Amorphous compositions of dyes and binder-mixtures in optical recording elements and information recorded elements

Claim 2

A recording element comprising a support having thereover a layer comprising an amorphous composition of a dye and a nonpolymeric binder-mixture at a high dye to binder-mixture ratio characterized in that the binder-mixture (a) is amorphous at high dye to binder ratios, (b) exhibits a single thermal transition with no phase separation after annealing, (c) is solid at about 20° C., and (d) comprises at least two different compounds, each having at least two linking components joining one multivalent organic nucleus with at least two organic nuclei wherein at least one of (e) the multivalent organic nucleus and (f) the organic nuclei is a multicyclic aromatic nucleus.

Claim 3

A recorded information element comprising a support having thereover a layer comprising an amorphous composition of a dye and a nonpolymeric binder-mixture at a high dye-binder ratio characterized in that the binder-mixture (a) is amorphous at high dye to binder ratios, (b) exhibits a single thermal transition with no phase separation after annealing, (c) is solid at about 20° C., and (d) comprises at least two different compounds each having at least two linking components joining one multivalent organic nucleus with at least two organic nuclei wherein at least one of (e) the multivalent organic nucleus and (f) the organic nuclei is a multicyclic aromatic nucleus.

Claim 4

A recorded information element comprising a support having thereover a layer comprising an amorphous composition of a dye and a nonpolymeric binder-mixture at a high dye-binder ratio characterized in that the binder-mixture (a) is amorphous at high dye to binder ratios, (b) exhibits a single thermal transition with no phase separation after annealing, (c) is solid at about 20° C., and (d) comprises at least two different compounds each having at least two linking components joining one multivalent organic nucleus with at least two organic nuclei wherein at least one of (e) the multivalent organic nucleus and (f) the organic nuclei is a multicyclic aromatic nucleus.

Claim 5

The recording element of claim 1 wherein each compound of the mixture has the structure (R.sup.1 Y.sup.1).sub.p [(Z.sup.1 Y.sup.2).sub.m R.sup.2 Y.sup.3 ].sub.n Z.sup.2 Y.sup.4 R.sup.3 ; wherein m is zero or one; n is the number of recurring units in the compound, and is zero up to, but not including, an integer at which said compound starts to become a polymer; p is an integer of from one to eight; R 1 and R 3 each independently represents a monovalent aliphatic or cycloaliphatic hydrocarbon group having 1 to 20 carbon atoms or an aromatic group; R 2 , Z 1 and Z 2 each independently represent multivalent aliphatic or cycloaliphatic hydrocarbon groups having 1 to 20 carbon atoms or an aromatic group; Y 1 , Y 2 , Y 3 and Y 4 each independently represent a linking group; provided that at least one of R 1 , Z 1 , R 2 , Z 2 and R 3 is a multicyclic aromatic nucleus.

Claim 6

The recorded information element of claim 2 wherein each compound in the mixture has the structure (R.sup.1 Y.sup.1).sub.p [(Z.sup.1 Y.sup.2).sub.m R.sup.2 Y.sup.3 ].sub.n Z.sup.2 Y.sup.4 R.sup.3 ; wherein m is zero or one; n is the number of recurring units in the compound, and is zero up to, but not including, an integer at which said compound starts to become a polymer; p is an integer of from one to eight; R 1 and R 3 each independently represents a monovalent aliphatic or cycloaliphatic hydrocarbon group having 1 to 20 carbon atoms or an aromatic group; R 2 , Z 1 and Z 2 each independently represent multivalent aliphatic or cycloaliphatic hydrocarbon groups having 1 to 20 carbon atoms or an aromatic group; Y 1 , Y 2 , Y 3 and Y 4 each independently represent a linking group; provided that at least one of R 1 , Z 1 , R 2 , Z 2 and R 3 is a multicyclic aromatic nucleus.

Claim 7

The element of claim 3 or 4 wherein n is zero; p is one to eight; R 1 and R 3 each independently represent methyl, ethyl, propyl, isopropyl, butyl, hexyl, 2-ethylhexyl, methoxyethyl, ethoxycarbonylpropyl, 3-oxobutyl, 3-thiapentyl, furfuryl, 2-thiazolylmethyl, cyclohexylmethyl, benzyl, phenethyl, phenoxyethyl, vinyl, 2-methylvinyl, pyridyl, phenyl, tolyl, xylyl, naphthyl, anthryl, triptycenyl, p-chlorophenyl, p-nitrophenyl, p-bromophenyl, 2,4-dichlorophenyl, 2-chlorophenyl, 3,5-dinitrophenyl, p-(tetrabromophthalimido)phenyl, p-(tetrachlorophthalimido)phenyl, p-tertraphenylphthalimido)phenyl, p-naphthalimidophenyl, p-(4-nitrophthalimido)phenyl, p-phthalimidophenyl, 1-hydroxy-2-naphthyl, 3,5-dibromo-4-(4-bromobenzoyloxy)phenyl, 3,5-dibromo-4-(3,5-dinitrobenzoyloxy)phenyl or 3,5-dibromo-4-(1-naphthoyloxy)phenyl; Z 2 represents a nucleus derived from 9,9-bis(4-hydroxy-3,5-dichlorophenyl)fluorene; 4,4'-hexahydro-4,7-methanoindan-5-ylidenebis(2,6-dichlorophenol); 9,9-bis(4-hydroxy-3,5-dibromophenyl)fluorene; 4,4'-hexahydro-4,7-methanoindan-5-ylidenebis(2,6-dibromophenol); 3',3",5',5"-tetrabromophenolphthalein; 9,9-bis(4-aminophenyl)fluorene, phenylindandiol, 1,1'-spirobiindandiol; 1,1'-spirobiindaniamine, 2,2'spirobichroman; 7,7-dimethyl-7H-dibenzo[c,h]xanthenediol; xanthylium salt diols; 9,9-dimethylxanthene-3,6-bis(oxyacetic acid), 4,4'(3-phenyl-1-indanylidene)diphenol, 3',3'-dibromo-5',5"-dinitro-2',2"-oxaphenolphthalein or 9-phenyl-3-oxo-2,6,7-trihydroxyanthene; and Y 1 and Y 4 each independently represents an ester, urethane, amide or imide linking group.

Claim 8

The element of claim 1 or 2 wherein at least one compound in the mixture is an oligomer in which m is one and n is from one to ten.

Claim 9

The element of claims 1 or 2 in which the mixture is selected from the group consisting of ##STR65##

Claim 10

The element of claim 1 or 2 wherein the mixture has a glass transition temperature of at least 100° C.

Claim 11

The element of claim 1 or 2 wherein the mixture has a glass transition temperature greater than 150° C.

Claim 12

The element of claim 1 and 2 wherein the layer has a single glass transition temperature.

Claim 13

The element of claim 1 or 2 wherein the dye is selected from the group consisting of indolizine, indolizinium and metal dithiene dyes.

Claim 14

The element of claim 1 or 2 wherein the dye is a nickel dithiene.

Claim 15

The element of claim 1 or 2 wherein the dye is selected from the group consisting of ##STR66## and mixtures of said dyes.

Claim 16

The element of claim 1 or 2 wherein the dye is selected from the group consisting of 7-[2-(1,2-dimethyl-1,2,3,4-tetrahydro-6-quinolinyl)-1-ethenyl]-2,3-diphenyl-8-methyl-1-oxo-indolizinium trifluoromethanesulfonate; 7-[2-(1,2-dimethyl-1,2,3,4-tetrahydro-6-quinolinyl)-1-ethenyl]-2,3-diphenyl-6-methyl-1-oxo-indolizinium trifluoromethanesulfonate; 7-[2-(1,2-dimethyl-1,2,3,4-tetrahydro-6-quinolinyl)-1-ethenyl]-2,3-di(2,5-dimethoxyphenyl)-8-methyl-1-oxo-(1H)-indolizinium trifluoromethane sulfonate and mixtures of said dyes.