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US4970272A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyphenylene ether-polyamide compositions

Assignee: General Electric Co
•
Filing: 1989-01-27
•
Granted: 1990-11-13
•
Expires: 2009-01-27
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Abstract

Abstract Polyphenylene ether-polyamide compositions having improved resistance to water absorption and swell are provided by incorporating therein a phenolic compound.

Inventors

  • 👤 Robert R. Gallucci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 17:19
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L61/00; C08L61/04; C08L61/06; C08L77/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 213 words
An improved polyphenylene ether-polyamide composition exhibiting reduced water absorption and improved resistance to swell upon exposure to moisture consisting essentially of: (a) at least one polyphenylene ether; (b) at least one polyamide; and (c) an effective water absorption reducing amount of at least one effective polyhydric phenol, said amount being from about 1 to about 20 parts by weight of said polyhydric phenol per 100 parts by weight of (a) and (b), selected from polyhydric phenols represented by the formulae: ##STR8## wherein n has a value of from 2 to 3 inclusive, m has a value of from 3 to 4 inclusive and (n+m)=6, p is one or two, each r independently has a value of from 0 to 2 inclusive, each s independently has a value of from 2 to 4 inclusive, t has a value of from 0 to 4 inclusive, each R is hydrogen, and each R' independently selected from a direct carbon-carbon bond or a bridge member selected from divalent alkyl, aryl, arylalkyl, hydroxy aryl or alkyl hydroxy aryl, including halogen substituted derivatives thereof, divalent ester or amide radicals, and hetero atom containing bridges selected from ##STR9## provided that there are no phenolic hydroxy groups having two adjacent alkyl radicals to the phenyl ring with tertiary alpha carbon atoms.
Claim 2
Dependent Claim 213 words
An improved polyphenylene ether-polyamide composition exhibiting reduced water absorption and improved resistance to swell upon exposure to moisture consisting essentially of: (a) at least one polyphenylene ether; (b) at least one polyamide; and (c) an effective water absorption reducing amount of at least one effective polyhydric phenol, said amount being from about 1 to about 20 parts by weight of said polyhydric phenol per 100 parts by weight of (a) and (b), selected from polyhydric phenols represented by the formulae: ##STR8## wherein n has a value of from 2 to 3 inclusive, m has a value of from 3 to 4 inclusive and (n+m)=6, p is one or two, each r independently has a value of from 0 to 2 inclusive, each s independently has a value of from 2 to 4 inclusive, t has a value of from 0 to 4 inclusive, each R is hydrogen, and each R' independently selected from a direct carbon-carbon bond or a bridge member selected from divalent alkyl, aryl, arylalkyl, hydroxy aryl or alkyl hydroxy aryl, including halogen substituted derivatives thereof, divalent ester or amide radicals, and hetero atom containing bridges selected from ##STR9## provided that there are no phenolic hydroxy groups having two adjacent alkyl radicals to the phenyl ring with tertiary alpha carbon atoms.
Claim 3
Dependent Claim 34 words
The composition of claim 1 which contains from about 1.5 to about 10 parts by weight of said polyhydric phenol per one hundred parts by weight of the mixture of polyphenylene ether and polyamide.
Claim 4
Dependent Claim 11 words
The composition of claim 1 wherein said polyhydric phenol is II.
Claim 5
Dependent Claim 9 words
The composition of claim 3 wherein t is zero.
Claim 6
Dependent Claim 9 words
The composition of claim 4 wherein p is one.
Claim 7
Dependent Claim 25 words
The composition of claim 5 wherein R' is selected from a direct carbon-carbon bond or a bridge member selected from divalent alkyl, aryl, arylakyl, ##STR10##
Claim 8
Dependent Claim 13 words
The composition of claim 6 wherein R' is selected from divalent alkyl radicals.
Claim 9
Dependent Claim 14 words
The composition of claim 7 wherein said divalent alkyl radical is the isopropylidene radical.
Claim 10
Dependent Claim 10 words
The composition of claim 1 which further contains a filler.
Claim 11
Dependent Claim 10 words
The composition of claim 9 wherein said filler is glass.
Claim 12
Dependent Claim 12 words
The composition of claim 9 wherein said filler is a mineral filler.
Claim 13
Dependent Claim 19 words
The composition of claim 1 which further contains a flame retardant amount of at least one flame retardant compound.
Claim 14
Dependent Claim 71 words
A polyphenylene ether-polyamide composition comprising: (a) at least one polyphenylene ether; (b) at least one polyamide; and (c) 2,2-bis(4-hydroxyphenyl)propane present in an amount selected from 0.5 to 30 parts by weight per 100 parts by weight of the combination of polyphenylene ether and polyamide, the blending ratio of polyphenylene ether to polyamide being from 5 to 95% by weight of polyphenylene ether to 95 to 5% by weight of the polyamide.
Claim 15
Dependent Claim 71 words
A polyphenylene ether-polyamide composition comprising: (a) at least one polyphenylene ether; (b) at least one polyamide; and (c) 2,2-bis(4-hydroxyphenyl)propane present in an amount selected from 0.5 to 30 parts by weight per 100 parts by weight of the combination of polyphenylene ether and polyamide, the blending ratio of polyphenylene ether to polyamide being from 5 to 95% by weight of polyphenylene ether to 95 to 5% by weight of the polyamide.
Claim 16
Dependent Claim 34 words
The composition of claim 13 wherein said 2,2-bis(4-hydroxyphenyl)propane is present in an amount selected from 1 to 20 parts by weight per 100 parts by weight of the combination of polyphenylene ether and polyamide.
Claim 17
Dependent Claim 33 words
The composition of claim 14 wherein the blending ratio of polyphenylene ether to polyamide is from 30 to 70% by weight of polyphenylene ether to 70 to 30% by weight of the polyamide.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

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