Patent US4997694A successfully refreshed from Google Patents.
US4997694A
Expired / Lapsed
US
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Cellular ceramic and foam materials
Assignee: FIRE KING INTERNATIONAL LLC
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Filing: 1989-09-11
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Granted: 1991-03-05
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Expires: 2009-09-11
Abstract
Abstract Methods of forming by polymerization reaction a silicate gel which exhibits intumescence upon application of heat and various products formed from the resulting ceramic foam materials. Specific formulations and processing steps best suited to particular applications are set forth, together with examples of various types and configurations of the resulting products. These include structural materials, such as sheets of wall board, very low density insulation materials, articles useful as a protective barrier from heat or flame, vitreous materials useful as heat resistant tiles or as abrasive wheels or blocks for grinding or polishing, and ceramic foam materials incorporating silica gel and processed solely with microwave heat.
Inventors
- 👤 David J. Legare
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:53
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/16; C04B38/00; C04B38/02; C04B2111/00; C04B2111/00474; C04B2111/00612; Y; Y10; Y10T; Y10T428/00; Y10T428/23; Y10T428/233; Y10T428/249921; Y10T428/249953; Y10T428/249954; Y10T428/249967; Y10T428/249969; Y10T428/24997
Claims Analysis
Total Claims: 47
Claim 1
Independent Claim
135 words
A method of producing sheets of wall board, or similar products, comprising the steps of: (a) thoroughly mixing 1 to 10 parts by weight of calcium carbonate powder into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 1:1 to 5:1 to form a slurry; (b) adding about 2 to 8 parts sodium chloride and/or potassium chloride (powder or fine granules) to said slurry, and quickly and thoroughly mixing or blending to provide a gel by polymerization reaction; (c) forming said gel into sheets of predetermined length, width and thickness; and (d) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete to form a rigid, cellular, ceramic product.
Claim 2
Independent Claim
135 words
A method of producing sheets of wall board, or similar products, comprising the steps of: (a) thoroughly mixing 1 to 10 parts by weight of calcium carbonate powder into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 1:1 to 5:1 to form a slurry; (b) adding about 2 to 8 parts sodium chloride and/or potassium chloride (powder or fine granules) to said slurry, and quickly and thoroughly mixing or blending to provide a gel by polymerization reaction; (c) forming said gel into sheets of predetermined length, width and thickness; and (d) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete to form a rigid, cellular, ceramic product.
Claim 3
Dependent Claim
16 words
A sheet of wall board, or the like, produced according to the method of claim 1.
Claim 4
Dependent Claim
45 words
The method of claim 1 including the further step of bonding to said sheets of cellular ceramic on at least one major surface thereof a layer of paper or paperboard having said predetermined length and width and a thickness substantially less than said predetermined thickness.
Claim 5
Dependent Claim
26 words
The method of claim 1 wherein a sheet of aluminum foil, or other heat-tolerant material is bonded to said gel sheets prior to said heating step.
Claim 6
Dependent Claim
27 words
The method of claim 1 including the further step of thoroughly mixing about 3 parts by weight of magnesium carbonate and/or magnesium silicate to said aqueous solution.
Claim 7
Dependent Claim
16 words
A sheet of wall board, or the like, produced according to the method of claim 3.
Claim 8
Independent Claim
142 words
A method of producing sheets of wall board, or similar products, comprising the steps of: (a) thoroughly mixing 2 to 8 parts by weight of calcium carbonate powder into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 3.4 to 1 and colloidal SiO 2 to soluble silicate ratio of about 2:1; (b) adding about 3 to 6 parts sodium chloride and/or potassium chloride (powder or fine granules) to said slurry, and quickly and thoroughly mixing or blending to provide a gel by polymerization reaction; (c) forming said gel into sheets of predetermined length, width and thickness; and (d) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete to form a rigid, cellular, ceramic product.
Claim 9
Independent Claim
142 words
A method of producing sheets of wall board, or similar products, comprising the steps of: (a) thoroughly mixing 2 to 8 parts by weight of calcium carbonate powder into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 3.4 to 1 and colloidal SiO 2 to soluble silicate ratio of about 2:1; (b) adding about 3 to 6 parts sodium chloride and/or potassium chloride (powder or fine granules) to said slurry, and quickly and thoroughly mixing or blending to provide a gel by polymerization reaction; (c) forming said gel into sheets of predetermined length, width and thickness; and (d) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete to form a rigid, cellular, ceramic product.
Claim 10
Dependent Claim
16 words
A sheet of wall board, or the like, produced according to the method of claim 7.
Claim 11
Independent Claim
107 words
A method of producing a very light weight bulk insulation product, or the like, comprising the steps of: (a) thoroughly mixing 2 to 8 parts by weight of potassium nitrate or sodium nitrate into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium silicate or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio between about 2:1 and 5:1 to provide a gel by polymerization reaction; (b) forming said gel in sheets or other predetermined shapes; (c) heating said gel at about 500° F. to 1100° F. until intumescence is substantially complete to form said bulk insulation product.
Claim 12
Independent Claim
107 words
A method of producing a very light weight bulk insulation product, or the like, comprising the steps of: (a) thoroughly mixing 2 to 8 parts by weight of potassium nitrate or sodium nitrate into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium silicate or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio between about 2:1 and 5:1 to provide a gel by polymerization reaction; (b) forming said gel in sheets or other predetermined shapes; (c) heating said gel at about 500° F. to 1100° F. until intumescence is substantially complete to form said bulk insulation product.
Claim 13
Dependent Claim
14 words
A bulk insulation product, or the like, produced by the method of claim 9.
Claim 14
Dependent Claim
33 words
The method of claim 9 including the further step of adding up to 2 parts by weight sodium and/or potassium sulfate and/or phosphate to said aqueous solution prior to formation of said gel.
Claim 15
Dependent Claim
11 words
The method of claim 9 wherein said silicate is sodium silicate.
Claim 16
Dependent Claim
17 words
The method of claim 12 wherein said nitrate is about 4 parts by weight of potassium nitrate.
Claim 17
Dependent Claim
34 words
The method of claim 13 including the further step of adding up to 5 parts by weight of fiber or mesh fillers to said aqueous solution prior to or during formation of said gel.
Claim 18
Dependent Claim
29 words
The method of claim 9 wherein a sheet of aluminum foil or similar materials is applied to the gel layer before heating, or to the finished cellular ceramic product.
Claim 19
Dependent Claim
14 words
A bulk insulation product, or the like, produced by the method' of claim 15.
Claim 20
Dependent Claim
97 words
A laminar structure for use as a fire and heat retardant product comprising a first layer of gel which exhibits intumescence upon application of heat formed by polymerization reaction by mixing at least one alkali metal chloride, bromide, iodide or nitrate in an aqueous solution of sodium silicate or potassium silicate sandwiched between second and third, substrate layers, whereby upon exposure of said product to heat or flame said gel layer intumesces with consequent absorption and dissipation of heat through the production and release of steam in transition of said gel layer to a ceramic foam layer.
Claim 21
Dependent Claim
97 words
A laminar structure for use as a fire and heat retardant product comprising a first layer of gel which exhibits intumescence upon application of heat formed by polymerization reaction by mixing at least one alkali metal chloride, bromide, iodide or nitrate in an aqueous solution of sodium silicate or potassium silicate sandwiched between second and third, substrate layers, whereby upon exposure of said product to heat or flame said gel layer intumesces with consequent absorption and dissipation of heat through the production and release of steam in transition of said gel layer to a ceramic foam layer.
Claim 22
Dependent Claim
13 words
The product of claim 17 wherein said substrate layers are of flammable material.
Claim 23
Dependent Claim
22 words
The product of claim 18 and further including an essentially moisture-impervious barrier between said gel layer and each of said substrate layers.
Claim 24
Dependent Claim
16 words
The product of claim 18 and further including an essentially moisture-impervious barrier surrounding said gel layer.
Claim 25
Dependent Claim
22 words
The product of claim 20 wherein said gel layer comprises a plurality of separately encapsulated portions each surrounded by said moisture-impervious barrier.
Claim 26
Dependent Claim
14 words
The product of claim 21 wherein said moisture-impervious barrier comprises a flexible, plastic membrane.
Claim 27
Dependent Claim
51 words
The product of claim 17 wherein said gel layer includes particles of at least one hydrated salt comprising up to 20 percent by weight of the total material and other filler materials such as glass or ceramic fibers or mesh comprising up to 12 percent by weight of the total material.
Claim 28
Dependent Claim
27 words
The product of claim 23 wherein said hydrated salt particles are added to and dispersed throughout said gel layer during and/or after the gel is essentially formed.
Claim 29
Dependent Claim
21 words
The product of claim 23 and further including a layer of essentially moisture-impervious material individually covering each of said salt particles.
Claim 30
Dependent Claim
11 words
The product of claim 17 wherein said silicate is potassium silicate.
Claim 31
Independent Claim
178 words
A method of producing a vitreous ceramic foam product comprising the steps of: (a) thoroughly mixing about 2 to 8 parts by weight sodium chloride and/or potassium chloride, and about 2 to 12 parts by weight of one or more of the class of compositions consisting of Bentonite clay, MgCO 3 , MgSiO 3 , Al 2 O 3 , Li 2 SiO 3 , LiCl, and CaCO 3 into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium' silicate and/or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 1:1 to 5:1, forming a gel by polymerization reaction; (b) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete, forming a rigid, cellular, ceramic foam product; (c) heating said foam product to a temperature at or near its melting point until the foam cells begin to fuse together, resulting in partial collapse and shrinkage but short of complete melting of said foam product; and (d) cooling the resulting vitreous, ceramic product.
Claim 32
Independent Claim
178 words
A method of producing a vitreous ceramic foam product comprising the steps of: (a) thoroughly mixing about 2 to 8 parts by weight sodium chloride and/or potassium chloride, and about 2 to 12 parts by weight of one or more of the class of compositions consisting of Bentonite clay, MgCO 3 , MgSiO 3 , Al 2 O 3 , Li 2 SiO 3 , LiCl, and CaCO 3 into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium' silicate and/or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 1:1 to 5:1, forming a gel by polymerization reaction; (b) heating said gel at about 1000° F. to 1200° F. until intumescence is substantially complete, forming a rigid, cellular, ceramic foam product; (c) heating said foam product to a temperature at or near its melting point until the foam cells begin to fuse together, resulting in partial collapse and shrinkage but short of complete melting of said foam product; and (d) cooling the resulting vitreous, ceramic product.
Claim 33
Dependent Claim
11 words
A vitreous ceramic product produced by the method of claim 27.
Claim 34
Dependent Claim
22 words
The method of claim 27 wherein about 3 to 5 parts sodium chloride and/or potassium chloride are mixed into said aqueous solution.
Claim 35
Dependent Claim
35 words
The method of claim 27, and further including adding filler materials consisting of particles of an abrasive material to said gel in a quantity which is essentially up to the saturation point of the gel.
Claim 36
Dependent Claim
19 words
The method of claim 30 wherein said abrasive material is at least one of sand, garnet and silicon carbide.
Claim 37
Dependent Claim
29 words
An abrasive wheel or block for grinding or polishing produced by the method of claim 30, wherein said vitreous, ceramic product serves as a matrix for said abrasive particles
Claim 38
Independent Claim
116 words
A method of producing a cellular, ceramic material comprising the steps of: (a) thoroughly mixing about 1.6 to 5 parts by weight hydrated silicic acid into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium silicate or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 2:1 to 5:1 to form a slurry; (b) thoroughly mixing about 1.6 to 4 parts by weight of at least one alkali metal chloride, bromide, iodide or nitrate into said slurry, thereby producing by polymerization reaction a gel which exhibits intumescence upon application of heat; (c) heating said gel via microwave energy (microwave oven) until intumescence is substantially complete.
Claim 39
Independent Claim
116 words
A method of producing a cellular, ceramic material comprising the steps of: (a) thoroughly mixing about 1.6 to 5 parts by weight hydrated silicic acid into 20 parts by weight of a 10% to 40% (by weight) aqueous solution of sodium silicate or potassium silicate having a soluble SiO 2 to alkali metal oxide ratio of about 2:1 to 5:1 to form a slurry; (b) thoroughly mixing about 1.6 to 4 parts by weight of at least one alkali metal chloride, bromide, iodide or nitrate into said slurry, thereby producing by polymerization reaction a gel which exhibits intumescence upon application of heat; (c) heating said gel via microwave energy (microwave oven) until intumescence is substantially complete.
Claim 40
Dependent Claim
20 words
The method of claim 33 and further comprising forming said gel into substantially flat sheets prior to said heating step.
Claim 41
Dependent Claim
12 words
A wall board product produced according to the method of claim 34.
Claim 42
Dependent Claim
11 words
The method of claim 33 wherein said silicate is sodium silicate.
Claim 43
Dependent Claim
20 words
The method of claim 36 wherein said alkali metal chloride, bromide, iodide or nitrate is sodium chloride and/or potassium chloride.
Claim 44
Dependent Claim
32 words
The method of claim 37 wherein said aqueous solution has a colloidal SiO 2 to soluble SiO 2 ratio of about 1:1 to 3:1, prior to the addition of said silicic acid.
Claim 45
Dependent Claim
40 words
The method of claim 38 wherein about 2 to 3 parts by weight of said silicic acid and about 2 parts by weight of said sodium chloride and/or potassium chloride are mixed into said aqueous solution to form the gel.
Claim 46
Dependent Claim
25 words
The method of claim 39 and further comprising mixing into said slurry up to about 1 part by weight of CaCO 3 and/or aluminum silicate.
Claim 47
Dependent Claim
17 words
The method of claim 40 wherein about 0.4 parts of CaCO 3 are mixed into said slurry.
References Cited (Backward Citations)
US4871694A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-03-04 | 1994-09-03 | 1995-03-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-03-04 | 1998-09-03 | 1999-03-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-03-04 | 2002-09-03 | 2003-03-05 | $7700.00 | Window Closed / Lapsed |