly(methacryloxy)-functionalized dialkylsiloxane polymer.

Claim 11

A toner in accordance with claim 9 wherein the functionalized polysiloxane is selected from the group consisting of mono(acryloxyalkyl)-functionalized polydimethylsiloxane, a mono(methacryloxyalkyl)-functionalized polydimethylsiloxane, a bis(acryloxyalkyl)-functionalized polydimethylsiloxane, a bis(methacryloxy)-functionalized polydimethylsiloxane, a poly(acryloxy)-functionalized and a poly(methacryloxy)-functionalized polydimethylsiloxane polymer.

Claim 12

A toner in accordance with claim 1 wherein the functionalized polysiloxane has a molecular weight of from about 500 to about 60,000.

Claim 13

A toner in accordance with claim 1 wherein the functionalized polysiloxane has a molecular weight of from about 5,000 to about 35,000.

Claim 14

A toner in accordance with claim 1 wherein the pigment is carbon black, iron oxides, magnetites, or mixtures thereof.

Claim 15

A toner in accordance with claim 13 wherein the magnetite is selected from the group consisting of Mapico Blacks and surface treated magnetites.

Claim 16

A toner in accordance with claim 1 wherein the pigment is selected from the group consisting of cyan, yellow, magent, red, green, blue, brown, and mixtures thereof.

Claim 17

A toner in accordance with claim 15 wherein the pigment is selected from the group consisting of Heliogen Blue L6900, D6840, D7080, D7020, Pylam Oil Blue, Pylam Oil Yellow, Pigment Blue 1, Pigment Violet 1, Pigment Red 48, Lemon Chrome Yellow DCC 1026, E.D. Toluidine Red, Bon Red C, NOVAperm Yellow FGL, Hostaperm Pink E, Cinquasia Magenta, Oil Red 2144, 2,9-dimethyl-substituted quinacridone and anthraquinone dye, CI Dispersed Red 15, diazo dye, CI Solvent Red 19, copper tetra-4(octadecyl sulfonamido) phthalocyanine, X-copper phthalocyanine pigment, CI Pigment Blue, Anthrathrene Blue, Special Blue X-2137, diarylide yellow 3,3- dichlorobenzidene acetoacetanilides, a monoazo pigment, CI Solvent Yellow 16, a nitrophenyl amine sulfonamide, CI Dispersed Yellow 33, 2,5-dimethoxy-4-sulfonanilide phenylazo-4'-chloro-2,5-dimethoxy acetoacetanilide, and Permanent Yellow FGL.

Claim 18

A toner in accordance with claim 1 wherein the shell represents from about 5 to about 30 percent by weight of toner, the core binder resin represents from about 20 to about 90 percent by weight of the toner, and the pigment or dye represent from about 2 to about 65 percent by weight of the toner.

Claim 19

A toner in accordance with claim 1 wherein the average toner shape is spherical, and the average toner particle diameter is from about 5 to about 25 microns.

Claim 20

A toner in accordance with claim 1 containing surface additives.

Claim 21

A toner in accordance with claim 19 wherein the surface additives are metal salts, metal salts of fatty acids or colloidal silicas.

Claim 22

A toner in accordance with claim 19 wherein a zinc stearate additive is selected.

Claim 23

A toner in accordance with claim 19 wherein the additives are present in an amount of from about 0.1 to about 5.0 weight percent.

Claim 24

A toner in accordance with claim 1 wherein the toner shell is prepared by interfacial polymerization.

Claim 25

A toner in accordance with claim 1 wherein the shell surface contains conductive components.

Claim 26

A toner in accordance with claim 24 wherein the conductive components are comprised of carbon blacks, graphite, or mixtures thereof.

Claim 27

A toner in accordance with claim 1 wherein the core binder resin is obtained by free radical polymerization of a functionalized polysiloxane or polysiloxanes, and an addition monomer or monomers.

Claim 28

A toner in accordance with claim 1 wherein the core binder resin contains a crosslinked polysiloxane-incorporated addition polymer.

Claim 29

A toner in accordance with claim 1 wherein mixtures of dyes and pigments are selected.

Claim 30

A toner in accordance with claim 1 wherein mixtures of dyes and pigments are selected.

Claim 31

An encapsulated toner composition comprised of a core comprised of a polysiloxane-incorporated polymer resin, colorants, and a shell thereover wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of functionalized polysiloxanes capable of undergoing addition polymerization, and a monomer.

Claim 32

An encapsulated toner composition comprised of a core comprised of a polysiloxane-incorporated polymer resin, colorants, and a shell thereover wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of functionalized polysiloxanes capable of undergoing addition polymerization, and a monomer.

Claim 33

A toner in accordance with claim 30 wherein the polymer resin is comprised of a crosslinked copolymer of a functionalized polysiloxane and an acrylate, methacrylate, or styryl-functionalized monomer or monomers.

Claim 34

A toner in accordance with claim 31 wherein the functionalized polysiloxane is acryloxy-, methacryloxy-functionalized polydimethylsiloxane, or styryl-functionalized polydimethylsiloxane.

Claim 35

A toner in accordance with claim 30 wherein the colorant is carbon black, magnetites, or mixtures thereof.

Claim 36

A toner in accordance with claim 30 wherein the colorant present in the core is black, cyan, magenta, yellow, red, blue, green, brown, or mixtures thereof.

Claim 37

A toner in accordance with claim 30 wherein the core monomer or monomers for the core polymer are selected from the group consisting of alkyl acrylates, alkyl methacrylates, styrene and styrene derivatives.

Claim 38

A toner in accordance with claim 30 wherein the core is a binder resin of a copolymer of a functionalized polysiloxane and a core monomer selected from the group consisting of n-butyl acrylate, s-butyl acrylate, isobutyl acrylate, n-butyl methacrylate, s-butyl methacrylate, isobutyl methacrylate, benzyl acrylate, benzyl methacrylate, propyl acrylate, isopropyl acrylate, hexyl acrylate, cyclohexyl acrylate, hexyl methacrylate, cyclohexyl methacrylate, lauryl acrylate, lauryl methacrylate, pentyl acrylate, pentyl methacrylate, stearyl acrylate, stearyl methacrylate, ethoxypropyl acrylate, ethoxypropyl methacrylate, heptyl acrylate, heptyl methacrylate, methylbutyl acrylate, methylbutyl methacrylate, m-tolyl acrylate, dodecyl styrene, hexylmethyl styrene, nonyl styrene, and tetradecyl styrene.

Claim 39

A toner in accordance with claim 30 wherein a polymeric shell is selected.

Claim 40

A toner in accordance with claim 30 wherein the shell is a crosslinked or an uncrosslinked polyurea, polyester, polyurethane, polyamide polymer, or mixtures thereof.

Claim 41

A toner in accordance with claim 30 wherein the polysiloxane is represented by the Formulas I, II, III, IV, V, or VI, wherein R' is alkylene, arylene, or the substituted derivatives thereof; R, R" and R'" are independently selected from the group consisting of alkyl and substituted alkyl; n represents the number of segments; and y and z are mole fraction numbers wherein y is greater than 0, and the sum of x+y is equal to 1.

Claim 42

A toner in accordance with claim 39 wherein the polysiloxane contains at least one addition type functionality.

Claim 43

An encapsulated toner comprised of a core comprised of a pigment and a polysiloxane incorporated core binder resin, and wherein the aforementioned core is encapsulated within a polymeric shell wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of a functionalized polysiloxane capable of undergoing addition polymerization, and a monomer.

Claim 44

An encapsulated toner comprised of a core comprised of a pigment and a polysiloxane incorporated core binder resin, and wherein the aforementioned core is encapsulated within a polymeric shell wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of a functionalized polysiloxane capable of undergoing addition polymerization, and a monomer.

Claim 45

An encapsulated toner composition comprised of a core comprised of pigment, a core resin binder comprised of a copolymer of a functionalized polysiloxane capable of undergoing addition polymerization, and a monomer; and wherein the aforementioned core components are encapsulated within a polymeric shell wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of functionalized polysiloxanes capable of undergoing addition polymerization, and a monomer.

Claim 46

An encapsulated toner composition comprised of a core comprised of pigment, a core resin binder comprised of a copolymer of a functionalized polysiloxane capable of undergoing addition polymerization, and a monomer; and wherein the aforementioned core components are encapsulated within a polymeric shell wherein the polysiloxane-incorporated core binder resin is comprised of a copolymer of functionalized polysiloxanes capable of undergoing addition polymerization, and a monomer.