Patent US4985536A successfully refreshed from Google Patents.
US4985536A
Expired / Lapsed
US
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Copolyetherester elastomer with cycloaliphatic hard segments
Assignee: EIDP Inc
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Filing: 1990-06-07
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Granted: 1991-01-15
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Expires: 2010-06-07
Abstract
Abstract An improved thermoplastic, segmented, linear copolyetherester elastomer having hard segments derived from diols and diacids which provide divalent cyclo-aliphatic radicals having a structure depicted by a formula which is ##STR1## Preferably the diol and diacid radicals are each at least 40% trans isomer and either one or the other radical is at least 70% trans isomer. The elastomers are suited for use as rubber-band substitutes, elastic strips, elastic coatings and the like.
Inventors
- 👤 Garret D. Figuly
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 14:01
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/199; C08G63/66; C08G63/668; C08G63/672
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
200 words
An improved thermoplastic, segmented, linear copolyetherester elastomer which consists essentially of a multiplicity of recurring long-chain units and short-chain ether-ester units connected head-to-tail through ester linkages, the long-chain units amounting to at least 50 percent by weight of the elastomer and being represented by the structural formula ##STR5## short-chain ester units amounting to 10 to 50 percent by weight of the elastomer and being represented by the structural formula ##STR6## in which R is a divalent radical which remains after removal of carboxyl groups from a dicarboxylic acid, G is a divalent radical which remains after removal of hydroxyl groups from a poly(alkylene oxide) glycol having a carbon-to-oxygen ratio in the range of 2.0 to 4.3 and a molecular weight in the range of 1,000 to 5,000, and D is a divalent radical remaining after removal of terminal hydroxyl groups from a diol, wherein the improvement comprises the R and D radicals being the same or different, R and D each being a divalent cycloaliphatic radical having a structural formula selected from the group consisting of ##STR7## R and D each being at least 40% trans isomer and either the R or D radical being at least 70% trans isomer.
Claim 2
Dependent Claim
200 words
An improved thermoplastic, segmented, linear copolyetherester elastomer which consists essentially of a multiplicity of recurring long-chain units and short-chain ether-ester units connected head-to-tail through ester linkages, the long-chain units amounting to at least 50 percent by weight of the elastomer and being represented by the structural formula ##STR5## short-chain ester units amounting to 10 to 50 percent by weight of the elastomer and being represented by the structural formula ##STR6## in which R is a divalent radical which remains after removal of carboxyl groups from a dicarboxylic acid, G is a divalent radical which remains after removal of hydroxyl groups from a poly(alkylene oxide) glycol having a carbon-to-oxygen ratio in the range of 2.0 to 4.3 and a molecular weight in the range of 1,000 to 5,000, and D is a divalent radical remaining after removal of terminal hydroxyl groups from a diol, wherein the improvement comprises the R and D radicals being the same or different, R and D each being a divalent cycloaliphatic radical having a structural formula selected from the group consisting of ##STR7## R and D each being at least 40% trans isomer and either the R or D radical being at least 70% trans isomer.
Claim 3
Dependent Claim
38 words
An elastomer in accordance with claim 1 wherein the poly(alkylene oxide) glycol is a poly(tetramethylene oxide) glycol or a glycol of a copolymer of tetrahydrofuran and 3-methyltetrahydrofuran having a molecular weight in the range of 1,500 to 3,000.
Claim 4
Dependent Claim
24 words
An elastomer in accordance with claim 2 wherein the weight percent of short chain ester units is in the range of 15 to 30.
Claim 5
Dependent Claim
32 words
An elastomer in accordance with claim 2 wherein the weight percent of short chain ester units is in the range of 20 to 25% and the glycol is a poly(tetramethylene oxide) glycol.
Claim 6
Dependent Claim
25 words
An elastomer in accordance with claim 1, 2, or 4 wherein the trans isomer content of the R or D radical is at least 90%.
Claim 7
Dependent Claim
13 words
A use of the elastomer of claim 1 to form a shaped article.
Claim 8
Dependent Claim
18 words
A use in accordance with claim 6 wherein the shaped article is a melt-spun strip, fiber or filament.
Claim 9
Dependent Claim
21 words
A use in accordance with claim 7 wherein the the strip, fiber or filament is a drawn strip, fiber or filament.
Claim 10
Dependent Claim
15 words
A use in accordance with claim 6 wherein the shaped article is a molded object.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-01-14 | 1994-07-16 | 1995-01-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-01-14 | 1998-07-16 | 1999-01-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-01-14 | 2002-07-16 | 2003-01-15 | $7700.00 | Window Closed / Lapsed |