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Preparation of cyano-containing perfluoropolymers having iodine curesites

Assignee: EIDP Inc
•
Filing: 1989-05-19
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Granted: 1991-01-08
•
Expires: 2009-05-19
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Abstract

Abstract In the preparation of perfluoropolymers by the interpolymerization of tetrofluoroethylene, perfluro (alkyl vinyl) ether and cyano-cure site monomer, the improvement of incorporating iodo moieties by the reaction of iodo-compounds of the formula RIn, in which R is a hydrocarbon or halocarbon radical of 1 to 8 carbon atoms and n is 1 or 2.

Inventors

  • 👤 Anestis L. Logothetis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 13:25
CPC Classifications
C; C08; C08F; C08F214/00; C08F214/18; C08F214/26; C08F214/262; C08F216/00; C08F216/12; C08F216/14

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 61 words
In a process for the preparation of perfluoropolymer by the random copolymerization of tetrafluoroethylene, perfluoro (alkyl vinyl) ether and fluorinated curesite monomer containing nitrile groups, the improvement wherein the copolymerization reactants further comprise iodo-compounds of the formula RI n , in which R is a hydrocarbon or halocarbon radical of 1 to 8 carbon atoms and n is 1 or 2.
Claim 2
Dependent Claim 61 words
In a process for the preparation of perfluoropolymer by the random copolymerization of tetrafluoroethylene, perfluoro (alkyl vinyl) ether and fluorinated curesite monomer containing nitrile groups, the improvement wherein the copolymerization reactants further comprise iodo-compounds of the formula RI n , in which R is a hydrocarbon or halocarbon radical of 1 to 8 carbon atoms and n is 1 or 2.
Claim 3
Dependent Claim 16 words
A process of Claim 1 wherein the R group in the iodo-compound is a hydrocarbon radical.
Claim 4
Dependent Claim 16 words
A process of Claim 1 wherein the R group in the iodo-reactant is a halocarbon radical.
Claim 5
Dependent Claim 12 words
A process of Claim 1 wherein the iodo-compound is a di-iodo compound.
Claim 6
Dependent Claim 12 words
A process of Claim 4 wherein the iodo-compound consists essentially of diiodoperfluorobutane.
Claim 7
Dependent Claim 12 words
A process of Claim 4 wherein the iodo-compound consists essentially of diiodoperfluorohexane.
Claim 8
Dependent Claim 13 words
A process of Claim 2 wherein the iodo-compound consists essentially of methylene iodide.
Claim 9
Dependent Claim 18 words
A process of Claim 1 wherein the perfluoro (alkyl vinyl) ether consists essentially of perfluoro (methyl vinyl) ether.
Claim 10
Dependent Claim 18 words
A process of Claim 1 wherein the perfluoro (alkyl vinyl) ether is a perfluoro (alkoxy alkyl vinyl) ether.
Claim 11
Dependent Claim 17 words
A process of Claim 9 wherein the perfluoro (alkoxy alkyl vinyl) ether consists essentially of perfluoro (5-methyl-3,6-dioxa-1-nonene).
Claim 12
Dependent Claim 29 words
A process of Claim 1 wherein the nitrile curesites comprise at least about 0.1% by weight of the perfluoropolymer, and are randomly distributed along the backbone of the perfluoropolymer.
Claim 13
Dependent Claim 17 words
A process of Claim 1 wherein the interpolymerization is carried out in a continuous stirred tank reactor.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-07 1994-07-09 1995-01-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-07 1998-07-09 1999-01-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-07 2002-07-09 2003-01-08 $7700.00 Window Closed / Lapsed

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