Multipurpose polymer bound stabilizers

Claim 2

A polymer with recurring units having a formula ##STR16## or both in which the units occur either in the polymer backbone, on grafted side chains, as pendant units, or as combinations thereof and wherein x is 0 or 1, R 1 and R 2 are independently hydrogen, alkyl of 1-6 carbons, cycloalkyl of 5-7 carbons, phenyl, chlorine or bromine and each ##STR17## is the residue of a primary amino substituted stabilizer group selected from (a) hindered phenols, (b) hindered amine light stabilizers, (c) 2-hydroxybenzophenones, (d) 2-(2-hydroxyphenyl)-2H-benzotriazoles, (e) secondary aromatic amines, (f) mercaptobenzothiazoles or mercaptobenzimidazoles, (g) aryl salicylates, (h) salicylic acid derivatives, (i) oxamide derivatives or (j) dialkyl sulfides, with the proviso that at least two different groups from (a) through (j) are attached to the polymer.

Claim 3

The composition of claim 1 in which (a) is ##STR18## wherein R 3 is t-alkyl of 4-8 carbons, R 4 is hydrogen, hydroxyl, alkyl of 1-8 carbons or alkoxy of 1-8 carbons and X 1 is a direct bond or a divalent radical --(CH 2 ) y -- or --CH 2 --CH 2 --O-- in which y is 1, 2 or 3.

Claim 4

The composition of claim 1 in which (b) is ##STR19## wherein R 5 is hydrogen or alkyl of 1-4 carbons, R 6 hydrogen, oxyl, hydroxyl, alkyl of 1-20 carbons, alkenyl of 3-8 carbons, alkynyl of 3-8 carbons, aralkyl of 7-12 carbons, aliphatic acyl of 1-10 carbons, aromatic acyl of 7-13 carbons, alkoxycarbonyl of 2-9 carbons, aryloxycarbonyl of 7-15 carbons, alkyl, aryl, cycloalkyl or aralkyl substituted carbamoyl of 2-13 carbons, hydroxyalkyl of 1-5 carbons, 2-cyanoethyl, epoxyalkyl of 3-10 carbons or a polyalkylene oxide group of 4-20 carbons, and X 9 is a direct bond or a divalent radical --(CH 2 ) y --, --CH 2 --CH 2 --O-- or --R 7 --N(R 23 )--, where y is 1, 2 or 3, R 7 is alkylene of 2-12 carbons and R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons, 2-cyanoethyl or a radical of the formula ##STR20##

Claim 5

The composition of claim 1 in which (j) is --X 2 --C(═O)--(CH 2 ) z --S--R 8 wherein R 8 is aralkyl of 7-12 carbons, alkyl of 1-18 carbons or dialkylaminoalkyl of 3-12 carbons, z is 1 or 2 and X 2 is a divalent radical --CH 2 --CH 2 --O-- or --R 7 --N(R 23 )--, wherein R 7 is alkylene of 2-12 carbons, R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons or 2-cyanoethyl, R 5 is hydrogen or alkyl of 1-4 carbons and R 6 is hydrogen, oxyl, hydroxyl, alkyl of 1-20 carbons, alkenyl or alkynyl of 3-8 carbons, aralkyl of 7-12 carbons, aliphatic acyl of 1-10 carbons, aromatic acyl of 7-13 carbons, alkoxycarbonyl of 2-9 carbons, aryloxycarbonyl of 7-15 carbons, alkyl, aryl, cycloalkyl or aralkyl substituted carbamoyl of 2-13 carbons, hydroxyalkyl of 1-5 carbons, 2-cyanoethyl, epoxyalkyl of 3-10 carbons or a polyalkylene oxide group of 4-20 carbons.

Claim 6

The composition of claim 1 in which (c) is ##STR21## wherein R 9 and R 10 are independently hydrogen, hydroxyl, alkyl of 1-8 carbons, alkoxy of 1-4 carbons or a connecting group X 3 , with the proviso that only one of either R 9 or R 10 can be the connecting group X 3 , and X 3 is a direct bond or a divalent radical --CH 2 --CH 2 --O--, --R 7 --N(R 23 )--C(═O)-- or --R 7 --N(R 23 )--S(═O) 2 , in which R 7 is alkylene of 2-12 carbons, R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons or 2-cyanoethyl, R 5 is hydrogen or alkyl of 1-4 carbons and R 6 is hydrogen, oxyl, hydroxyl, alkyl of 1-20 carbons, alkenyl or alkynyl of 3-8 carbons, aralkyl of 7-12 carbons, aliphatic acyl of 1-10 carbons, aromatic acyl of 7-13 carbons, alkoxycarbonyl of 2-9 carbons, aryloxycarbonyl of 7-15 carbons, alkyl, aryl, cycloalkyl or aralkyl substituted carbamoyl of 2-13 carbons, hydroxyalkyl of 1-5 carbons, 2-cyanoethyl, epoxyalkyl of 3-10 carbons or a polyalkylene oxide group of 4-20 carbons and optional substituents for the aromatic nuclei are one or more of hydroxyl, alkyl of 1-8 carbons or alkoxy of 1-4 carbons.

Claim 7

The composition of claim 1 in which (d) is ##STR22## where R 11 is hydrogen, alkyl of 1-4 carbons, alkoxy of 1-4 carbons, carboxyl, alkoxycarbonyl of 2-11 carbons, carboxamide, chlorine, bromine, sulfonic acid, alkylsulfonyl, or the connecting group X 4 , R 12 is hydrogen, alkyl of 1-8 carbons, aralkyl of 7-12 carbons, aryl of 6-14 carbons or the connecting group X 5 , with the proviso that when R 12 is X 5 , R 11 cannot be X 4 , X 4 is a divalent radical --R 7 --N(R 23 )--S(═O) 2 -- or --R 7 --N(R 23 )--C(═O)--, in which R 7 is alkylene of 2-12 carbons, R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons or 2-cyanoethyl, X 5 is a direct bond or a divalent radical --(CH 2 ) y -- or --CH 2 --CH 2 --O--, R 5 is hydrogen or alkyl of 1-4 carbons, R 6 is hydrogen, oxyl, hydroxyl, alkyl of 1-20 carbons, alkenyl or alkynyl of 3-8 carbons, aralkyl of 7-12 carbons, aliphatic acyl of 1-10 carbons, aromatic acyl of 7-13 carbons, alkoxycarbonyl of 2-9 carbons, aryloxycarbonyl of 7-15 carbons, alkyl, aryl, cycloalkyl or aralkyl substituted carbamoyl of 2-13 carbons, hydroxyalkyl of 1-5 carbons, 2-cyanoethyl, epoxyalkyl of 3-10 carbons or a polyalkylene oxide group of 4-20 carbons, y is 1, 2 or 3 and optional substituents for rings A and B are one or more of alkyl or 1-8 carbons, alkoxy of 1-8 carbons, chlorine or bromine.

Claim 8

The composition of claim 1 in which (e) is ##STR23## where R 13 is aryl of 6-14 carbons, alkyl of 1-12 carbons or cycloalkyl of 5-12 carbons and X 6 is a direct bond.

Claim 9

The composition of claim 1 in which (f) is ##STR24## where Q is --NH--, --S-- or --O--, X 7 is a direct bond and the aromatic nucleus is optionally substituted with one or more of hydroxy, alkyl of 1-8 carbons or alkoxy of 1-8 carbons.

Claim 10

The composition of claim 1 in which (h) is ##STR25## where X 2 is a divalent radical --CH 2 --CH 2 --O-- or --R 7 --N(R 23 )-- wherein R 7 is alkylene of 2-12 carbons, R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons or 2-cyanoethyl, and the aromatic nucleus is optionally substituted with one or more of hydroxy, alkyl of 1-8 carbons or alkoxy of 1-8 carbons.

Claim 11

The composition of claim 1 in which (g) is ##STR26## where R 14 is aryl of 6-10 carbons, optionally substituted with one or more of alkyl of 1-8 carbons, alkoxy of 1-8 carbons, chlorine or bromine and X 7 is a direct bond.

Claim 12

The composition of claim 1 in which (i) is ##STR27## wherein R 15 , R 16 , R 17 , R 18 and R 19 are independently hydrogen, hydroxyl, alkoxy of 1-12 carbons, alkylthio of 1-12 carbons, acyloxy of 2-12 carbons, acylthio of 2-12 carbons, alkyl of 1-8 carbons, aryl of 6-12 carbons, chlorine, bromine, aralkyl of 7-13 carbons, alkaryl of 7-13 carbons or alkoxycarbonyl of 2-8 carbons and X 8 is alkylene of 2-12 carbons, arylene of 6-12 carbons, aralkylene of 7-13 carbons or alkenylene of 2-13 carbons.

Claim 13

The composition of claim 3 in which at least one of the groups attached to the polymer is (b) in which R 5 is hydrogen or methyl, R 6 is hydrogen, methyl, acetyl, benzoyl, 2-hydroxyethyl or benzyl and X 9 is a direct bond, --(CH 2 ) y -- or --R 7 --N(R 23 )--, where R 7 is alkylene of 2-10 carbons and R 23 is hydrogen, alkyl of 1-4 carbons or 2,2,6,6-tetramethyl-4-piperidinyl.

Claim 14

The composition of claim 12 in which one of the other groups attached to the polymer is (d) having a structure ##STR28## in which R 11 is hydrogen or chlorine, R 12 is X 5 and X 5 is --(CH 2 ) y -- or --CH 2 --CH 2 --O--, an optional substituent for Ring B being alkyl of 1-8 carbons.

Claim 15

The composition of claim 12 in which one of the other groups attached to the polymer is (c) having a structure ##STR29## in which R 9 is hydrogen, hydroxyl or alkoxy of 1 to 4 carbons, R 10 is the connecting group X 3 and X 3 is --CH 2 --CH 2 --O--.

Claim 16

The composition of claim 12 in which one of the other groups attached to the polymer is (a) having a structure ##STR30## in which the hydroxyl group is in the 4 position, R 3 and R 4 are independently t-butyl or t-amyl where at least one of the t-alkyl groups is ortho to the hydroxyl group and X 1 is a direct bond or a divalent radical --(CH 2 ) y -- or --CH 2 --CH 2 --O-- in which y is 1, 2 or 3.

Claim 17

The composition of claim 12 in which one of the other groups attached to the polymer is (g) having a structure ##STR31## where R 14 is aryl of 6-10 carbons optionally substituted with one or more of alkyl of 1-8 carbons, chlorine or bromine and X 7 is a direct bond.

Claim 18

The composition of claim 12 in which one of the other groups attached to the polymer is (i) having a structure ##STR32## wherein R 15 , R 16 , R 17 , R 18 and R 19 are independently hydrogen, hydroxyl, alkyl of 1-4 carbons or alkoxy of 1-4 carbons, and X 8 is alkylene of 2-12 carbons, arylene of 6-12 carbons, aralkylene of 7-13 carbons, or alkenylene of 2-13 carbons.

Claim 19

The composition of claim 2 in which at least one of the groups attached to the polymer is (a) in which the hydroxyl group is in the 4 position, R 3 and R 4 are independently t-butyl or t-amyl where at least one of the t-alkyl groups is ortho to the hydroxyl group, X 1 is a direct bond or a divalent radical --(CH 2 ) y -- or --CH 2 --CH 2 --O-- and y is 1, 2 or 3.

Claim 20

The composition of claim 18 in which one of the other groups attached to the polymer is (j) having a structure --X.sup.2 --C(═O)--(CH.sub.2).sub.z --S--R.sup.8 in which R 8 is alkyl of 6-18 carbons, benzyl or dimethylaminoethyl, X 2 is --R 7 --N(R 23 )--, R 7 is alkylene of 2-6 carbons and R 23 is hydrogen.

Claim 21

The composition of claim 18 in which one of the other groups attached to the polymer is (c) having a structure ##STR33## in which R 9 is hydrogen, hydroxyl or alkoxy of 1-4 carbons, R 10 is the connecting group X 3 and X 3 is the diradical --CH 2 --CH 2 --O--.

Claim 22

The composition of claim 18 in which one of the other groups attached to the polymer is (d) having a structure ##STR34## in which R 11 is hydrogen or chlorine, R 12 is X 5 , X 5 is --(CH 2 ) y -- or --CH 2 --CH 2 --O-- and y is 1 or 2, an optional substituent for Ring B being alkyl of 1-8 carbons.

Claim 23

The composition of claim 18 in which one of the other groups attached to the polymer is (e) having a structure ##STR35## in which R 13 is aryl of 6-10 carbons or alkyl of 1-12 carbons and X 6 is a direct bond.

Claim 24

The composition of claim 5 in which at least one of the groups attached to the polymer is (c) in which R 9 is hydrogen, hydroxyl or alkoxy of 1 to 4 carbons, R 10 is the connecting group X 3 and X 3 is --CH 2 --CH 2 --O--.

Claim 25

The composition of claim 23 in which one of the other groups attached to the polymer is (h) having a structure ##STR36## in which X 2 is --R 7 --N(R 23 )--, wherein R 7 is alkylene of 2-12 carbons, R 23 is hydrogen, alkyl of 1-10 carbons, aryl of 6-12 carbons, aralkyl of 7-12 carbons, cycloalkyl of 5-12 carbons or 2-cyanoethyl.

Claim 26

The composition of claim 23 in which one of the other groups attached to the polymer is (f) having a structure ##STR37## in which Q is --NH--, --S-- or --O-- and X 7 is a direct bond.