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US4968593A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical information recording medium

Assignee: Fujifilm Corp
•
Filing: 1988-02-26
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Granted: 1990-11-06
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Expires: 2008-02-26
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Abstract

Abstract The present invention is directed to an optical information recording medium for carrying out recording, readout and erasing with laser beams which comprises a support having carried thereon at least one of the compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X and X' each represents an atomic group necessary for forming a carbon ring or an atomic group necessary for forming a specific heterocyclic ring; L 1 mainly represents a methine group, or a group formed by linking 3 or 5 methine groups in turn to form conjugated double bonds; and Q and Q' each represents an atomic group whereby a conjugated double bond chain is completed; ##STR2## wherein L 1 and Q are as defined in general formula (I); Z represents an atomic group necessary for forming a carbon ring or heterocyclic ring; R 1 to R 3 and E represent various substituents; and M represents an ion, etc.; ##STR3## in the above general formulae (III) and (IV), A represents an atomic group necessary for forming a pyridine, pyrimidine, pyrazine or triazine ring; and L 2 represents a methine group, or a group formed by linking 3 or 5 methine groups in turn to form conjugated double bonds. Optical information recording media of the invention each have a high C/N and thus adequate recording characteristics, and have a high stability with respect to long-term preservation or long-time reading. These effects may further be enhanced by using a singlet oxygen quencher.

Inventors

  • 👤 Yoshio Inagaki
  • 👤 Keiichi Adachi
  • 👤 Yoshihiro Jimbo
  • 👤 Masao Yabe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:13
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/249; G11B7/246; G11B7/247; G11B2007/24612; G11B7/245; G11B7/2472; G11B7/2478; G11B7/2495; G11B7/252; G11B7/253; G11B7/2533; G11B7/2534; Y; Y10; Y10S; Y10S430/00; Y10S430/146

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 552 words
An optical information recording medium for carrying out recording and readout with laser beams, which comprises a support, and a recording layer on the support containing at least one compound selected from the group consisting of general formulae (1), (II), (III) and (IV); ##STR104## wherein L 1 represents a methine group which may be substituted, or an atomic group whereby a polymethine chain is completed where 3, 5 or 7 methine groups are linked in turn to form conjugated double bonds and which chain may be substituted; Q and Q' are the same or different, and each represents an atomic group whereby a conjugated double bond chain is completed; m and n independently represent 0 or 1; and X and X' are the same or different, and each represents an atomic group necessary for forming a carbon ring, or an atomic group necessary for forming a heterocyclic ring selected from the following atomic groups (the carbon ring may form a condensed ring together with another ring, and the carbon ring or heterocyclic ring may have substituent(s)): ##STR105## (wherein R represents a hydrogen atom or a substituent) ##STR106## wherein Q, L 1 and m are as defined in general formula (I); Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring (the carbon ring or heterocyclic ring may form a condensed ring together with another ring, or any have substituent(s); M represents a hydrogen atom, a metal atom, a metal complex ion, an ammonium ion which may be substituted, or a quaternary phosphonium ion; E represents O, S or NR 4 ; R 1 and R 4 may be the same or different and each represents an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, an optionally substituted amino group, an optionally substituted hydrazino group or an optionally substituted diazenyl group; R 2 represents an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group or an optionally substituted heterocyclic group; R 3 represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a hydroxyl group, a carboxyl group, an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted alkenyl group, an optionally substituted alkoxy group, an optionally substituted aryloxy group, an optionally substituted heterocyclic group, an optionally substituted alkoxycarbonyl group, an optionally substituted aryloxycarbonyl group, an optionally substituted amino group, an optionally substituted acyloxy group, an optionally substituted carbamoyl group, an optionally substituted sulfamoyl group, an optionally substituted alkylthio group, an optionally substituted arylthio group, an optionally substituted alkylsulfonyl group, an optionally substituted arylsulfonyl group or an optionally substituted alkynyl group; and R 1 and R 4 may also combine to form a ring; ##STR107## in the above general formulae (III) and (IV), A represents an atomic group necessary for forming a pyridine, pyrimidine, pyrazine or triazine ring (these rings may each form a condensed ring together with a benzene ring, and these rings may each be substituted with substituent(s) each having 30 or less carbon atoms); and L 2 represents an optionally substituted methine group, or a group formed by linking optionally substituted 3 or 5 methine groups in turn to form conjugated double bonds.
Claim 2
Dependent Claim 552 words
An optical information recording medium for carrying out recording and readout with laser beams, which comprises a support, and a recording layer on the support containing at least one compound selected from the group consisting of general formulae (1), (II), (III) and (IV); ##STR104## wherein L 1 represents a methine group which may be substituted, or an atomic group whereby a polymethine chain is completed where 3, 5 or 7 methine groups are linked in turn to form conjugated double bonds and which chain may be substituted; Q and Q' are the same or different, and each represents an atomic group whereby a conjugated double bond chain is completed; m and n independently represent 0 or 1; and X and X' are the same or different, and each represents an atomic group necessary for forming a carbon ring, or an atomic group necessary for forming a heterocyclic ring selected from the following atomic groups (the carbon ring may form a condensed ring together with another ring, and the carbon ring or heterocyclic ring may have substituent(s)): ##STR105## (wherein R represents a hydrogen atom or a substituent) ##STR106## wherein Q, L 1 and m are as defined in general formula (I); Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring (the carbon ring or heterocyclic ring may form a condensed ring together with another ring, or any have substituent(s); M represents a hydrogen atom, a metal atom, a metal complex ion, an ammonium ion which may be substituted, or a quaternary phosphonium ion; E represents O, S or NR 4 ; R 1 and R 4 may be the same or different and each represents an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, an optionally substituted amino group, an optionally substituted hydrazino group or an optionally substituted diazenyl group; R 2 represents an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group or an optionally substituted heterocyclic group; R 3 represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a hydroxyl group, a carboxyl group, an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted alkenyl group, an optionally substituted alkoxy group, an optionally substituted aryloxy group, an optionally substituted heterocyclic group, an optionally substituted alkoxycarbonyl group, an optionally substituted aryloxycarbonyl group, an optionally substituted amino group, an optionally substituted acyloxy group, an optionally substituted carbamoyl group, an optionally substituted sulfamoyl group, an optionally substituted alkylthio group, an optionally substituted arylthio group, an optionally substituted alkylsulfonyl group, an optionally substituted arylsulfonyl group or an optionally substituted alkynyl group; and R 1 and R 4 may also combine to form a ring; ##STR107## in the above general formulae (III) and (IV), A represents an atomic group necessary for forming a pyridine, pyrimidine, pyrazine or triazine ring (these rings may each form a condensed ring together with a benzene ring, and these rings may each be substituted with substituent(s) each having 30 or less carbon atoms); and L 2 represents an optionally substituted methine group, or a group formed by linking optionally substituted 3 or 5 methine groups in turn to form conjugated double bonds.
Claim 3
Dependent Claim 99 words
The optical information recording medium of claim 1, wherein in the formula, (I), the atomic group forming a carbon ring represented by X or X' is selected from the group consisting of: ##STR108## the "substituent" in the definition of R or R' represents an optionally substituted alkyl group, an optionally substituted aralkyl group or an optionally substituted aryl group; and L 1 is selected from the group consisting of general formulae (a) to (h): ##STR109## in general formulae (a) to (h), Y represents a hydrogen atom or a monovalent group, and p and q independently represent 0 or 1.
Claim 4
Dependent Claim 77 words
The optical information recording medium of claim 2, wherein in general formula (II), a ring containing Z and Q is a 4-, 5-, 6- or 7-membered ring, these rings may each form a condensed ring together with another 4-, 5-, 6- or 7-membered ring, these rings may have substituent(s), and heteroatoms used for forming a heterocyclic ring containing Z and Q are selected from the group consisting of B, N, O, S, Se, Te and combinations thereof.
Claim 5
Dependent Claim 116 words
The optical information recording medium of claim 3, wherein in general formula (II), the atomic group forming a carbon ring represented by Z is selected from the group consisting of ##STR110## and the atomic group forming a heterocyclic ring represented by Z is selected from the group consisting of ##STR111## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted, aralkyl group or a substituted or unsubstituted aryl group, R' has the same meaning as R provided that R' does not represent a hydrogen atom, A has the same meaning as defined in general formula (III) and (IV) and E has the same meaning as defined in general formula (II).
Claim 6
Dependent Claim 118 words
The optical information recording medium of claim 1, wherein in the general formula (III) or (IV), the substituent(s) each having 30 or less carbon atoms represent(s) a member selected from the group consisting of alkyl, aralkyl, aryl, hydroxyl, F, Cl, Br, I, cyano, nitro, alkoxy, aralkyloxy, aryloxy, acyl, acyloxy, acylamino, sulfonamino, aryloxycarbonyl, aralkyloxycarbonyl, alkoxycarbonyl, carbamoyl, sulfamoyl, carboxyl or carboxylato, sulfonic acid or sulfonato, acrbamoylamino, sulfamoyl amino, alkylsulfonyl, aralkylsulfonyl, araylsulfonyl, alkylsulfinyl, aralkylsulfinyl, alkylthio, aralkylthio or arylthio group(s) (these groups may each further have substituent(s); and L 2 represents a group selected from the groups of the general formulae (a') to (g'): ##STR112## in the general formulae (a') to (g'), and Y represents a hydrogen atom or a monovalent group.
Claim 7
Dependent Claim 14 words
The optical information recording medium of claim 1, further comprising a singlet oxygen quencher.
Claim 8
Dependent Claim 60 words
The optical information recording medium of claim 6, wherein the singlet oxygen quencher is a compound represented by general formula (XI) or (XII): wherein [Cat 1 ] and [Cat 2 ] each represents a cation necessary for making each complex neutral, M 1 and M 2 each represents nickel, copper, cobalt, palladium or platinum, and r represents 1 or 2.
Claim 9
Dependent Claim 38 words
The general information recording medium of claim 6, wherein the quencher is used in an amount of 0.05 to 12 moles per 1 mole of at least one of the dyes of the general formulae (I) to (Iv).
Claim 10
Dependent Claim 33 words
The optical information recording medium of claim 1, further comprising a subbing layer on the support, a protective layer on said recording layer, and a reflecting layer on the support or recording layer.
Claim 11
Dependent Claim 16 words
The optical information medium of claim 6, wherein the quencher is contained in said recording layer.
Claim 12
Dependent Claim 66 words
The optical information recording medium of claim 2, wherein Y is a monovalent group selected from the group consisting of an optionally substituted lower alkyl group, an optionally substituted aralkyl group, an optionally substituted aryl group, a lower alkoxy group, a cycloalkyloxy group, a disubstituted amino group, an alkylcarbonyloxy group, an alkylthio group, an arylthio group, a cyano group, a nitro group and a halogen atom.
Claim 13
Dependent Claim 34 words
The optical information recording medium of claim 2, wherein L 1 is represented by general formulae (a) or (b), Y is a hydrogen atom and at least one of p and q is O.
Claim 14
Dependent Claim 94 words
The optical information recording medium of claim 1, wherein in formula (II), M is selected from the group consisting of a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, a nickel ion, a copper ion, an iron ion, a cobalt ion, a chromium ion, a cation complex containing Ni, Cu, Fe, Co or Cr, an ammonium ion optionally substituted with alkyl, aryl or aralkyl group(s) each having 30 or less carbon atoms, and a quaternary phosphonium ion substituted with alkyl, aryl or aralkyl group(s) each having 40 or less carbon atoms.
Claim 15
Dependent Claim 61 words
The optical information recording medium of claim 1, wherein in formula (II), R 1 or R 4 are selected from the group consisting of an optionally substituted alkyl group having 1 to 30 carbon atoms, an optionally substituted phenyl group having 6 to 30 carbon atoms, and an optionally substituted 5- or 6-membered heterocyclic group having 1 to 30 carbon atoms.
Claim 16
Dependent Claim 55 words
The optical information recording medium of claim 1, wherein in formula (11), R 2 is selected from the group consisting of an optionally substituted alkyl group having 1 to 30 carbon atoms, an optionally substituted phenyl group having 6 to 30 carbon atoms, and an optionally substituted heterocyclic group having 1 to 30 carbon atoms.
Claim 17
Dependent Claim 86 words
The optical information recording medium of claim 1, wherein in formula (II), R 3 is selected from the group consisting of a hydrogen atom, an optionally substituted alkyl group having 1 to 30 carbon atoms, an optionally substituted phenyl group having 6 to 30 carbon atoms, an optionally substituted carbamoyl group having 1 to 30 carbon atoms, an optionally substituted alkoxycarbonyl group having 2 to 30 carbon atoms, an optionally substituted phenoxycarbonyl group having 7 to 30 carbon atoms, a carbonyl group, and a hydroxyl group.
Claim 18
Dependent Claim 25 words
The optical information recording medium of claim 7, wherein [Cat 1 ] and [Cat 2 ] are alkali metal ions or alkaline earth metal ions.
Claim 19
Dependent Claim 24 words
The optical information recording medium of claim 7, wherein [Cat 1 ] and [Cat 2 ] are quaternary ammonium ions or quaternary phosphonium ions.
Claim 20
Dependent Claim 123 words
The optical information recording medium of claim 7, wherein [CatI] and [Cat 2 ] are selected from the group consisting of formulae (XIII-a), (XIII-b), (XIII-c), (XIII-d) and (XIII-e) wherein R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 , R 19 , R 20 , R 21 , and R 22 each represents a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 14 carbon atoms, and Z 1 and Z 2 each represent a nonmetal atomic group which forms a 5-membered or 6-membered ring together with a nitrogen atom or a phosphorous atom in each formula.
Claim 21
Dependent Claim 29 words
The optical information recording medium of claim 19 wherein [Cat 1 ] and [Cat 2 ] are selected from the group consisting of formulas (XIII-a), (XIII-b), (XIII-d) and (XIII-e).

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