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US4971897A
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Photographic silver halide element containing cyclic phosphazene and salt antistatic composition
Assignee: Eastman Kodak Co
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Filing: 1989-02-03
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Granted: 1990-11-20
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Expires: 2009-02-03
Abstract
Abstract The present invention provides an antistatic composition comprising a binder, a cyclic phosphazene, and a salt that complexes with the cyclic phosphazene. The cyclic phosphazene has the general formula <IMAGE> wherein x is 3 or 4.
Inventors
- 👤 Janglin Chen
- 👤 Wayne T. Ferrar
- 👤 Hans R. Grashof
- 👤 Akemi S. Marshall
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 23:48
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/856; C; C09; C09K; C09K3/00; C09K3/16
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
190 words
An element comprising a radiation sensitive layer comprising a silver halide emulsion and an insulating support having thereon an antistatic layer of a composition comprising a binder, not less than 1 percent of a cyclic phosphazene and an effective amount of a salt that complexes with the cyclic phosphazene to produce an antistatic layer, wherein said cyclic phosphazene may be represented as ##STR15## wherein the x is 3 or 4, R 1 represents the formula --(R 2 --O) n --R 3 wherein n is 0 to 50 and n is 2 or more in at least half of the total substituents, R 2 is randomly alkyl of from 2 to 4 carbon atoms, having from 2 to 4 carbon atoms in the straight chain between oxygen atoms, and R 3 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, amine, or thio of from 1 to 18 carbon atoms, W and X each independently represents ##STR16## wherein R 6 , R 7 , and R 8 each independently represents H, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, amine, or thio of from 1 to 18 carbon atoms.
Claim 2
Dependent Claim
190 words
An element comprising a radiation sensitive layer comprising a silver halide emulsion and an insulating support having thereon an antistatic layer of a composition comprising a binder, not less than 1 percent of a cyclic phosphazene and an effective amount of a salt that complexes with the cyclic phosphazene to produce an antistatic layer, wherein said cyclic phosphazene may be represented as ##STR15## wherein the x is 3 or 4, R 1 represents the formula --(R 2 --O) n --R 3 wherein n is 0 to 50 and n is 2 or more in at least half of the total substituents, R 2 is randomly alkyl of from 2 to 4 carbon atoms, having from 2 to 4 carbon atoms in the straight chain between oxygen atoms, and R 3 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, amine, or thio of from 1 to 18 carbon atoms, W and X each independently represents ##STR16## wherein R 6 , R 7 , and R 8 each independently represents H, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, amine, or thio of from 1 to 18 carbon atoms.
Claim 3
Dependent Claim
34 words
An element according to claim 1 wherein R 2 has 2 carbon atoms in the straight chain between oxygen atoms and n is from 2 to 10, and m is from 0 to 10.
Claim 4
Dependent Claim
14 words
An element according to claim 2 wherein W and X each independently represent --O--.
Claim 5
Dependent Claim
22 words
An antistatic composition according to claim 3 wherein R 2 is ethyl, and R 3 is each independently ethyl, perfluoroethyl, or phenyl.
Claim 6
Dependent Claim
82 words
An element according to claim 1 wherein the salt is selected from the group consisting of KCF 3 SO 3 , LiBF 4 , NaBF 4 , NaCF 3 SO 3 , KCF 3 CO 2 , LiCF 3 CO 2 , NaCF 3 CO 2 , KC 3 F 7 CO 2 , LiC 3 F 7 CO 2 , NaC 3 F 7 CO 2 , LiI, NaI, KI, C 4 F 4 SO 3 K, and KPF 6 .
Claim 7
Dependent Claim
11 words
An element according to claim 1 wherein said phosphazene is octakis[2-(2-methoxyethoxy)ethoxy]cyclotetraphosphazene.
Claim 8
Dependent Claim
13 words
An element according to claim 1 wherein the binder is a hydrophilic colloid.
Claim 9
Dependent Claim
19 words
The element of claim 1 wherein the layer comprising phosphazene is a layer other than the radiation sensitive layer.
Claim 10
Dependent Claim
10 words
The element of claim 1 wherein said support is planar.
Claim 11
Dependent Claim
31 words
The elements of claim 1 wherein R 3 is substituted or unsubstituted alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl, substituted aromatic, amine, or thio of from 1 to 18 carbon atoms.
Claim 12
Dependent Claim
19 words
The element of claim 10 wherein at least one of said R 3 represents a halogen substituted alkyl group.
Claim 13
Dependent Claim
12 words
The element of claim 1 wherein said binder comprises a hydrophobic polymer.
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