Copolyesters and formulations thereof for adhesives

Claim 2

A copolyester comprising (A) an acid component comprising repeating units of (1) 60 to 75 mol % of terephthalic acid, and (2) 25 to 40 mol % of a dicarboxylic aliphatic or cycloaliphatic acid having from 4 to 20 carbon atoms, and (B) a glycol component comprising repeating units of (1) 55 to 65 mol % 1,4-butanediol, and (2) 35 to 45 mol % of one or more other aliphatic diols having 2 to 12 carbon atoms, wherein the total mol % of acid component and glycol component are each 100 mol %; the inherent viscosity of the copolyester is about 0.4 to about 0.6 determined at 25° C. in 60/40 (wt./wt.) phenol/tetrachloroethane at a concentration of 0.5 gram/100 ml; and said copolyester has a heat of fusion value of less than about 20 calories per gram.

Claim 3

The copolyester of claim 1 wherein said inherent viscosity is about 0.4 to about 0.55.

Claim 4

The copolyester of claim 1 wherein the aliphatic diol of component (B)(2) has 2 to 12 carbon atoms.

Claim 5

The copolyester of claim 1 wherein component (B)(2) is diethylene glycol.

Claim 6

The copolyester of claim 1 wherein component (A)(2) is glutaric acid, sebacic acid, adipic acid, or azelaic acid.

Claim 7

The copolyester of claim 1 wherein component (A)(1) is 75 to about 60 mol % terephthalic acid, component (A)(2) is 25 to about 40 mol % glutaric acid, component (B)(1) is about 60 to about 65 mol % 1,4-butanediol, and component (B)(2) is about 35 to about 40 mol % diethylene glycol.

Claim 8

The copolyester of claim 1 wherein component (A)(1) is about 74 mol % terephthalic acid, component (A)(2) is about 26 mol % glutaric acid, component (B)(1) is about 58 mol % 1,4-butanediol, and component (B)(2) is about 42 mol % diethylene glycol.

Claim 9

The copolyester of claim 1 wherein component (A)(1) is 75 mol % terephthalic acid, component (A)(2) is 25 mol % glutaric acid, component (B)(1) is about 65 mol % 1,4-butanediol, and component (B)(2) is about 35 mol % diethylene glycol.

Claim 10

The copolyester of claim 1 wherein component (A)(1) is about 60 mol % terephthalic acid, component (A)(2) is about 40 mol % glutaric acid, component (B)(1) is about 58 mol % 1,4-butanediol, and component (B)(2) is about 42 mol % diethylene glycol.

Claim 11

The copolyester of claim 1 in the form of a hot-melt adhesive useful with a glue gun, wherein said polyester has a melt viscosity value of about 10,000 to about 50,000 cP at application temperature.

Claim 12

The copolyester of claim 10 wherein said melt viscosity is about 20,000 to about 40,000 cP at application temperature.

Claim 13

A hot-melt adhesive blend for use with a glue gun comprising (I) greater than about 70 weight % of a copolyester comprising (A) an acid component comprising repeating units of (1) 60 to 75 mol % of terephthalic acid, and (2) 25 to 40 mol % of a dicarboxylic aliphatic or cycloaliphatic acid having from 4 to 20 carbon atoms, and (B) a glycol component comprising repeating units of (1) 55 to 65 mol % 1,4-butanediol, and (2) 35 to 45 mol % of one or more other aliphatic diols having 2 to 12 carbon atoms, wherein the total mol % of acid component and glycol component are each 100 mol %; the inherent viscosity of the copolyester is about 0.4 to about 0.6 determined at 25° C. in 60/40 (wt./wt.) phenol/tetrachloroethane at a concentration of 0.5 gram/100 ml; and a heat of fusion value of less than about 20 calories per gram, and (II) greater than 0 but less than about 30 weight % of a tackifying resin, wherein the melt viscosity of the blend is about 10,000 to about 50,000 cP at application temperature.

Claim 14

A hot-melt adhesive blend for use with a glue gun comprising (I) greater than about 70 weight % of a copolyester comprising (A) an acid component comprising repeating units of (1) 60 to 75 mol % of terephthalic acid, and (2) 25 to 40 mol % of a dicarboxylic aliphatic or cycloaliphatic acid having from 4 to 20 carbon atoms, and (B) a glycol component comprising repeating units of (1) 55 to 65 mol % 1,4-butanediol, and (2) 35 to 45 mol % of one or more other aliphatic diols having 2 to 12 carbon atoms, wherein the total mol % of acid component and glycol component are each 100 mol %; the inherent viscosity of the copolyester is about 0.4 to about 0.6 determined at 25° C. in 60/40 (wt./wt.) phenol/tetrachloroethane at a concentration of 0.5 gram/100 ml; and a heat of fusion value of less than about 20 calories per gram, and (II) greater than 0 but less than about 30 weight % of a tackifying resin, wherein the melt viscosity of the blend is about 10,000 to about 50,000 cP at application temperature.

Claim 15

The blend of claim 12 wherein the inherent viscosity of said copolyester is about 0.4 to about 0.55, and said blend has a melt viscosity at application temperature of about 20,000 to about 40,000 cP.

Claim 16

The blend of claim 12 wherein component (I) is present in an amount of about 80-95 weight % and component (II) is present in an amount of about 5-20 weight %.

Claim 17

The blend of claim 12 wherein component II is hydrogenated rosin, a rosin ester, or a mixture thereof.

Claim 18

The blend of claim 12 wherein component (I)(A)(2) is glutaric acid, sebacic acid, adipic acid, or azelaic acid, and component (I)(B)(2) is diethylene glycol.

Claim 19

The blend of claim 12 wherein component (I)(A)(1) is 75 to about 60 mol % terephthalic acid, component (I)(A)(2) is 25 to about 40 mol % glutaric acid, component (I)(B)(1) is about 60-65 mol % 1,4-butanediol, and component (I)(B)(2) is about 35-40 mol % diethylene glycol.

Claim 20

The blend of claim 12 wherein component (I)(A)(1) is about 74 mol % terephthalic acid, component (I)(A)(2) is about 26 mol % glutaric acid, component (I)(B)(1) is about 58 mol % 1,4-butanediol, and component (I)(B)(2) is about 42 mol % diethylene glycol.

Claim 21

The blend of claim 12 wherein component (I)(A)(1) is 75 mol % terephthalic acid, component (I)(A)(2) is 25 mol % glutaric acid, component (I)(B)(1) is about 65 mol % 1,4-butanediol, and component (I)(B)(2) is about 35 mol % diethylene glycol.

Claim 22

The blend of claim 12 wherein component (I)(A)(1) is about 60 mol % terephthalic acid, component (I)(A)(2) is about 40 mol % glutaric acid, component (I)(B)(1) is about 58 mol % 1,4-butanediol, and component (I)(B)(2) is about 42 mol % diethylene glycol.