Abstract A liquid separation membrane for pervaporation composed of a polymeric substance having in the main chain a glycosidic skeleton containing cationic groups and/or anionic groups at least some of which form a salt with counter anions and/or counter cations; and a method for pervaporation, which comprises separating a water-organic liquid mixture or an organic liquid-organic liquid mixture by pervaporation using a separation membrane, said membrane being composed of a polymeric substance having in the main chain a glycosidic skeleton containing cationic groups and/or anionic groups at least some of which form a salt with counter anions and/or counter cations and being dried so as to have a water content of not more than 25% by weight.
A membrane for pervaporation composed of a salt of chitosan containing at least 2 mole % of nonpolymeric polybasic acid ion based on the amino groups of the chitosan.
Claim 2
Dependent Claim
29 words
A membrane for pervaporation composed of a salt of chitosan containing at least 2 mole % of nonpolymeric polybasic acid ion based on the amino groups of the chitosan.
Claim 3
Dependent Claim
15 words
The membrane for pervaporation of claim 1 in which the polybasic acid is sulfuric acid.
Claim 4
Dependent Claim
15 words
The membrane for pervaporation of claim 1 in which the polybasic acid is phosphoric acid.
Claim 5
Dependent Claim
94 words
A membrane for pervaporation composed of a salt of chitosan containing at least 2 mole % of nonpolymeric polybasic acid ion based on the amino group of the chitosan, said membrane being produced by a process comprising the steps of: (I) dissolving chitosan in a dilute aqueous solution of a monobasic acid, (II) producing a membrane composed of a chitosan salt containing a monobasic acid ion, (III) neutralizing the membrane with an aqueous alkaline solution, and (IV) contacting the chitosan membrane thus produced with an acid solution containing at least a nonpolymeric polybasic acid.
Claim 6
Dependent Claim
94 words
A membrane for pervaporation composed of a salt of chitosan containing at least 2 mole % of nonpolymeric polybasic acid ion based on the amino group of the chitosan, said membrane being produced by a process comprising the steps of: (I) dissolving chitosan in a dilute aqueous solution of a monobasic acid, (II) producing a membrane composed of a chitosan salt containing a monobasic acid ion, (III) neutralizing the membrane with an aqueous alkaline solution, and (IV) contacting the chitosan membrane thus produced with an acid solution containing at least a nonpolymeric polybasic acid.
Claim 7
Dependent Claim
15 words
The membrane for pervaporation of claim 4 in which the polybasic acid is sulfuric acid.
Claim 8
Dependent Claim
15 words
The membrane for pervaporation of claim 4 in which the polybasic acid is phosphoric acid.