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US5011516A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic oxidation of SO2 to SO3 in the presence of fly ash

Assignee: Electric Power Research Institute
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Filing: 1989-11-06
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Granted: 1991-04-30
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Expires: 2009-11-06
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Abstract

Abstract A method is provided for improving the electrostatic precipitation of particulates, i.e., from combustion gases by withdrawing part of the flue gases, catalytically converting the SO 2 to SO 3 and reinjecting it into the main flue stream.

Inventors

  • 👤 Ralph A. Altman
  • 👤 John P. Gooch
  • 👤 Edward B. Dismukes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 07:57
CPC Classifications
B; B03; B03C; B03C3/00; B03C3/01; B03C3/013

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 156 words
A combustion gas conditioning method whereby particulates are removed from the main stream of combustion gases containing sulfur dioxide in a flue by electrostatic precipitation means, said method comprising the steps of withdrawing from a location upstream of said electrostatic precipitation means a minor amount of the total volume of said combustion gases entering said flue, including the particulates associated with said minor amount of combustion gases; contacting said minor amount of combustion gases and particulates associated therewith with catalytic means to convert SO 2 contained therein to SO 3 ; and mixing said minor amount of combustion gases and SO 3 into said main stream of combustion gases and subjecting the mixture formed thereby to electrostatic precipitation; wherein said catalytic means is exposed to said combustion gases within an open gas flow passage whereby particulates freely flow therethrough without substantially interfering with the catalytic conversion of SO 2 to SO 3 by said catalytic means.
Claim 2
Dependent Claim 156 words
A combustion gas conditioning method whereby particulates are removed from the main stream of combustion gases containing sulfur dioxide in a flue by electrostatic precipitation means, said method comprising the steps of withdrawing from a location upstream of said electrostatic precipitation means a minor amount of the total volume of said combustion gases entering said flue, including the particulates associated with said minor amount of combustion gases; contacting said minor amount of combustion gases and particulates associated therewith with catalytic means to convert SO 2 contained therein to SO 3 ; and mixing said minor amount of combustion gases and SO 3 into said main stream of combustion gases and subjecting the mixture formed thereby to electrostatic precipitation; wherein said catalytic means is exposed to said combustion gases within an open gas flow passage whereby particulates freely flow therethrough without substantially interfering with the catalytic conversion of SO 2 to SO 3 by said catalytic means.
Claim 3
Dependent Claim 29 words
A method according to claim 1 wherein said minor amount of combustion gases is removed at a temperature in the range of about 750°-900° F. from said flue gases.
Claim 4
Dependent Claim 20 words
A method according to claim 1 wherein said combustion gases contain less than 0.1% by volume of SO 2 .
Claim 5
Dependent Claim 31 words
A method according to claim 1 wherein said combustion gases and SO 3 are remixed with said main stream of combustion gases at a temperature in the range of 250°-400° F.
Claim 6
Dependent Claim 14 words
A method according to claim 1 wherein said catalytic means comprises alkali-modified vanadium pentoxide.
Claim 7
Dependent Claim 27 words
A method according to claim 5 wherein the catalytic conversion efficiency of SO 2 to SO 3 by said catalytic means is greater or equal to 50%.
Claim 8
Dependent Claim 26 words
A method according to claim 1 wherein said minor amount of combustion gases comprises from 1-5% by volume of the total combustion gases entering said flue.
Claim 9
Dependent Claim 14 words
A method according to claim 1 wherein said gas flow passages are substantially parallel.
Claim 10
Dependent Claim 12 words
A method according to claim 8 wherein said passages comprise hollow tubes.
Claim 11
Dependent Claim 18 words
A method according to claim 8 wherein said passages are formed by contiguous walls in a honeycomb configuration.
Claim 12
Dependent Claim 27 words
A method according to claim 9 or 10 wherein the minimum transverse dimension between opposing surfaces within each of said passages is at least about 0.25 inches.

References Cited (Backward Citations)

US3581463A Cited
US3689213A Cited
US3993429A Cited
US3993429B1 Cited
US4770674A Cited
US4770674B1 Cited
US4770674B2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-04-29 1994-10-29 1995-04-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-04-29 1998-10-29 1999-04-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-04-29 2002-10-29 2003-04-30 $7700.00 Window Closed / Lapsed

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