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US4980040A
Expired / Lapsed
US
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Photopromoted method for decomposing oxides of nitrogen into environmentally compatible products
Assignee: CLEARLOW Inc
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Filing: 1989-06-26
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Granted: 1990-12-25
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Expires: 2009-06-26
Abstract
Abstract A method is provided for the photopromoted solid-catalyzed decomposition of oxides of nitrogen such as nitric oxide which are major pollutants of air and the environment at large. By this method, oxides of nitrogen are decomposed into molecular nitrogen and molecular oxygen by reactive passage over a solid metal oxide catalyst at an elevated temperature under irradiation at wavelengths absorbable by the catalyst. In this manner, the major oxides of nitrogen pollutants originating in the exhaust gases produced by automobile engines, jet engines used in the propulsion of aircraft, gas-turbine power generators, and the combustion of fossil fuels generally are controlled and eliminated.
Inventors
- 👤 Norman N. Lichtin
- 👤 Kallambella M. Vijayakumar
- 👤 Junchang Dong
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 02:27
CPC Classifications
F; F01; F01N; F01N3/00; F01N3/08; F01N3/10; F01N3/18; F01N3/20; F01N3/2086; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01J; B01J19/00; B01J19/08; B01J19/12; B01J19/122; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
124 words
A photopromoted method for decomposing oxides of nitrogen into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergy at a predeterminable wavelength; introducing a gaseous stream comprising at least one oxide of nitrogen to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said oxide of nitrogen is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 2
Dependent Claim
124 words
A photopromoted method for decomposing oxides of nitrogen into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergy at a predeterminable wavelength; introducing a gaseous stream comprising at least one oxide of nitrogen to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said oxide of nitrogen is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 3
Dependent Claim
135 words
A photopromoted method for decomposing oxides of nitrogen into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergy at a predeterminable wavelength; introducing a gaseous stream comprising at least one oxide of nitrogen compound having the formula: NO.sub.x wherein x is a positive number to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said NO x compound is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 4
Dependent Claim
135 words
A photopromoted method for decomposing oxides of nitrogen into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergy at a predeterminable wavelength; introducing a gaseous stream comprising at least one oxide of nitrogen compound having the formula: NO.sub.x wherein x is a positive number to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said NO x compound is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 5
Dependent Claim
120 words
A photopromoted method for decomposing nitric oxide into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergY at a predeterminable wavelength; introducing a gaseous stream comprising at least nitric oxide to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said nitric oxide is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 6
Dependent Claim
120 words
A photopromoted method for decomposing nitric oxide into environmentally compatible products, said method comprising the steps of: obtaining at least one solid metal oxide catalyst capable of absorbing photoenergY at a predeterminable wavelength; introducing a gaseous stream comprising at least nitric oxide to said solid metal oxide catalyst to form a reaction mixture; heating said reaction mixture to an elevated temperature between about 100°-700° C.; and adding photoenergy at a wavelength absorbable by said heated solid metal oxide catalyst of said heated reaction mixture wherein the absorption of said photoenergy causes said heated metal oxide catalyst to enter into an activated catalytic state and said nitric oxide is decomposed by said activated catalytic state into molecules of nitrogen and oxygen.
Claim 7
Dependent Claim
45 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said reaction mixture further comprises at least one substance selected from the group consisting of water vapor, dinitrogen, dioxygen, methane, carbon monoxide, carbon dioxide, unburned hydrocarbons, partially oxidized hydrocarbons, soot, and particulate matter.
Claim 8
Dependent Claim
25 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said elevated temperature of said heated reaction mixture is between about 200°-400° C.
Claim 9
Dependent Claim
17 words
The photopromoted method as recited in claim 5 wherein said elevated temperature is between about 225°-275° C.
Claim 10
Dependent Claim
21 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said method is performed at ambient environmental total pressure.
Claim 11
Dependent Claim
19 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said solid metal oxide catalyst comprises iron.
Claim 12
Dependent Claim
19 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said solid metal oxide catalyst comprises nickel.
Claim 13
Dependent Claim
21 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said solid metal oxide catalyst comprises a particulate powder.
Claim 14
Dependent Claim
19 words
The photopromoted method as recited in claim 1, 2, or 3 wherein said photoenergy is supplied by a lamp.
Claim 15
Dependent Claim
18 words
The photopromoted method as recited in claim 11 wherein said lamp is a metal oxide heated to incandescence.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-12-24 | 1994-06-25 | 1994-12-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-12-24 | 1998-06-25 | 1998-12-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-12-24 | 2002-06-25 | 2002-12-25 | $7700.00 | Window Closed / Lapsed |