Thermosetting resin compositions

Claim 2

A thermosetting resin composition comprising: (i) about 100 parts by weight of a polymer having recurring units represented by the formula (I): ##STR12## wherein R 1 represents a divalent group selected from the group consisting of ##STR13## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups containing from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups, and Z represents at least one compound selected from the group consisting of ##STR14## wherein Y represents a tetravalent group selected from the group consisting of aliphatic groups having at least two carbon atoms, cycloaliphatic groups, monocyclic aromatic groups, fused polycyclic aromatic groups, and non-fused cyclic aromatic groups composed of aromatic groups bonded together directly or via a crosslink; and (ii) from about 5 to about 100 parts by weight of a bismaleimide compound selected from the group consisting of compounds of the formula (II): ##STR15## and compounds of the formula (III): ##STR16## wherein R 2 represents a divalent group selected from the group consisting of ##STR17## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups.

Claim 3

The thermosetting resin composition of claim 1, wherein said polymer is a polyamic acid prepared by reacting (a) a diamine compound of the formula (IV): ##STR18## wherein R 3 represents a divalent group selected from the group consisting of ##STR19## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups, with (b) a compound selected from the group consisting of at least one tetracarboxylic dianhydride and a polyimide.

Claim 4

The resin composition of claim 2 wherein in said diamine compound of the formula (IV), R 3 is selected from the group consisting of ##STR20##

Claim 5

The resin composition of claim 2, wherein said tetracarboxylic dianhydride has the formula (V): ##STR21## wherein Y is a tetravalent group selected from the group consisting of aliphatic groups having at least two carbon atoms, cycloaliphatic groups, monocyclic aromatic groups, fused polycyclic aromatic groups, and non-fused cyclic aromatic groups.

Claim 6

The resin composition of claim 4 wherein Y is a tetravalent group selected from the group consisting of aliphatic hydrocarbons having from 1 to 4 carbon atoms, cycloaliphatic hydrocarbons having from 4 to 8 carbon atoms, ##STR22## wherein X is selected from the group consisting of a direct bond, aliphatic hydrocarbons having from 1 to 4 carbon atoms, aliphatic hydrocarbons having from 1 to 4 carbon atoms substituted by from 1 to 6 fluorine atoms, --O--, --CO--, ##STR23##

Claim 7

The resin composition of claim 2 wherein said diamine compound is selected from the group consisting of 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(3-aminophenoxy)phenyl]propane, bis[4-(3aminophenoxy)phenyl]sulfite and 1,3-bis(3-aminophenoxy)benzene.

Claim 8

The resin composition of claim 2 wherein said tetracarboxylic dianhydride selected from the group consisting of pyromellitic dianhydride and 3,3',4,4'-benzophenonetetracarboxylic dianhydride.

Claim 9

The resin composition of claim 1 wherein said bismaleimide compound is selected from the group consisting of N,N'-4,4'-diphenylmethanebismaleimide, 4,4'-bis(3-maleimidophenoxy)biphenyl, 2,2-bis[4-(3maleimidophenoxy)phenyl]propane, bis[4-(3-maleimidophenoxy)phenyl]sulfide and 1,3-bis(3-maleimidophenoxy)benzene.

Claim 10

A process for preparing a thermosetting resin composition comprising mixing (i) about 100 parts by weight of a polymer having recurring units represented by the formula (I): ##STR24## wherein R 1 represents a divalent group selected from time group consisting of ##STR25## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups, and Z represents at least one compound selected from the group consisting of ##STR26## wherein Y represents a tetravalent group selected from the group consisting of aliphatic groups having at least two carbon atoms, cycloaliphatic groups, monocyclic aromatic groups, fused polycyclic aromatic groups, and non-fused cyclic aromatic groups composed of aromatic groups bonded together directly or via a crosslink, and (ii) from about 5 to about 100 parts by weight of a bismaleimide compound selected from the group consisting of compounds of the formula (II): ##STR27## and compounds of the formula (III): ##STR28## wherein R 2 represents a divalent group selected from the group consisting of ##STR29## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups.

Claim 11

A process for preparing a thermosetting resin composition comprising mixing (i) about 100 parts by weight of a polymer having recurring units represented by the formula (I): ##STR24## wherein R 1 represents a divalent group selected from time group consisting of ##STR25## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups, and Z represents at least one compound selected from the group consisting of ##STR26## wherein Y represents a tetravalent group selected from the group consisting of aliphatic groups having at least two carbon atoms, cycloaliphatic groups, monocyclic aromatic groups, fused polycyclic aromatic groups, and non-fused cyclic aromatic groups composed of aromatic groups bonded together directly or via a crosslink, and (ii) from about 5 to about 100 parts by weight of a bismaleimide compound selected from the group consisting of compounds of the formula (II): ##STR27## and compounds of the formula (III): ##STR28## wherein R 2 represents a divalent group selected from the group consisting of ##STR29## X is selected from the group consisting of a direct bond, divalent hydrocarbon groups having from about 1 to about 10 carbon atoms, hexafluorinated isopropylidene groups, carbonyl groups, thio groups, sulfinyl groups, sulfonyl groups and oxo groups.

Claim 12

The process of claim 9 wherein said bismaleimide compound is dissolved in a polymer varnish prior to mixing with said polymer.

Claim 13

The process of claim 9 wherein said bismaleimide compound is dissolved in a polymer suspension prior to mixing with said polymer.