← Back to Patent Explorer
US4987177A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating composition of an acrylic polymer containing glycidyl groups and acetoacetoxy groups and an amino ester acrylic polymer

Assignee: EIDP Inc
•
Filing: 1989-07-18
•
Granted: 1991-01-22
•
Expires: 2009-07-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A coating composition which cures at ambient temperatures and contains 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder contains about: A. 60-80% by weight, based on the weight of the binder, of an acrylic polymer A of polymerized monomers of methyl methacrylate and monomers of styrene, alkylmethacrylate and/or alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups, B. 20-40% by weight, based on the weight of the binder, of an acrylic crosslinking polymer B of polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent of glycidyl methacrylate or acrylate, at least 5% by weight, based on the weight of the crosslinking polymer, of an alkyl methacrylate or acrylate having a pendent group of the formula <IMAGE> and the remainder of the monomers are alkyl methacrylate an acrylate each having 1-12 carbon atoms in the alkyl group; the composition is useful as an exterior finish for automobiles and trucks and for repairing and finishes of automobiles and trucks.

Inventors

  • 👤 Herman C. Den Hartog
  • 👤 George T. Palmer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:05
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/068; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/062

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 256 words
A coating composition comprising 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder consists essentially of about: A. 60-80% by weight of the binder, of an acrylic polymer A consisting essentially of polymerized monomers of methyl metharcrylate and monomers selected from the group consisting of styrene, alkyl metharylate and alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive groups selected from the group consisting of aminoester groups of the formula ##STR10## where R is an alkylene group having 2-3 carbon atoms, hydroxyaminio ester groups of the formula ##STR11## groups of the formula ##STR12## where R 1 is an alkyl group of 1-8 carbons atoms; and B. 20-40% by weight, based on the weight of the binder, of an acrylic crosslinking polymer B consisting essentially of polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent selected from the group consisting of glycidyl methacrylate and glycidyl acrylate, at least 5% by weight of an alkyl acrylate or alkyl methacrylate having a pendent group of the formula ##STR13## and the remainder of the monomers being selected from the group consisting of alkyl methacrylate and alkyl acrylate each having 1-12 carbon atoms in the alkyl groups; wherein said polymers A and B each have a weight average molecular weight of about 5,000-40,000 determined by gel permeation chromatography using polymethyl methacrylate as a standard.
Claim 2
Dependent Claim 256 words
A coating composition comprising 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder consists essentially of about: A. 60-80% by weight of the binder, of an acrylic polymer A consisting essentially of polymerized monomers of methyl metharcrylate and monomers selected from the group consisting of styrene, alkyl metharylate and alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive groups selected from the group consisting of aminoester groups of the formula ##STR10## where R is an alkylene group having 2-3 carbon atoms, hydroxyaminio ester groups of the formula ##STR11## groups of the formula ##STR12## where R 1 is an alkyl group of 1-8 carbons atoms; and B. 20-40% by weight, based on the weight of the binder, of an acrylic crosslinking polymer B consisting essentially of polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent selected from the group consisting of glycidyl methacrylate and glycidyl acrylate, at least 5% by weight of an alkyl acrylate or alkyl methacrylate having a pendent group of the formula ##STR13## and the remainder of the monomers being selected from the group consisting of alkyl methacrylate and alkyl acrylate each having 1-12 carbon atoms in the alkyl groups; wherein said polymers A and B each have a weight average molecular weight of about 5,000-40,000 determined by gel permeation chromatography using polymethyl methacrylate as a standard.
Claim 3
Dependent Claim 17 words
The coating composition of claim 1 containing pigments in a pigment-to-binder weight ratio of 1:100 to 200:100.
Claim 4
Dependent Claim 73 words
The coating composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive aminoester groups of the formula ##STR14## where R is an alkylene group having 2-3 carbon atoms.
Claim 5
Dependent Claim 91 words
The coating composition of claim 3 in which the acrylic polymer A consists essentially of about 20-30% by weight, based on the acrylic polymer, of methyl methacrylate 30-40% by weight, based on the weight of the acrylic polymer, of styrene,, 25-35% by weight, based on the weight of the acrylic polymer, of an alkyl methacrylate having 4-12 carbon atoms in the alkyl group and 10-15% by weight, based on the weight of the acrylic polymer, of methacrylic acid; said polymer reacted with an alkylene imine to provide said amino ester groups.
Claim 6
Dependent Claim 63 words
The coatings composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone hydroxyaminio ester groups of the formula ##STR15##
Claim 7
Dependent Claim 67 words
The coating composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the backbone groups of the formula ##STR16## where R 1 is an alkyl group of 1-8 carbon atoms.
Claim 8
Dependent Claim 98 words
The coating composition of claim 3 in which the acrylic crosslinking polymer B consists essentially of about 3-80% by weight, bases on the weight of the acrylic crosslinking polymer, of glycidyl methacrylate, or glycidyl acrylate 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of an alkyl methacrylate having 1-12 carbon atoms in the alkyl group and 3-57 by weight, based on the weight of the acrylic crosslinking polymer of an alkyl methacrylate or alkyl acrylate each having 1-4 carbon atoms in the alkyl group and each having a pendent group of the formula ##STR17##
Claim 9
Dependent Claim 75 words
The coating composition of claims 4,5 or 6 in which the acrylic crosslinking polymer B consists essentially of about 3-80% by weight based on the weight of the acrylic crosslinking polymer, of glycidyl metharylate, 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of an alkyl methacrylate having 4-12 carbon atoms in the alkyl group and 3-57% by weight, based on the weight of the acrylic crosslinking polymer of acetoacetoxy ethyl methacrylate.
Claim 10
Dependent Claim 40 words
The coating composition of claim 1 containing about 0.1-4% by weight, based on the weight of the binder, of a catalyst selected from the group consisting of resorcinol, resorcinol monobenzoate, boron trifuloride amine complex, phenol, para methoxy phenol, parahydroxymethyl benzoate.
Claim 11
Dependent Claim 21 words
The coating composition of claim 1 containing 0.1-5% by weight, based on the weight of the binder, of ultraviolet light stabilizer.
Claim 12
Dependent Claim 180 words
The coating composition of claim 2 in which the binder consists essentially of about A. acrylic polymer A consists essentially of about 20-30% by weight, based on the acrylic polymer, of methyl methacrylate, 30-40% by weight, based on the weight of the acrylic polymer, of styrene, 25-35% by weight, based on the weight of the acrylic polymer, of alkyl methacrylate methacrylate having 4-12 carbon atoms in the alkyl group and 10-15% by weight, based on the weight of the acrylic polymer, of methacrylic acid; said polymer reacted with an alkylene imine to provide amino ester groups pendent from the carbon-carbon polymer backbone of the formula ##STR18## where R is an alkylene group having 2-3 carbon atoms; and B. acrylic crosslinking polymer B consists essentially of about 3-80% by weight, based on the weight of the acrylic crosslinking polymer, of glycidyl methacrylate, 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of alkyl methacrylate having 14-12 carbons in the alkyl group and 5-57% by weight, based on the weight of the acrylic crosslinking polymer, of acetoacetoxy ethyl methacrylate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-21 1994-07-23 1995-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-21 1998-07-23 1999-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-21 2002-07-23 2003-01-22 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag