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Blends of high nitrile copolymers and thermoplastic polymers

Assignee: Standard Oil Co
•
Filing: 1988-08-22
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Granted: 1991-04-02
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Expires: 2008-08-22
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Abstract

Abstract A polymer blend comprises a high nitrile copolymer and a compatible thermoplastic polymer or copolymer containing polar groups, formed from monomers selected from the group consisting of alkylacrylamides, aliphatic and cyclic methacrylates, unsaturated carboxylic acid anhydrides, vinyl pyrrolidones, heterocyclic ring compounds containing two hetero atoms, lactones and phosphorus-containing monomers that form highly crystalline polymers. Such blends can be used to form films and membranes having improved thermal, mechanical and optical properties.

Inventors

  • 👤 Elena S. Percec
  • 👤 Doreen Y. Takigawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:51
CPC Classifications
C; C08; C08L; C08L39/00; C08L39/04; C08L39/06; C08L33/00; C08L33/18; C08L33/24; C08L35/00; C08L51/00; C08L51/04; C08L73/00; C08L73/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 323 words
A polymer blend comprising: a high nitrile copolymer prepared by the polymerization of 100 parts by weight of (A) from 60 percent to 90 percent by weight of at least one nitrile having the structure ##STR18## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 percent to 40 percent by weight based on the combined weights of (A) and (B) of at least one member selected from the group consisting of (1) an ester having the structure ##STR19## wherein R 1 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 30 carbon atoms, (2) an alpha-olefin having the structure ##STR20## wherein R 3 and R 4 are alkyl groups having from 1 to 7 carbon atoms, (3) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, (4) vinyl acetate, (5) styrene, and (6) indene, in the presence of from 0 to 40 parts by weight of (C) a rubbery polymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and a comonomer selected from the group consisting of styrene, a monomer having the structure ##STR21## wherein R has the foregoing designation, and an ester having the structure ##STR22## wherein R 1 and R 2 have the foregoing respective designations, said rubbery polymer containing from 50 percent to 100 percent by weight of polymerized conjugated diene and from 0 percent to 50 percent by weight of comonomer; and a compatible thermoplastic homopolymer or copolymer containing polar groups, consisting of the polymerization product formed from monomers selected from the group consisting of alkylacrylamides, unsaturated carboxylic acid anhydrides, vinyl pyrrolidones, heterocyclic ring compounds containing two hetero atoms, lactones and phosphorus-containing monomers that form highly crystalline polymers.
Claim 2
Dependent Claim 323 words
A polymer blend comprising: a high nitrile copolymer prepared by the polymerization of 100 parts by weight of (A) from 60 percent to 90 percent by weight of at least one nitrile having the structure ##STR18## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 percent to 40 percent by weight based on the combined weights of (A) and (B) of at least one member selected from the group consisting of (1) an ester having the structure ##STR19## wherein R 1 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 30 carbon atoms, (2) an alpha-olefin having the structure ##STR20## wherein R 3 and R 4 are alkyl groups having from 1 to 7 carbon atoms, (3) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, (4) vinyl acetate, (5) styrene, and (6) indene, in the presence of from 0 to 40 parts by weight of (C) a rubbery polymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and a comonomer selected from the group consisting of styrene, a monomer having the structure ##STR21## wherein R has the foregoing designation, and an ester having the structure ##STR22## wherein R 1 and R 2 have the foregoing respective designations, said rubbery polymer containing from 50 percent to 100 percent by weight of polymerized conjugated diene and from 0 percent to 50 percent by weight of comonomer; and a compatible thermoplastic homopolymer or copolymer containing polar groups, consisting of the polymerization product formed from monomers selected from the group consisting of alkylacrylamides, unsaturated carboxylic acid anhydrides, vinyl pyrrolidones, heterocyclic ring compounds containing two hetero atoms, lactones and phosphorus-containing monomers that form highly crystalline polymers.
Claim 3
Dependent Claim 19 words
A polymer blend, as set forth in claim 1, wherein said high nitrile copolymer comprises acrylonitrile and methyl acrylate.
Claim 4
Dependent Claim 38 words
A polymer blend, as set forth in claim 2, comprising from about 1 to 99 parts by weight of said high acrylonitrile copolymer and from about 99 to 1 parts by weight of poly(N,N-dimethylacrylamide) as said thermoplastic polymer.
Claim 5
Dependent Claim 39 words
A polymer blend, as set forth in claim 2, comprising from about 1 to 99 parts by weight of said high acrylonitrile copolymer and from about 99 to 1 parts by weight of poly(maleic anhydride) as said thermoplastic polymer.
Claim 6
Dependent Claim 39 words
A polymer blend, as set forth in claim 2, comprising from about 1 to 99 parts by weight of said high acrylonitrile copolymer and from about 99 to 1 parts by weight of poly(vinyl pyrrolidone) as said thermoplastic polymer.
Claim 7
Dependent Claim 39 words
A polymer blend, as set forth in claim 2, comprising from about 1 to 85 parts by weight of said high acrylonitrile copolymer and from about 99 to 15 parts by weight of poly(2-ethyl oxazoline) as said thermoplastic polymer.
Claim 8
Dependent Claim 37 words
A polymer blend, as set forth in claim 6, comprising from about 80 to 90 parts by weight of high acrylonitrile copolymer and from about 20 to 10 parts by weight of poly(2-ethyloxazoline) as said thermoplastic polymer.
Claim 9
Dependent Claim 38 words
A polymer blend, as set forth in claim 2, comprising from about 95 to 99 parts by weight of said high acrylonitrile copolymer and from about 1 to 5 parts by weight of poly(ε-caprolactone) as said thermoplastic polymer.
Claim 10
Dependent Claim 33 words
A polymer blend comprising: from about 1 to 99 parts by weight of a high nitrile copolymer comprising acrylonitrile and methyl acrylate; and from about 99 to 1 parts by weight of poly(N,N-dimethylacrylamide).
Claim 11
Dependent Claim 33 words
A polymer blend comprising: from about 1 to 99 parts by weight of a high nitrile copolymer comprising acrylonitrile and methyl acrylate; and from about 99 to 1 parts by weight of poly(N,N-dimethylacrylamide).

References Cited (Backward Citations)

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US3378605A Cited
US3676526A Cited
US3729531A Cited
US3732339A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-04-01 1994-10-01 1995-04-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-04-01 1998-10-01 1999-04-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-04-01 2002-10-01 2003-04-02 $7700.00 Window Closed / Lapsed

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