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US4987156A Expired / Lapsed US ⏱️ 0.0 years remaining

Shock-absorbing polyurethane foam and production process thereof

Assignee: Honda Motor Co Ltd
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Filing: 1989-06-05
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Granted: 1991-01-22
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Expires: 2009-06-05
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Abstract

Abstract A shock-absorbing polyurethane foam is formed of a polyol component and a polyisocyanate component. The polyol component is a mixed polyol having an average hydroxyl number of 130-250 and composed at least of 20-70 parts by weight of a low-molecular polyol having a molecular weight of 300-500 and 80-30 parts by weight of a high-molecular polyol having a molecular weight of 1,500-8,000 per 100 parts by weight of the whole polyol component. The foam further contains 5-150 parts by weight of a plasticizer having a solidification point not higher than -20° C. per 100 parts by weight of the whole polyol component. The foam can be produced by reacting the polyol component and polyisocyanate component in the presence of 5-150 parts by weight of the plasticizer per 100 parts by weight of the polyol component.

Inventors

  • 👤 Sigeru Tozune
  • 👤 Shizuo Yamazaki
  • 👤 Ryuichi Komori
  • 👤 Masashi Ishii
  • 👤 Yoshio Sakaguchi
  • 👤 Tetsuya Oda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 10:27
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0838; C08G18/0842; C08G18/16; C08G18/18; C08G18/20; C08G18/2045; C08G18/2063; C08G18/28; C08G18/65; C08G18/66; C08G18/6666; C08G18/667; C08G18/6674; C08G18/6677; C08K3/00; C08K3/18; C08K3/24; C08K3/26; C08K5/0008; C08K5/0016; C08K5/49; C08K5/51; C08K5/52; C08K5/521; C08G2110/00; C08G2110/0008; C08G2110/0041; C08G2110/005; C08G2110/0058; C08G2110/0083

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 103 words
A shock-absorbing polyurethane foam comprising a polyol component and a polyisocyanate component, characterized in that the polyol component is a mixed polyol having an average hydroxyl number of 130-250 and composed at least of 20-70 parts by weight of a low-molecular polyol having a molecular weight of 300-500 and 80-30 parts by weight of a high-molecular polyol having a molecular weight of 1,500-8,000 per 100 parts by weight of the whole polyol component; and the foam contains 5-150 parts by weight of a plasticizer having a solidification point not higher than -20° C. per 100 parts by weight of the whole polyol component.
Claim 2
Dependent Claim 103 words
A shock-absorbing polyurethane foam comprising a polyol component and a polyisocyanate component, characterized in that the polyol component is a mixed polyol having an average hydroxyl number of 130-250 and composed at least of 20-70 parts by weight of a low-molecular polyol having a molecular weight of 300-500 and 80-30 parts by weight of a high-molecular polyol having a molecular weight of 1,500-8,000 per 100 parts by weight of the whole polyol component; and the foam contains 5-150 parts by weight of a plasticizer having a solidification point not higher than -20° C. per 100 parts by weight of the whole polyol component.
Claim 3
Dependent Claim 18 words
The foam as claimed in claim 1, wherein the average molecular weight of the high-molecular polyol is 2,000-6,000.
Claim 4
Dependent Claim 36 words
The foam as claimed in claim 1, wherein each of the low-molecular and high-molecular polyols is a polyol obtained by adding at least one alkylene oxide to a compound containing at least two active hydrogen atoms.
Claim 5
Dependent Claim 27 words
The foam as claimed in claim 1, wherein the low-molecular and high-molecular polyols amount in combination to at least 50 parts by weight of the mixed polyol.
Claim 6
Dependent Claim 27 words
The foam as claimed in claim 1, wherein the low-molecular and high-molecular polyols amount in combination to at least 70 parts by weight of the mixed polyol.
Claim 7
Dependent Claim 39 words
The foam as claimed in claim 1, wherein a plasticizer having a solidification point not higher than -50° C. is contained in an amount of 5-50 parts by weight per 100 parts by weight of the whole polyol component.
Claim 8
Dependent Claim 105 words
A process for the production of a shock-absorbing polyurethane foam, characterized in that said process comprises reacting a mixed polyol and a polyisocyanate in the presence of 5-150 parts by weight of a plasticizer having a solidification point not higher than -20° C. per 100 parts by weight of the mixed polyol, said mixed polyol having an average hydroxyl number of 130-250 and composed at least of 20-70 parts by weight of a low-molecular polyol having a molecular weight of 300-500 and 80-30 parts by weight of a high-molecular polyol having a molecular weight of 1,500-8,000 per 100 parts by weight of the mixed polyol.
Claim 9
Dependent Claim 105 words
A process for the production of a shock-absorbing polyurethane foam, characterized in that said process comprises reacting a mixed polyol and a polyisocyanate in the presence of 5-150 parts by weight of a plasticizer having a solidification point not higher than -20° C. per 100 parts by weight of the mixed polyol, said mixed polyol having an average hydroxyl number of 130-250 and composed at least of 20-70 parts by weight of a low-molecular polyol having a molecular weight of 300-500 and 80-30 parts by weight of a high-molecular polyol having a molecular weight of 1,500-8,000 per 100 parts by weight of the mixed polyol.
Claim 10
Dependent Claim 18 words
The process as claimed in claim 7, wherein the average molecular weight of the high-molecular polyol is 2,000-6,000.
Claim 11
Dependent Claim 36 words
The process as claimed in claim 7, wherein each of the low-molecular and high-molecular polyols is a polyol obtained by adding at least one alkylene oxide to a compound containing at least two active hydrogen atoms.
Claim 12
Dependent Claim 27 words
The process as claimed in claim 7, wherein the low-molecular and high-molecular polyols amount in combination to at least 50 parts by weight of the mixed polyol.
Claim 13
Dependent Claim 27 words
The process as claimed in claim 7, wherein the low-molecular and high-molecular polyols amount in combination to at least 70 parts by weight of the mixed polyol.
Claim 14
Dependent Claim 41 words
The process as claimed in claim 7, wherein the reaction is conducted in the presence of 5-50 parts by weight of a plasticizer having a solidification point not higher than -50° C. per 100 parts by weight of the mixed polyol.
Claim 15
Dependent Claim 30 words
The process as claimed in claim 7, wherein the polyisocyanate is a mixture of the 2,4-isomer and 2,6-isomer of tolylene diisocyanate at a weight ratio of from 80:20 to 65:35.
Claim 16
Dependent Claim 21 words
The process as claimed in claim 7, wherein the mixed polyol and polyisocyanate are reacted at an NCO/OH ratio of 0.90-1.15.
Claim 17
Dependent Claim 21 words
The process as claimed in claim 7, wherein the mixed polyol and polyisocyanate are reacted in the presence of calcium carbonate.
Claim 18
Dependent Claim 29 words
The process as claimed in claim 15, wherein calcium carbonate is added in an amount of 1-20 parts by weight per 100 parts by weight of the mixed polyol.
Claim 19
Dependent Claim 34 words
The process as claimed in claim 7, wherein a tertiary amine salt represented by the following formula (a) is used as a reaction catalyst: ##STR2## wherein n is an integer of at least 0.
Claim 20
Dependent Claim 21 words
The process as claimed in claim 17, wherein the mixed polyol and polyisocyanate are reacted in the presence of calcium carbonate.
Claim 21
Dependent Claim 29 words
The process as claimed in claim 18, wherein calcium carbonate is added in an amount of 1-20 parts by weight per 100 parts by weight of the mixed polyol.
Claim 22
Dependent Claim 12 words
The foam as claimed in claim 1 wherein the foam is flexible.
Claim 23
Dependent Claim 14 words
The foam as claimed in claim 20 wherein the foam is an open-cell foam.
Claim 24
Dependent Claim 14 words
The foam as claimed in claim 1 wherein the cell is an open-cell foam.
Claim 25
Dependent Claim 11 words
An automotive cushioning material formed from the foam of claim 1.

References Cited (Backward Citations)

US4565833A Cited
US4746682A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-21 1994-07-23 1995-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-21 1998-07-23 1999-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-21 2002-07-23 2003-01-22 $7700.00 Window Closed / Lapsed

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