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US5010144A
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Copolymer-containing compositions from substituted triazine-capped polyphenylene ethers
Assignee: General Electric Co
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Filing: 1990-06-07
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Granted: 1991-04-23
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Expires: 2010-06-07
Abstract
Abstract Substituted alkoxy-or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymer containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.
Inventors
- 👤 Ott Phanstiel, IV
- 👤 Sterling B. Brown
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 13:22
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C08G81/00; C08L67/00; C08L77/00; C08L77/12; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
192 words
A composition comprising copolymers prepared by the reaction of a polymer containing reactive groups with a substituted alkoxy- or alkylthio-triazine-capped polyphenylene ether having end groups of the formula ##STR13## wherein: each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 ; X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary or secondary alkyl or a non hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 2
Dependent Claim
192 words
A composition comprising copolymers prepared by the reaction of a polymer containing reactive groups with a substituted alkoxy- or alkylthio-triazine-capped polyphenylene ether having end groups of the formula ##STR13## wherein: each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 ; X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary or secondary alkyl or a non hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 3
Dependent Claim
21 words
A composition according to claim 1 wherein the reactive groups are amine, hydroxy, thio or carboxy groups or functional derivatives thereof.
Claim 4
Dependent Claim
14 words
A composition according to claim 2 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether).
Claim 5
Dependent Claim
16 words
A composition according to claim 3 wherein X 1 is an alkyl, cycloalkyl or aromatic radical.
Claim 6
Dependent Claim
20 words
A composition according to claim 4 wherein the polymer containing reactive groups is a polyester, polyamide or carboxy-functionalized olefin polymer.
Claim 7
Dependent Claim
15 words
A composition according to claim 5 wherein each Z is oxygen and n is 1.
Claim 8
Dependent Claim
16 words
A composition according to claim 6 wherein each R 1 and each R 3 is hydrogen.
Claim 9
Dependent Claim
17 words
A composition according to claim 7 wherein X 1 is a primary or secondary lower alkyl radical.
Claim 10
Dependent Claim
18 words
A composition according to claim 7 wherein X 1 is a monocyclic aromatic radical containing 6-10 carbon atoms.
Claim 11
Dependent Claim
11 words
A composition according to claim 9 wherein X 1 is 2,4,6-trimethylphenyl.
Claim 12
Dependent Claim
17 words
A composition according to claim 7 wherein the polymer containing reactive groups is a polyester or polyamide.
Claim 13
Dependent Claim
12 words
A composition according to claim 6 which also contains an impact modifier.
Claim 14
Dependent Claim
157 words
A composition comprising copolymers prepared by the reaction of a polymer containing groups capable of nucleophilic aliphatic substitution with a product prepared by effecting reaction, in the presence of an alkaline reagent, between a polyphenylene ether and a substituted alkoxy- or alkylthiochlorotriazine of the formula ##STR15## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR16## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary of secondary alkyl or a non-hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-31 3.
Claim 15
Dependent Claim
157 words
A composition comprising copolymers prepared by the reaction of a polymer containing groups capable of nucleophilic aliphatic substitution with a product prepared by effecting reaction, in the presence of an alkaline reagent, between a polyphenylene ether and a substituted alkoxy- or alkylthiochlorotriazine of the formula ##STR15## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR16## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary of secondary alkyl or a non-hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-31 3.
Claim 16
Dependent Claim
21 words
A composition according to claim 13 wherein the reactive groups are amine, hydroxy, thio or carboxy groups or functional derivatives thereof.
Claim 17
Dependent Claim
14 words
A composition according to claim 14 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether).
Claim 18
Dependent Claim
16 words
A composition according to claim 15 wherein X 1 is an alkyl, cycloalkyl or aromatic radical.
Claim 19
Dependent Claim
20 words
A composition according to claim 16 wherein the polymer containing reactive groups is a polyester, polyamide or carboxy-functionalized olefin polymer.
Claim 20
Dependent Claim
24 words
A composition according to claim 17 wherein each Z is oxygen, n is 1 and each R 1 and each R 3 is hydrogen.
Claim 21
Dependent Claim
18 words
A composition according to claim 18 wherein X 1 is a monocyclic aromatic radical containing 6-10 carbon atoms.
Claim 22
Dependent Claim
17 words
A composition according to claim 18 wherein the polymer containing reactive groups is a polyester or polyamide.
Claim 23
Dependent Claim
12 words
A composition according to claim 19 which also contains an impact modifier.
References Cited (Backward Citations)
EP0347828A2
Cited
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