Patent US5010144A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5010144A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymer-containing compositions from substituted triazine-capped polyphenylene ethers

Assignee: General Electric Co
•
Filing: 1990-06-07
•
Granted: 1991-04-23
•
Expires: 2010-06-07
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Substituted alkoxy-or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymer containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.

Inventors

  • 👤 Ott Phanstiel, IV
  • 👤 Sterling B. Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 13:22
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C08G81/00; C08L67/00; C08L77/00; C08L77/12; Y; Y10; Y10S; Y10S525/00; Y10S525/905

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 192 words
A composition comprising copolymers prepared by the reaction of a polymer containing reactive groups with a substituted alkoxy- or alkylthio-triazine-capped polyphenylene ether having end groups of the formula ##STR13## wherein: each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 ; X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary or secondary alkyl or a non hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 2
Dependent Claim 192 words
A composition comprising copolymers prepared by the reaction of a polymer containing reactive groups with a substituted alkoxy- or alkylthio-triazine-capped polyphenylene ether having end groups of the formula ##STR13## wherein: each Q 1 is independently halogen, primary or secondary lower alkyl, phenyl, haloalkyl, aminoalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms separate the halogen and oxygen atoms; each Q 2 is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy as defined for Q 1 ; X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary or secondary alkyl or a non hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 3
Dependent Claim 21 words
A composition according to claim 1 wherein the reactive groups are amine, hydroxy, thio or carboxy groups or functional derivatives thereof.
Claim 4
Dependent Claim 14 words
A composition according to claim 2 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether).
Claim 5
Dependent Claim 16 words
A composition according to claim 3 wherein X 1 is an alkyl, cycloalkyl or aromatic radical.
Claim 6
Dependent Claim 20 words
A composition according to claim 4 wherein the polymer containing reactive groups is a polyester, polyamide or carboxy-functionalized olefin polymer.
Claim 7
Dependent Claim 15 words
A composition according to claim 5 wherein each Z is oxygen and n is 1.
Claim 8
Dependent Claim 16 words
A composition according to claim 6 wherein each R 1 and each R 3 is hydrogen.
Claim 9
Dependent Claim 17 words
A composition according to claim 7 wherein X 1 is a primary or secondary lower alkyl radical.
Claim 10
Dependent Claim 18 words
A composition according to claim 7 wherein X 1 is a monocyclic aromatic radical containing 6-10 carbon atoms.
Claim 11
Dependent Claim 11 words
A composition according to claim 9 wherein X 1 is 2,4,6-trimethylphenyl.
Claim 12
Dependent Claim 17 words
A composition according to claim 7 wherein the polymer containing reactive groups is a polyester or polyamide.
Claim 13
Dependent Claim 12 words
A composition according to claim 6 which also contains an impact modifier.
Claim 14
Dependent Claim 157 words
A composition comprising copolymers prepared by the reaction of a polymer containing groups capable of nucleophilic aliphatic substitution with a product prepared by effecting reaction, in the presence of an alkaline reagent, between a polyphenylene ether and a substituted alkoxy- or alkylthiochlorotriazine of the formula ##STR15## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR16## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary of secondary alkyl or a non-hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-31 3.
Claim 15
Dependent Claim 157 words
A composition comprising copolymers prepared by the reaction of a polymer containing groups capable of nucleophilic aliphatic substitution with a product prepared by effecting reaction, in the presence of an alkaline reagent, between a polyphenylene ether and a substituted alkoxy- or alkylthiochlorotriazine of the formula ##STR15## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR16## X 2 is a group displaceable by nucleophilic aliphatic substitution; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen, C 1-4 primary of secondary alkyl or a non-hydrocarbon substituent substantially inert to displacement by nucleophilic moieties; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-31 3.
Claim 16
Dependent Claim 21 words
A composition according to claim 13 wherein the reactive groups are amine, hydroxy, thio or carboxy groups or functional derivatives thereof.
Claim 17
Dependent Claim 14 words
A composition according to claim 14 wherein the polyphenylene ether is a poly(2,6-dimethyl-1,4-phenylene ether).
Claim 18
Dependent Claim 16 words
A composition according to claim 15 wherein X 1 is an alkyl, cycloalkyl or aromatic radical.
Claim 19
Dependent Claim 20 words
A composition according to claim 16 wherein the polymer containing reactive groups is a polyester, polyamide or carboxy-functionalized olefin polymer.
Claim 20
Dependent Claim 24 words
A composition according to claim 17 wherein each Z is oxygen, n is 1 and each R 1 and each R 3 is hydrogen.
Claim 21
Dependent Claim 18 words
A composition according to claim 18 wherein X 1 is a monocyclic aromatic radical containing 6-10 carbon atoms.
Claim 22
Dependent Claim 17 words
A composition according to claim 18 wherein the polymer containing reactive groups is a polyester or polyamide.
Claim 23
Dependent Claim 12 words
A composition according to claim 19 which also contains an impact modifier.

References Cited (Backward Citations)

EP0347828A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-04-22 1994-10-22 1995-04-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-04-22 1998-10-22 1999-04-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-04-22 2002-10-22 2003-04-23 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag