Actinic ray curable composition for casting polymerization and casting polymerization molded products

Claim 2

An actinic ray curable composition for casting polymerization which comprises: (A) 40-90 parts by weight of an urethane poly(meth)acrylate having at least two (meth)acryloyl groups in one molecule, obtained by addition reaction of a hydroxyl group-containing (meth)acrylate and a polyisocyanate represented by the general formula (IV) ##STR10## (wherein Ar represents a phenyl group, a biphenyl group, a naphthylene group or a diphenylmethane group), (B) 10-60 parts by weight of a radical polymerizable vinyl monomer having a boiling point of 100° C. or higher, being at least one monofunctional monomer selected from benzyl (meth)acrylate, phenyl (meth)acrylate, phenoxyethyl (meth)acrylate, biphenyl (meth) acrylate and cyclohexyl (meth)acrylate and/or at least one polyfunctional monomer selected from ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, pentaethylene glycol di(meth)acrylate, 1,3-butylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, tetrapropylene glycol di(meth)acrylate, 2,2 -bis(4-(meth)acryloxydiethoxyphenyl)propane, 2,2'-bis(4-(meth)acryloxydiethoxyphenyl)propane, 2,2'-bis(4-(meth)acryloxypentaethoxyphenyl)propane, 2,2'-bis(4-(meth)acryloxyethoxy-3,5-dibromophenyl)propane, 2,2'-bis(4-(meth)acryloxydiethoxy-3,5-dibromophenyl)propane and 2,2'-bis(4-(meth)acryloxypentaethoxy-3,5-dibromo-phenyl)propane, and (C) 0.01 to 0.1 parts by weight, per 100 parts by weight of total of the above components (A) and (B), of at least one member selected from methylphenyl glyoxylate, 2-hydroxy-2-methyl-1-phenylpropane-1-one, hydroxycyclohexyl phenyl ketone and a photo-initiator represented by the general formula (I): ##STR11## (wherein R 1 and R 2 which may be identical or different each represents a phenyl group, a methoxy group, an ethoxy group or an isopropyloxy group).

Claim 3

An actinic ray curable composition for casting polymerization according to claim 1 wherein the radical polymerizable vinyl monomer (B) represented by the general formula (II) is at least one selected from benzyl (meth)acrylate, phenyl (meth)acrylate, phenoxyethyl (meth)acrylate, biphenyl (meth)acrylate and cyclohexyl (meth)acrylate.

Claim 4

An actinic ray curable composition for casting polymerization according to claim 1 wherein the polyisocyanate represented by the general formula (IV) is at least one selected from m-tetramethylxylene diisocyanate and p-tetramethylxylene diisocyanate.

Claim 5

An actinic ray curable composition for casting polymerization according to claim 1 wherein the polymerization initiator (C) is 2,4,6-trimethylbenzoyl-diphenylphosphine oxide and is used in an amount of 0.01-0.1 part by weight per 100 parts by weight of casting polymerization composition.

Claim 6

A casting polymerization molded product obtained by radical polymerization, with actinic ray, of an actinic ray curable composition for casting polymerization comprising: (A) 40-90 parts by weight of an urethane poly-(meth)acrylate having at least two (meth)acryloyl groups in one molecule obtained by addition reaction of a hydroxyl group-containing (meth)acrylate and a polyisocyanate represented by the general formula (IV) ##STR12## (wherein Ar represents a phenyl group, a biphenyl group, a naphthalene group or a diphenylmethane group), (B) 10-60 parts by weight of a radical polymerizable vinyl monomer having a boiling point of 100° C. or higher, being at least one monofunctional monomer selected from benzyl (meth)acrylate, phenyl (meth)acrylate, phenoxyethyl (meth)acrylate, biphenyl (meth) acrylate and cyclohexyl (meth)acrylate and/or at least one polyfunctional monomer selected from ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, pentaethylene glycol di(meth)acrylate, 1,3-butylene glycol di(meth)acrylate, dipropylene glycol di,(meth)acrylate, tetrapropylene glycol di(meth)acrylate, 2,2'-bis(4-(meth)acryloxydiethoxyphenyl)propane, 2,2'-bis(4-(meth)acryloxypentaethoxyphenyl) propane, 2,2'-bis(4-(meth)acryloxyethoxy)-3,5-dibromophenyl)propane, 2,2'-bis(4-(meth)acryloxydiethoxy-3,5-dibromophenyl)propane and 2,2'-bis(4-(meth)acryloxypentaethoxy-3,5-dibromophenyl)propane, and (C) 0.01 to 0.1 parts by weight, per 100 parts by weight of total of the above components (A) and (B), of at least one member selected from methylphenyl glyoxylate, 2-hydroxy-2-methyl-1-phenylpropane-1-one, hydroxycyclohexyl phenyl ketone and a photo-initiator represented by the general formula (I): ##STR13## (wherein R 1 and R 2 which may be identical or different each represents a phenyl group, a methoxy group, an ethoxy group or an isopropyloxy group).

Claim 7

A casting polymerization molded product obtained by radical polymerization, with actinic ray, of an actinic ray curable composition for casting polymerization comprising: (A) 40-90 parts by weight of an urethane poly-(meth)acrylate having at least two (meth)acryloyl groups in one molecule obtained by addition reaction of a hydroxyl group-containing (meth)acrylate and a polyisocyanate represented by the general formula (IV) ##STR12## (wherein Ar represents a phenyl group, a biphenyl group, a naphthalene group or a diphenylmethane group), (B) 10-60 parts by weight of a radical polymerizable vinyl monomer having a boiling point of 100° C. or higher, being at least one monofunctional monomer selected from benzyl (meth)acrylate, phenyl (meth)acrylate, phenoxyethyl (meth)acrylate, biphenyl (meth) acrylate and cyclohexyl (meth)acrylate and/or at least one polyfunctional monomer selected from ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, pentaethylene glycol di(meth)acrylate, 1,3-butylene glycol di(meth)acrylate, dipropylene glycol di,(meth)acrylate, tetrapropylene glycol di(meth)acrylate, 2,2'-bis(4-(meth)acryloxydiethoxyphenyl)propane, 2,2'-bis(4-(meth)acryloxypentaethoxyphenyl) propane, 2,2'-bis(4-(meth)acryloxyethoxy)-3,5-dibromophenyl)propane, 2,2'-bis(4-(meth)acryloxydiethoxy-3,5-dibromophenyl)propane and 2,2'-bis(4-(meth)acryloxypentaethoxy-3,5-dibromophenyl)propane, and (C) 0.01 to 0.1 parts by weight, per 100 parts by weight of total of the above components (A) and (B), of at least one member selected from methylphenyl glyoxylate, 2-hydroxy-2-methyl-1-phenylpropane-1-one, hydroxycyclohexyl phenyl ketone and a photo-initiator represented by the general formula (I): ##STR13## (wherein R 1 and R 2 which may be identical or different each represents a phenyl group, a methoxy group, an ethoxy group or an isopropyloxy group).

Claim 8

A casting polymerization molded product according to claim 5 wherein the radical polymerizable monomer (B) represented by the general formula (II) is at least one selected from benzyl (meth)acrylate, phenyl (meth)acrylate, phenoxyethyl (meth)acrylate, biphenyl (meth)acrylate and cyclohexyl (meth)acrylate.

Claim 9

A casting polymerization molded product according to claim 5 wherein the polyisocyanate represented by the general formula (IV) is at least one selected from m-tetramethylxylene diisocyanate and p-tetramethylxylene diisocyanate.

Claim 10

A casting polymerization molded product according to claim 5 wherein the polymerization initiator (C) is 2,4,6-trimethylbenzoyldiphenylphosphine oxide and is used in an amount of 0.01-0.1 part by weight per 100 parts by weight of casting polymerization composition.