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US4972027A Expired / Lapsed US ⏱️ 0.0 years remaining

Composition curable at low temperature

Assignee: Kansai Paint Co Ltd
•
Filing: 1988-11-15
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Granted: 1990-11-20
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Expires: 2008-11-15
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Abstract

Abstract Disclosed is a composition curable at a low temperature and characterized in that the composition comprises: (a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing a radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising as its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer, (b) a chelate compound admixed with a nonaqueous dispersion.

Inventors

  • 👤 Osamu Isozaki
  • 👤 Noboru Nakai
  • 👤 Shinji Sugiura
  • 👤 Satoru Ito
  • 👤 Seiji Takami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:16
CPC Classifications
C; C08; C08L; C08L83/00; C08K; C08K5/00; C08K5/0091; C08F; C08F2/00; C08F2/04; C08F2/06; C08F2/08; C08L101/00; C08L101/02; C08L101/10; C09; C09D; C09D143/00; C09D143/04

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 363 words
A composition curable at a low temperature and characterized in that the composition comprises: (a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing at least one radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one copolymer selected from the group consisting of a copolymer X and a vinyl copolymer Y, wherein said copolymer X comprises as its monomer components an oxiranecontaining vinyl monomer and an alkoxysilane-containing vinyl monomer represented by the formula ##STR48## wherein A is ##STR49## or ##STR50## R 1 is a hydrogen atom or methyl, R 2 is a bivalent aliphatic saturated hydrocarbon group having 1 to 6 carbon atoms, R 3 and R 4 are the same or different and are each phenyl, alkyl having 1 to 6 carbon atoms or alkoxyl having 1 to 10 carbon atoms, R 5 is alkyl having 1 to 10 carbon atoms, and n is an integer of from 1 to 10, and wherein said vinyl copolymer Y comprises: i) the polysiloxane macromonomer prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR51## wherein R 6 is an aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl, and R 7 , R 8 and R 9 are each alkoxyl having 1 to 4 carbon atoms or hydroxyl with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR52## wherein R 10 is a hydrocarbon atom or methyl, R 11 , R 12 and R 13 are each hydroxyl, alkoxyl having 1 to 4 carbon atoms or an aliphatic hydrocarbon group having 1 to 8 carbon atoms, at least one of R 11 , R 12 and R 13 being hydroxyl or alkoxyl, and m is an integer of 1 to 6, the polysiloxane macromonomer having per molecule at least two functional groups selected from hydroxyl and the alkoxyl and being about 400 to about 100,000 in number average molecular weight, and ii) an oxirane-containing vinyl monomer, (b) a chelate compound admixed with the nonaqueous dispersion. dispersion.
Claim 2
Dependent Claim 363 words
A composition curable at a low temperature and characterized in that the composition comprises: (a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing at least one radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one copolymer selected from the group consisting of a copolymer X and a vinyl copolymer Y, wherein said copolymer X comprises as its monomer components an oxiranecontaining vinyl monomer and an alkoxysilane-containing vinyl monomer represented by the formula ##STR48## wherein A is ##STR49## or ##STR50## R 1 is a hydrogen atom or methyl, R 2 is a bivalent aliphatic saturated hydrocarbon group having 1 to 6 carbon atoms, R 3 and R 4 are the same or different and are each phenyl, alkyl having 1 to 6 carbon atoms or alkoxyl having 1 to 10 carbon atoms, R 5 is alkyl having 1 to 10 carbon atoms, and n is an integer of from 1 to 10, and wherein said vinyl copolymer Y comprises: i) the polysiloxane macromonomer prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR51## wherein R 6 is an aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl, and R 7 , R 8 and R 9 are each alkoxyl having 1 to 4 carbon atoms or hydroxyl with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR52## wherein R 10 is a hydrocarbon atom or methyl, R 11 , R 12 and R 13 are each hydroxyl, alkoxyl having 1 to 4 carbon atoms or an aliphatic hydrocarbon group having 1 to 8 carbon atoms, at least one of R 11 , R 12 and R 13 being hydroxyl or alkoxyl, and m is an integer of 1 to 6, the polysiloxane macromonomer having per molecule at least two functional groups selected from hydroxyl and the alkoxyl and being about 400 to about 100,000 in number average molecular weight, and ii) an oxirane-containing vinyl monomer, (b) a chelate compound admixed with the nonaqueous dispersion. dispersion.
Claim 3
Dependent Claim 21 words
A composition as defined in claim 1 wherein the oxirane-containing vinyl monomer is a vinyl monomer containing an alicyclic oxirane group.
Claim 4
Dependent Claim 24 words
A composition as defined in claim 1 wherein the oxirane-containing vinyl monomer is an acrylic or methacrylic acid ester containing an alicyclic oxirane group.
Claim 5
Dependent Claim 36 words
A composition as defined in claim 1 wherein the coplymerx is prepared from 1 part by weight of the alkoxysilane-containing vinyl monomer and about 0.02 to about 10,000 parts by weight of the oxirane-containing vinyl monomer.
Claim 6
Dependent Claim 30 words
A composition as defined in claim 1 wherein the compound (A) is at least one compound selected from the group consisting of methyltrimethoxysilane, phenyltrimethoxysilane, butyltrimethoxysilane, methyltriethoxysilane, methyltributoxysilane, phenyltrisilanol and methyltrisilanol.
Claim 7
Dependent Claim 31 words
A resin composition as defined in claim 1 wherein the compound (B) is at least one compound selected from the group consisting of β-acryloxyethyltriethoxysilane, β-methacryloxyethyltriethoxysilane, γ-methacryloxypropyltrimethoxysilane, γ-methacryloxypropyltriethoxysilane, γ-acryloxypropyltrimethoxysilane, γ-methacryloxybutyltriethoxysilane, and γ-acryloxypropyltrisilanol.
Claim 8
Dependent Claim 25 words
A composition as defined in claim 1 wherein the polysiloxane macromonomer has about 0.2 to about 1.9 polymerizable unsaturated bonds per molecule on the average.
Claim 9
Dependent Claim 39 words
A composition as defined in claim 1 wherein the vinyl copolymer y is prepared from about 0.01 to about 98 wt. % of the polysiloxane macromonomer and about 99.9 to about 2 wt. % of the oxirane-containing vinyl monomer.
Claim 10
Dependent Claim 23 words
A composition as defined in claim 1 wherein the vinyl copolymer y is about 2,000 to about 200,000 in number average molecular weight.
Claim 11
Dependent Claim 31 words
A composition as defined in claim 1 wherein the chelate compound is at least one selected from the group consisting of aluminum chelate compound, titanium chelate compound and zirconium chelate compound.
Claim 12
Dependent Claim 33 words
A composition as defined in claim 1 which comprises about 0.01 to about 30 parts by weight of the chelate compound per 100 parts by weight of the resin solids in the composition.

References Cited (Backward Citations)

US4618656A Cited
US4618653A Cited
US4690986A Cited
US4826893A Cited
US4618644A Cited
US4772672A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-11-19 1994-05-21 1994-11-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-11-19 1998-05-21 1998-11-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-11-19 2002-05-21 2002-11-20 $7700.00 Window Closed / Lapsed

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