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US4992228A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for preparing preforms for molding processes

Assignee: DOW-UNITED TECHNOLOGY COMOSITES PRODUCTS Inc
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Filing: 1989-09-28
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Granted: 1991-02-12
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Expires: 2009-09-28
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Abstract

Abstract Preforms for molding processes such as resin transfer molding processes are prepared by melting a solid, non-sintering, thermoplastic-like resinous compound on the surface of a substrate material; after cooling, assembling one or more plies of the coated substrate material into the desired shape; heating the thus shaped substrate material to a temperature above the melting temperature of resinous compound and subsequently cooling to a temperature below the melting point of the resinous compound.

Inventors

  • 👤 Henry G. Heck
  • 👤 Warren D. White

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:45
CPC Classifications
B; B29; B29B; B29B15/00; B29B15/08; B29B15/10; B29B15/105; B29B11/00; B29B11/14; B29B11/16; B29C; B29C70/00; B29C70/003; B29C70/04; B29C70/28; B29C70/30; C; C08; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/244

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 207 words
A method for preparing preforms which comprises (1) applying substantially evenly onto the surface of each of one or more plys of an unimpregnated substrate material one or more non-sintering thermoplastic-like resinous compounds which are substantially free of any compound which would serve as a crosslinker for said thermoplastic-like, solid resinous compound, said resinous compound being in the form of a powder having a particle size of less than about 500 microns and having a melting point of from about 50° C. to about 70° C. in an amount of from about 2 to about 12 percent by weight based upon the weight of said substrate material; (2) fusing said powdered thermoplastic-like resinous compound into a film on the surface of said substrate material: (3) cooling said resinous material: (4) assembling one or more plies of the thus treated substrate material and conforming said plies of said treated substrate material into a desired shape: (5) subjecting the thus shaped plies of treated substrate material at a temperature sufficient to melt said resinous compound; and (6) cooling said shaped treated plies of substrate material to a temperature below the melting point of said resinous compound; thereby forming a preshaped preform for use in molding processes as reinforcing material.
Claim 2
Independent Claim 207 words
A method for preparing preforms which comprises (1) applying substantially evenly onto the surface of each of one or more plys of an unimpregnated substrate material one or more non-sintering thermoplastic-like resinous compounds which are substantially free of any compound which would serve as a crosslinker for said thermoplastic-like, solid resinous compound, said resinous compound being in the form of a powder having a particle size of less than about 500 microns and having a melting point of from about 50° C. to about 70° C. in an amount of from about 2 to about 12 percent by weight based upon the weight of said substrate material; (2) fusing said powdered thermoplastic-like resinous compound into a film on the surface of said substrate material: (3) cooling said resinous material: (4) assembling one or more plies of the thus treated substrate material and conforming said plies of said treated substrate material into a desired shape: (5) subjecting the thus shaped plies of treated substrate material at a temperature sufficient to melt said resinous compound; and (6) cooling said shaped treated plies of substrate material to a temperature below the melting point of said resinous compound; thereby forming a preshaped preform for use in molding processes as reinforcing material.
Claim 3
Dependent Claim 62 words
The method of claim 1 wherein said non-sintering, thermoplastic-like resinous compounds have a particle size in the range of from about 20 to about 500 microns; a melting point of from about 55° C. to about 65° C.; and is employed in an amount of from about 3 to about 8 percent by weight based upon the weight of said substrate material.
Claim 4
Dependent Claim 62 words
The method of claim 1 wherein said non-sintering, thermoplastic-like resinous compounds have a particle size in the range of from about 30 to about 200 microns; a melting point of from about 57° C. to about 60° C.: and is employed in an amount of from about 4 to about 6 percent by weight based upon the weight of said substrate material.
Claim 5
Dependent Claim 26 words
The method of claim 3 wherein said non-sintering, thermoplastic-like resinous compounds have a particle size in the range of from about 40 to about 80 microns.
Claim 6
Independent Claim 70 words
The method of any one of claims 1, 2, 3 or 4 wherein said non-sintering, solid, thermoplastic-like resinous compound is an epoxy resin, unsaturated polyester resin or vinyl ester resin, or any combination thereof; said substrate material is glass, graphite or carbon, or any combination thereof: and said substrate material is in the form of woven or non-woven fibrous material, random fibers, monofilaments, multi-strands of monofilaments or any combination thereof.
Claim 7
Dependent Claim 69 words
The method of claim 5 wherein said non-sintering, solid, thermoplastic-like resinous compound is a di- or polyglycidyl ether of biphenol, bisphenol, hydrocarbyl substituted biphenol, hydrocarbyl substituted bisphenol, phenol or hydrocarbyl substituted bisphenol-aldehyde novolac resin, unsaturated hydrocarbon-phenol or hydrocarbyl substituted phenol resin, or any combination thereof; said substrate material is glass, graphite or carbon, or any combination thereof; and said substrate material is in the form of woven fibrous material.
Claim 8
Dependent Claim 28 words
The method of claim 6 wherein said non-sintering, solid, thermoplastic-like resinous compound is a diglycidyl ether of bisphenol A, bisphenol F or bisphenol K, or any combination thereof.

References Cited (Backward Citations)

US3922418A Cited
JPS53143665A Cited
US4213930A Cited
US4329387A Cited
JPS56163173A Cited
US4325770A Cited
US4496415A Cited
JPS598374A Cited
GB2158471A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-02-11 1994-08-13 1995-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-02-11 1998-08-13 1999-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-02-11 2002-08-13 2003-02-12 $7700.00 Window Closed / Lapsed

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