Process for reducing nitrogen oxides without generating nitrous oxide

Claim 2

A process for the reduction of the concentration of nitrogen oxides in the oxygen rich effluent from the combustion of a carbonaceous fuel, the process comprising introducing a treatment agent which comprises ammonium carbamate into said effluent which is at a temperature greater than about 1300° F. and in an amount effective to substantially avoid the presence of nitrous oxide.

Claim 3

The process of claim 1 wherein the temperature of the effluent is greater than about 1400° F.

Claim 4

The process of claim 1 wherein the temperature of the effluent is below about 2100° F.

Claim 5

The process of claim 1 wherein said treatment agent is injected into the effluent at a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen oxides level of 1:5 to about 10:1.

Claim 6

The process of claim 4 wherein the molar ratio of treatment agent nitrogen to the baseline nitrogen oxides level is about 1:3 to about 5:1.

Claim 7

The process of claim 1 wherein said treatment agent further comprises an enhancer for ammonium carbamate.

Claim 8

A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel without the generation of a substantial amount of nitrous oxide, the process comprising: (a) introducing a first treatment agent into the effluent at a first effluent temperature zone; and (b) introducing a second treatment agent which comprises ammonium carbamate into the effluent at a second effluent temperature zone.

Claim 9

A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel without the generation of a substantial amount of nitrous oxide, the process comprising: (a) introducing a first treatment agent into the effluent at a first effluent temperature zone; and (b) introducing a second treatment agent which comprises ammonium carbamate into the effluent at a second effluent temperature zone.

Claim 10

The process of claim 7 wherein said first treatment agent comprises urea or ammonia.

Claim 11

The process of claim 8 wherein said first temperature zone is about 1800° F. to about 2100° F.

Claim 12

The process of claim 7 wherein said second temperature zone is about 1300° F. to about 1800° F.

Claim 13

The process of claim 7 wherein said ammonium carbamate is injected into the effluent at a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen contained in said treatment agent to the baseline nitrogen oxides level of 1:5 to about 10:1.

Claim 14

The process of claim 11 wherein the molar ratio of ammonium carbamate nitrogen to the baseline nitrogen oxides level is about 1:3 to about 5:1.

Claim 15

The process of claim 7 wherein said second treatment agent further comprises an enhancer for ammonium carbamate.

Claim 16

A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel, the process comprising: a. determining the condition of the effluent which exists at a location for injection; b. introducing a treatment agent which comprises ammonium carbamate into the effluent, which treatment agent is effective to reduce the nitrogen oxides concentration of the effluent at the determined effluent conditions through a reaction or series of reactions facilitated by said treatment agent; and c. adjusting the components, dilution/introduction rate or relative presence of components of said treatment agent to cause the introduction of said treatment agent to operate further toward the right side of its nitrogen oxides reduction versus effluent temperature curve.

Claim 17

A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel, the process comprising: a. determining the condition of the effluent which exists at a location for injection; b. introducing a treatment agent which comprises ammonium carbamate into the effluent, which treatment agent is effective to reduce the nitrogen oxides concentration of the effluent at the determined effluent conditions through a reaction or series of reactions facilitated by said treatment agent; and c. adjusting the components, dilution/introduction rate or relative presence of components of said treatment agent to cause the introduction of said treatment agent to operate further toward the right side of its nitrogen oxides reduction versus effluent temperature curve.

Claim 18

The process of claim 14 which further comprises increasing the introduction rate of said treatment agent to increase the normalized stoichiometric ratio until a predetermined maximum level of nitrous oxide is substantially attained but not surpassed.

Claim 19

The process of claim 14 which further comprises increasing the introduction rate of said treatment agent to increase the normalized stoichiometric ratio until a predetermined target level of nitrogen oxides reduction is substantially attained provided that a predetermined maximum level of nitrous oxide is not surpassed.

Claim 20

The process of claim 14 wherein said ammonium carbamate is injected into the effluent at a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen contained in said treatment agent to the baseline nitrogen oxides level of 1:5 to about 10:1.

Claim 21

The process of claim 17 wherein the molar ratio of ammonium carbamate nitrogen to the baseline nitrogen oxides level is about 1:3 to about 5:1.

Claim 22

The process of claim 14 wherein said treatment agent further comprises an enhancer for ammonium carbamate.