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US4980430A
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Epoxy vinyl ethers and synthesis of an epoxy vinyl ether from a hydroxylated vinyl ether and a diepoxide
Assignee: ISP Investments LLC
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Filing: 1990-02-16
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Granted: 1990-12-25
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Expires: 2010-02-16
Abstract
Abstract This invention relates to epoxy vinyl ethers having the formula: ##STR1## where R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkyleneoxy; A is branched or linear C 1 to C 4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5; and T is ##STR2## when p is one, and is ##STR3## or a mixture of ##STR4## and ##STR5## when p is greater than one.
Inventors
- 👤 Kou-Chang Liu
- 👤 Fulvio J. Vara
- 👤 James A. Dougherty
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:11
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/14; C08G59/1433; C08G59/1438; C08G59/1444; C08G59/18; C08G59/40; C08G59/62
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
95 words
The compound having the formula ##STR19## wherein R is a polyvalent linear, branched or cyclic hydrocarbon or alkoxylated hydrocarbon radical containing from 2 to 20 carbon atoms; A is branched or linear C 1 to C 4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5 and Y is ##STR20## when p is 1 and is ##STR21## or a mixture of ##STR22## and ##STR23## when p is greater than one.
Claim 2
Dependent Claim
95 words
The compound having the formula ##STR19## wherein R is a polyvalent linear, branched or cyclic hydrocarbon or alkoxylated hydrocarbon radical containing from 2 to 20 carbon atoms; A is branched or linear C 1 to C 4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5 and Y is ##STR20## when p is 1 and is ##STR21## or a mixture of ##STR22## and ##STR23## when p is greater than one.
Claim 3
Dependent Claim
47 words
The compound of claim 1 wherein R is a C 2 to C 6 aliphatic hydrocarbon, A is --CH 2 -- or ##STR24## m has a value of 0, n has a value of from 0 to 12 and p has a value of 1 to 3.
Claim 4
Dependent Claim
3 words
The compound ##STR25##
Claim 5
Dependent Claim
3 words
The compound ##STR25##
Claim 6
Dependent Claim
3 words
The compound ##STR26##
Claim 7
Dependent Claim
3 words
The compound ##STR26##
Claim 8
Dependent Claim
3 words
The compound ##STR27##
Claim 9
Dependent Claim
3 words
The compound ##STR27##
Claim 10
Dependent Claim
97 words
The process for synthesizing the compound of claim 1 by contacting a hydroxylated vinyl ether reactant of the formula (HO).sub.p ROCH═CH.sub.2 and a diepoxy aryl hydroxyalkyl ether coreactant of the formula ##STR28## wherein R, A, B, m, n and p are as defined, and wherein the number of epoxy groups exceeds the number of hydroxy groups in the reaction mixture by 1 to 5 and reacting said reactant and coreactant at a temperature of from about 100° C. to 175° C. in the presence of from about 0.01 to about 2 wt. % of a base catalyst.
Claim 11
Dependent Claim
15 words
The process of claim 6 wherein said hydroxylated vinyl ether is CH.sub.2 ═CHOC.sub.4 H.sub.8 OH
Claim 12
Dependent Claim
17 words
The process of claim 6 wherein said hydroxylated vinyl ether is the monovinyl ether of cyclohexane dimethanol.
Claim 13
Dependent Claim
17 words
The process of claim 6 wherein said hydroxylated vinyl ether is the monovinyl ether of cyclohexane trimethanol.
Claim 14
Dependent Claim
27 words
The process of claim 6 wherein A of the aromatic polyepoxide is ##STR29## m has value of zero n has a value of from 0 to 4.
Claim 15
Dependent Claim
31 words
The process of claim 6 wherein A of the aromatic polyepoxide is --CH 2 --, m has a value of zero and n has a value of from 0 to 4.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-12-24 | 1994-06-25 | 1994-12-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-12-24 | 1998-06-25 | 1998-12-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-12-24 | 2002-06-25 | 2002-12-25 | $7700.00 | Window Closed / Lapsed |