US4985475A
Expired / Lapsed
US
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Encapsulant compositions for use in signal transmission devices
Assignee: 3M Co
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Filing: 1988-11-25
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Granted: 1991-01-15
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Expires: 2008-11-25
Abstract
Abstract The invention provides a grease compatible encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized compound, a crosslinking agent, and an oxirane containing material which provides improved hydrolytic stability to the encapsulant composition.
Inventors
- 👤 Thomas S. Croft
- 👤 Hartwick Haugen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 17:57
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/44; H01B3/26; H01B7/00; H01B7/17; H01B7/28; H01B7/282; H01B7/285
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
135 words
A grease compatible, hydrolytically stable dielectric encapsulant capable of being used to encapsulate a splice of a signal conducting device comprising: an extended reaction product of an admixture of (a) an effective amount of an anhydride functionalized compound having reactive anhydride sites; (b) an effective amount of a crosslinking agent that reacts with the anhydride sites of said compound to form a cured cross-linked material; and (c) an effective amount of an oxirane containing material to provide hydrolytic stability; wherein said reaction product is extended with at least one plasticizer present in the range of between 5 and 95 percent by weight of the encapsulant and said at least one plasticizer is essentially inert with said reaction product and is substantially non-exuding therefrom; and said encapsulant having a C-H adhesion value of at least 4.
Claim 2
Dependent Claim
135 words
A grease compatible, hydrolytically stable dielectric encapsulant capable of being used to encapsulate a splice of a signal conducting device comprising: an extended reaction product of an admixture of (a) an effective amount of an anhydride functionalized compound having reactive anhydride sites; (b) an effective amount of a crosslinking agent that reacts with the anhydride sites of said compound to form a cured cross-linked material; and (c) an effective amount of an oxirane containing material to provide hydrolytic stability; wherein said reaction product is extended with at least one plasticizer present in the range of between 5 and 95 percent by weight of the encapsulant and said at least one plasticizer is essentially inert with said reaction product and is substantially non-exuding therefrom; and said encapsulant having a C-H adhesion value of at least 4.
Claim 3
Dependent Claim
16 words
The encapsulant of claim 1 wherein said oxirane containing material has at least one oxirane group.
Claim 4
Dependent Claim
27 words
The encapsulant of claim 2 wherein said admixture has a ratio of equivalents of anhydride functionalized compound to epoxy equivalent of between about 0.25 to about 1.5.
Claim 5
Dependent Claim
15 words
The encapsulant of claim 3 wherein said ratio is between about 0.25 to about 0.55.
Claim 6
Dependent Claim
24 words
The encapsulant of claim 2 wherein said oxirane containing material is selected from the group consisting of aliphatic alkyl, alkenyl, alkadiene, and cycloalkyl epoxies.
Claim 7
Dependent Claim
37 words
The encapsulant of claim 5 wherein said oxirane containing material is selected from the group consisting of aliphatic glycidyl ethers, aliphatic glycidyl esters, epoxidized dienes, epoxidized polyesters, epoxidized alpha olefins, epoxidized polyolefins, epoxidized natural rubber, epoxidized oils.
Claim 8
Dependent Claim
14 words
The encapsulant of claim 6 wherein said oxirane containing material is an epoxidized oil.
Claim 9
Dependent Claim
15 words
The encapsulant of claim 7 wherein said epoxidized oil is an epoxidized polyunsaturated vegetable oil.
Claim 10
Dependent Claim
25 words
The encapsulant of claim 2 wherein said oxirane containing material is selected from the group consisting of monoepoxy, diepoxy and polyepoxy compounds and combinations thereof.
Claim 11
Dependent Claim
34 words
The encapsulant of claim 1 wherein said oxirane containing material is present in an amount ranging between about 1.5 to about 50 percent by weight based on the total solids of said reaction product.
Claim 12
Dependent Claim
61 words
The encapsulant of claim 10 wherein said anhydride functionalized compound is present in an amount ranging between about 1 to about 90 percent by weight based on total solids of said reaction product and said crosslinking agent is present in an amount ranging between about 0.5 to about 80 percent by weight based on the total solids of said reaction product.
Claim 13
Dependent Claim
70 words
The encapsulant of claim 1 wherein said anhydride functionalized compound is present in an amount ranging from about 3 to 60 percent by weight, said crosslinking agent is present in an amount ranging from about 1 to 30 percent by weight and said oxirane containing material is present in an amount ranging from about 1.5 to about 20 percent by weight, each based on the total weight of the encapsulant.
Claim 14
Dependent Claim
28 words
The encapsulant of claim 11 further comprising a catalyst present in an amount between 0.1 and 5 percent by weight based on total solids of said reaction product.
Claim 15
Dependent Claim
26 words
The encapsulant of claim 1 wherein said encapsulant has a tensile strength of less than about 21.1N/cm 2 and between about 50 to 250 percent elongation.
Claim 16
Dependent Claim
17 words
The encapsulant of claim 1 having a total solubility parameter of between about 7.9 to about 9.5.
Claim 17
Dependent Claim
14 words
The encapsulant of claim 1 having a Polycarbonate Compatibility Value of at least 80.
Claim 18
Dependent Claim
158 words
A hydrolytically stable dielectric encapsulant capable of being used to encapsulate a signal transmission device comprising: (1) an extended reaction product of an admixture of (a) an effective amount of an anhydride functionalized compound having reactive anhydride sites; (b) an effective amount of a polyol cross-linking agent that reacts with the anhydride sites of said compound to form a cured crosslinked material; (c) an effective amount of an oxirane material sufficient to provide hydrolytic stability; (d) an effective amount of a catalyst for the reaction between said anhydride functionalized composition, said polyol crosslinking agent and said oxirane material capable of catalyzing the reaction thereof in less than about 24 hours at 25° C.; and (2) at least one plasticizer present in the range of between 5 and 95 percent by weight of said encapsulant and being essentially inert with said reaction product and substantially non-exuding therefrom, wherein said encapsulant has a C-H adhesion value of at least 4.
Claim 19
Dependent Claim
158 words
A hydrolytically stable dielectric encapsulant capable of being used to encapsulate a signal transmission device comprising: (1) an extended reaction product of an admixture of (a) an effective amount of an anhydride functionalized compound having reactive anhydride sites; (b) an effective amount of a polyol cross-linking agent that reacts with the anhydride sites of said compound to form a cured crosslinked material; (c) an effective amount of an oxirane material sufficient to provide hydrolytic stability; (d) an effective amount of a catalyst for the reaction between said anhydride functionalized composition, said polyol crosslinking agent and said oxirane material capable of catalyzing the reaction thereof in less than about 24 hours at 25° C.; and (2) at least one plasticizer present in the range of between 5 and 95 percent by weight of said encapsulant and being essentially inert with said reaction product and substantially non-exuding therefrom, wherein said encapsulant has a C-H adhesion value of at least 4.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-01-14 | 1994-07-16 | 1995-01-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-01-14 | 1998-07-16 | 1999-01-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-01-14 | 2002-07-16 | 2003-01-15 | $7700.00 | Window Closed / Lapsed |